Heat capacity of nanostructured multiferroics BiFe1–x Zn x O3

The heat capacity of ceramic BiFe1–x Zn x O3 multiferroics has been studied in the temperature range 150–750 K. It is found that the antiferromagnetic transition temperature T N slightly shifts to lower temperatures as the concentration of the substitutional impurity Zn increases. An excess heat treatment has been observed; it is considered as the Schottky anomaly in three-level states

Dielectric properties and ac conductivities of Bi 1− x Sm x FeO 3 ceramics

Dielectric permittivity, dielectric losses and ac-conductivity of polycrystalline Bi1−xSmxFeO3 (x = 0; 0.05; 0.1; 0.15; 0.2) are measured in the frequency range 1 kHz–10 MHz and in the temperature range 25–600 °C. Anomalies have been observed at the 200 °C, 300 °C and at the Néel temperature. It has been demonstrated that doping with Sm has enhanced the dielectric properties and increased conduction in the frequency region 1 MHz) and at a certain temperature Tm, depending on the composition Bi1−xSmxFeO3, the conductivity reaches a maximum. The results are discussed with reference to the model of correlated barrier hopping.Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART