Initial stages of cavitation damage and erosion on copper and brass tested in a rotating disk device

In view of the differences in flow and experimental conditions, there has been a continuing debate as to whether or not the ultrasonic method of producing cavitation damage is similar to the damage occurring in cavitating flow systems, namely, venturi and rotating disk devices. In this paper, the progress of cavitation damage during incubation periods on polycrystalline copper and brass tested in a rotating disk device is presented. The results indicate several similarities and differences in the damage mechanism encountered in a rotating disk device (which simulates field rotary devices) and a magnetostriction apparatus. The macroscopic erosion appears similar to that in the vibratory device except for nonuniform erosion and apparent plastic flow during the initial damage phase

Modelling of Multiple Transverse Cracks In Angle - Ply Laminates

Multiple transverse cracking is one of the most common fai'ure modes in composite laminates. In this paper, transverse crack behaviour in 1±0/90°], angle-ply composite laminates under uniaxial loading has been studied by 3D finite element method. Energy method is used for calculating strain energy release rate and stiffness reduction as the crack extends in the width direction. A control volume having a single transverse crack has been used for the analysis. Eight noded isonarametric layered composite elements with three degrees of freedom per node have been used to discretise the control volume. Load is applied in longitudinal direction via uniform applied displacements through the ±0 outer layers. Strain energy release rate and stiffness reduction are calculated for different crack lengths, crack densities and fibre orientation angle 0 of the outer layers. From the analysis it has been observed that strain energy release rate increases with the increase in fibre orientation angle 0 of the outer layers. However, the variation of strain energy release rate in width direction is negligible. Stiffness reduction has been noticed with increase in fibre orientation angle 0 and crack density

Rapid Determination of Copper in Copper Ores

Low grade copper ores and copper ores in association with considerable quantities of other elements such as iron, lead, zinc and vanadium require a separational step wherein copper is generally seperated as sulphide either with sodium thiosulfate or with thiocetamide. In these methods the precipitated copper sulfide is ignited to cupric oxide, dissolved in dilute nitric acid and titrated idometrically. In a recent methorl wet oxidation of precipitated copper sulfide is effected with nitric acid ,and perchloric acid and titrated with disodium ethylene diamine tetraacetate (EDTA). The authors' work on the beneficiation of low grade copper ores. and extraction of copper, from these ores has necessitated developing a rapid and accurate method for the determination of copper. A separational step wherein cupric ion could be preci-pitated as cuprous oxide has been introduced to avoid ignition of copper sulfide to cupric oxide, which is time consuming

Magnetic and electron transport properties of the rare-earth cobaltates, La0.7-xLnxCa0.3CoO3 (Ln = Pr, Nd, Gd and Dy) : A case of phase separation

Magnetic and electrical properties of four series of rare earth cobaltates of the formula La0.7-xLnxCa0.3CoO3 with Ln = Pr, Nd, Gd and Dy have been investigated. Compositions close to x = 0.0 contain large ferromagnetic clusters or domains, and show Brillouin-like behaviour of the field-cooled DC magnetization data with fairly high ferromagnetic Tc values, besides low electrical resistivities with near-zero temperature coefficients. The zero-field-cooled data generally show a non-monotonic behaviour with a peak at a temperatures slightly lower than Tc. The near x = 0.0 compositions show a prominent peak corresponding to the Tc in the AC-susceptibility data. The ferromagnetic Tc varies linearly with x or the average radius of the A-site cations, (rA). With increase in x or decrease in (rA), the magnetization value at any given temperature decreases markedly and the AC-susceptibility measurements show a prominent transition arising from small magnetic clusters with some characteristics of a spin-glass. Electrical resistivity increases with increase in x, showed a significant increase around a critical value of x or (rA), at which composition the small clusters also begin to dominate. These properties can be understood in terms of a phase separation scenario wherein large magnetic clusters give way to smaller ones with increase in x, with both types of clusters being present in certain compositions. The changes in magnetic and electrical properties occur parallely since the large ferromagnetic clusters are hole-rich and the small clusters are hole-poor. Variable-range hopping seems to occur at low temperatures in these cobaltates.Comment: 23 pages including figure

