Weaknesses and strenghts in assessing early childhood programmes: an assessment of an early childhood spanish trilingual priogramme in two- to three- year- old children

This article gives an account of the results from an assessment of an early childhood education programme, conducted over the course of two academic years (1999–2000 and 2000–2001), in a centre in northeastern Spain. The purpose of the assessment was to discover how a particular educational programme contributed to the short‐term competency levels of children aged from two to three years old. The programme’s curriculum encompassed different areas of development, including physical exercise and motor movement and social and linguistic development, using a unique teaching methodology that exposes the children to three different languages at the same time. The article includes a discussion of the weaknesses and strengths in implementing evaluation in early childhood education programmes, and concludes with some guiding principles that may prove useful in the evaluation of the appropriateness of any given assessment method used within an early childhood educational programme

Self-assembly of a functional oligo(aniline)-based amphiphile into helical conductive nanowires

A tetra(aniline)-based cationic amphiphile, TANI-NHC(O)C5H10N(CH3)3+Br– (TANI-PTAB) was synthesized, and its emeraldine base (EB) state was found to self-assemble into nanowires in aqueous solution. The observed self-assembly is described by an isodesmic model, as shown by temperature-dependent UV–vis investigations. Linear dichroism (LD) studies, combined with computational modeling using time-dependent density functional theory (TD-DFT), suggests that TANI-PTAB molecules are ordered in an antiparallel arrangement within nanowires, with the long axis of TANI-PTAB arranged perpendicular to the nanowire long axis. Addition of either S- or R- camphorsulfonic acid (CSA) to TANI-PTAB converted TANI to the emeraldine salt (ES), which retained the ability to form nanowires. Acid doping of TANI-PTAB had a profound effect on the nanowire morphology, as the CSA counterions’ chirality translated into helical twisting of the nanowires, as observed by circular dichroism (CD). Finally, the electrical conductivity of CSA-doped helical nanowire thin films processed from aqueous solution was 2.7 mS cm–1. The conductivity, control over self-assembled 1D structure and water-solubility demonstrate these materials’ promise as processable and addressable functional materials for molecular electronics, redox-controlled materials and sensing