The Use of Social Networks to Train the Intercultural Dimension of Foreign Languages at Higher Educational Institutions

The paper aims to identify how social networks contribute to training the intercultural dimension of foreign languages at higher educational institutions. We attempted to answer the questions of what effect the use of social networks has on foreign language training, fostering intercultural and occupational skills, and how both students and teachers perceive the intervention. To achieve research goals, we used quantitative tools, such as (1) checklists, (2) assessment records on English for Specific Purposes, (3) the cultural intelligence scale, (4) the multidimensional emotional empathy scale, and (5) the questionnaire for reflective thinking. Qualitative data were drawn from the observations and interviews. The research findings confirmed that the use of social networks provided students with a true-to-life (authentic) environment and context to gain cultural experience and train a foreign language. This strategy boosts English for Specific Purposes learning and teaching experiences using a distance-learning component. A longitudinal research design enhances transformations in students in terms of emotional empathy and reflective thinking

Effects of fertilization on Picea abies stands situated on drained peat soils

ArticleNorway spruce used for afforestation of drained peat soils frequently has low productivity and decay in a long - term, which could be related to soil chemical composition and nutrient status. The research aim was to elucidate the effect of PSM on new Norway spruce plantings (1st experiment) and 20 - year - old spruce stands (2nd experiment) on drained peat soils by evaluating: (1) nutrient accumulation in soil - plant system, (2) soil microbiological activity, (3) health status of spruce individuals, (4) growth int ensity and productivity of spruce, (5) changes in composition of vascular plant and moss species. The study was conducted at two forest ( Myrtillosa turf.mel .) sites in Latvia, each consisting of two plots: control and treated with PMS (100 g m - 2 in Septemb er 2007, 50 g m - 2 in April 2008). During 2008 – 2016, regular analysis of soil, spruce needles, soil microbiology, assessment of tree crown vitality, stand productivity, inventory of vascular plant and moss species were done. The results showed that the fert ilization with PMS resulted in a significantly improved K, Ca, Zn, and N status of trees, crown vitality and up to three times increased tree growth parameters at both experiments during the study period. The average count of bacteria and fungi in soil of fertilized plots, accompanied by a remarkable variability in the study years, was significantly higher only for the 1 st experiment. Fungi : bacteria ratio for the fertilized and control plots differed significantly only for the 1 st experiment. Significant i ncrease of cover with nitrophilic plant ( Urtica dioica, Antriscus sylvestris, Rubus idaeus ) and moss ( Plagiomnium cuspidatum , P. ellipticum ) species at both fertilized sites were stated

Silicon redistribution, acid site loss and the formation of a core-shell texture upon steaming SAPO-34 and their impact on catalytic performance in the methanol-to-olefins (MTO) reaction

IBM has received funding from the Engineering and Physical Sciences Research Council (EPSRC, Centre for Doctoral Training in Critical Resource Catalysis, EP/I017008/1) and Scotland's Chemistry departments (ScotCHEM). IBM also received a scholarship from the SCI and Santander. Johnson Matthey is thanked for in-kind contributions and hosting IBM in their R&D labs. ABN gratefully acknowledges support from the EPSRC (grants EP/L017008/1 and EP/R023751/1). The research data supporting this publication can be accessed at: https://doi.org/10.17630/09ddc03e-f121-4e79-9b55-674f64d9c8c4 [62].SAPO-34 is a commercially-implemented silicoaluminophosphate catalyst for selective high yield production of ethene and propene from methanol, but high temperature regeneration in the presence of steam leads to its deactivation. A comprehensive investigation of the effect of prolonged hydrothermal treatment on the structure and properties of SAPO 34 explains the changes in its catalytic methanol-to-olefins (MTO) performance. Microcrystalline powdered SAPO-34 (ca. 3 µm crystals, Al17.1P15.6Si3.3O72) and two batches of larger single crystals of SAPO-34 of different Si concentration (20-100 µm; Al17.3P14.7Si4.0O72 and Al17.7P12.3Si5.9O72 ) were steamed (pH2O = 0.95 atm) at 873–1023 K for up to 240 h. The acidity (NH3-TPD), crystallinity (PXRD), framework cation environment (solid-state 27Al, 29Si and 31P MAS NMR) and porosity were followed for all materials; larger crystals were amenable to single crystal X-ray diffraction, FIB-SEM and synchrotron IR microspectroscopy, including operando study during methanol and dimethyl ether conversions. Some level of steaming improved the lifetime of all SAPO-34 materials in MTO catalysis without affecting their olefin selectivity, although more severe conditions led to the formation of core-shell structures, microporosity loss and eventually at 1023 K, recrystallization to a dense phase. All these irreversible changes occurred faster in crystals with higher Si contents. The initial increase in catalytic lifetime results from an activated reduction in acid site density (Eact = 146(18) kJ mol⁻1), a result of redistribution of Si within the SAPO framework without porosity loss. Operando IR with online product analysis during methanol conversion suggests similar reaction pathways in calcined and steamed crystals, but with greatly reduced methoxy group densities in the latter. The gradual development of optically dark crystal cores upon progressive steaming was shown by FIB-SEM to be due to the formation of regions with meso- and macropores, and these were shown by IR mapping to possess low hydroxyl densities.PostprintPostprintPeer reviewe

CSD 2039327 & 2039328: Experimental Crystal Structure Determination

Related Article: Ivalina B. Minova, Nathan S. Barrow, Andrea C. Sauerwein, Aaron B. Naden, David B. Cordes, Alexandra M.Z. Slawin, Stephen J. Schuyten, Paul A. Wright|2021|J.Catalysis|395|425|doi:10.1016/j.jcat.2021.01.01