Disentangling the dominant drivers of gravity wave variability in the Martian thermosphere

In this study, we extracted the amplitudes of the gravity waves (GWs)from the neutral densities measured in situ by the neutral gas and ion mass spectrometer aboard the Mars atmosphere and volatile evolution mission. The spatial and temporal variabilities of the GWs show that solar activity (the F10.7 cm solar flux corrected for a heliocentric distance of 1.66 AU), solar insolation, and the lower atmospheric dust are the dominant drivers of the GW variability in the thermosphere. We developed a methodology in which a linear regression analysis has been used to disentangle the complex variabilities of the GWs. The three dominant drivers could account for most of the variability in the GW amplitudes. Variability caused by the sources of GWs and the effects of winds and the global circulation in the mesosphere and lower thermosphere are the other factors that could not be addressed. The results of the present study show that for every 100 sfu increase in the solar activity, the GW amplitudes in the thermosphere decrease by ~9%. Solar insolation drives the diurnal, seasonal and latitudinal variations of ~9%, ~4% and ~6%, respectively. Using the historical data of the dust opacity and solar activity, we estimated the GW amplitudes of the Martian thermosphere from MY 24 to MY 35. The GW amplitudes were significantly reduced during the maximum of solar cycle 23 and were highest in the solar minimum. The global dust storms of MY 25, 28, and 34 lead to significant enhancements in the GW amplitudes.Comment: Accepted for publication in the astrophysical journal; 18 page

Training needs assessment in Malaysia: Exercise held at Kuala Lampur and Kota Bharu from 13th October 1989

Training / Irrigation / Evaluation / Malaysia

Multi component one pot synthesis and characterization of derivatives of 2-amino-7,7- dimethyl-5-oxo-4-phenyl-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile and study of anti-microbial activity

An efficient and convenient procedure has been described for one-pot multi-component synthesisof tetrahydrobenzo[b]pyrans known as 2-amino-7,7-dimethyl-5-oxo-4-phenyl-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile which can be obtained from the reaction of substituted aromatic aldehydes, dimedone, malonitrile, in the presence of base such as potassium tertiary butoxide and THF in methanol as solvent at RT condition. All the compounds were examined by advanced spectroscopic data (1H NMR, 13C NMR and LCMS) and the structural determination was evaluated by elemental analysis. In addition to this, all the newly synthesized compounds were examined for their antibacterial activities and antifungal activity by disc diffusion method against the organism of Aspergillus niger and Candida ablicans L.               KEY WORDS: Aromatic aldehydes, Dimedone, Malonitrile, Potasium tertiary butoxide, 2-Amino-7,7-dimethyl-5-oxo-4-phenyl-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, Anti-microbial activity Bull. Chem. Soc. Ethiop. 2018, 32(1), 133-138DOI: https://dx.doi.org/10.4314/bcse.v32i1.1

Amino acid imbalance and tryptophanniacin metabolism: I. Effect of excess leucine on the urinary excretion of tryptophan-niacin metabolites in rats

The effect of feeding excess leucine on the urinary excretion of tryptophan-niacin metabolites and nitrogen was studied in young and adult rats. Urinary excretion of quinolinic acid and N'methylnicotinamide was increased in both young and adult rats when L-leucine was added at 1.5% level to a 9% casein diet. Quinolinic acid excretion was more markedly affected in young rats, whereas N'-methylnicotinamide excretion was more affected in adult rats. Isoleucine counteracted the effect of leucine in young rats. Nitrogen excretion increased on leucine feeding in adult rats but not in young rats. Adult rats fed a jowar (Sorghum vulgare) diet tended to excrete relatively more N'-methylnicotinamide and niacin than when fed a wheat diet