7 research outputs found
Local Strain Engineering in Atomically Thin MoS<sub>2</sub>
Controlling the bandstructure through
local-strain engineering
is an exciting avenue for tailoring optoelectronic properties of materials
at the nanoscale. Atomically thin materials are particularly well-suited
for this purpose because they can withstand extreme nonhomogeneous
deformations before rupture. Here, we study the effect of large localized
strain in the electronic bandstructure of atomically thin MoS<sub>2</sub>. Using photoluminescence imaging, we observe a strain-induced
reduction of the direct bandgap and funneling of photogenerated excitons
toward regions of higher strain. To understand these results, we develop
a nonuniform tight-binding model to calculate the electronic properties
of MoS<sub>2</sub> nanolayers with complex and realistic local strain
geometries, finding good agreement with our experimental results
Perovskite/Perovskite Tandem Solar Cells in the Substrate Configuration with Potential for Bifacial Operation
Perovskite/perovskite tandem solar cells have recently
exceeded
the record power conversion efficiency (PCE) of single-junction perovskite
solar cells. They are typically built in the superstrate configuration,
in which the device is illuminated from the substrate side. This limits
the fabrication of the solar cell to transparent substrates, typically
glass coated with a transparent conductive oxide (TCO), and adds constraints
because the first subcell that is deposited on the substrate must
contain the wide-bandgap perovskite. However, devices in the substrate
configuration could potentially be fabricated on a large variety of
opaque and inexpensive substrates, such as plastic and metal foils.
Importantly, in the substrate configuration the narrow-bandgap subcell
is deposited first, which allows for more freedom in the device design.
In this work, we report perovskite/perovskite tandem solar cells fabricated
in the substrate configuration. As the substrate we use TCO-coated
glass on which a solution-processed narrow-bandgap perovskite solar
cell is deposited. All of the other layers are then processed using
vacuum sublimation, starting with the charge recombination layers,
then the wide-bandgap perovskite subcell, and finishing with the transparent
top TCO electrode. Proof-of-concept tandem solar cells show a maximum
PCE of 20%, which is still moderate compared to those of best-in-class
devices realized in the superstrate configuration yet higher than
those of the corresponding single-junction devices in the substrate
configuration. As both the top and bottom electrodes are semitransparent,
these devices also have the potential to be used as bifacial tandem
solar cells
Electronic Structure and Charge Transport Properties of a Series of 3,6-(Diphenyl)‑<i>s</i>‑tetrazine Derivatives: Are They Suitable Candidates for Molecular Electronics?
Optoelectronic and charge-transport
related properties of a series of 3,6-diphenyl-<i>s</i>-tetrazine
derivatives, including F, Cl, Br, and CN substituents, have been analyzed.
The molecular structure and electronic properties of the new fluorine-containing
derivative, bis(3,6-difluorophenyl)-<i>s</i>-tetrazine,
were explored by spectroscopic, electrochemical, and theoretical methods.
The effects of the substituent on the pristine compound have been
assessed from a theoretical perspective, showing that the fluorinated
and brominated derivatives have the highest predicted electron mobilities,
whereas the cyano derivative is foreseen to undergo the most efficient
electron injection process