True mid-infrared Pr3+ absorption cross-section in a selenide-chalcogenide host-glass

The mid-infrared (MIR) spans the 3-25 m wavelength range. Rare-earth-ion doped selenide-chalcogenide glasses are being developed for direct-emission MIR fibre lasers. The true Pr3+ absorption cross-section in the 3.5-6 µm wavelength region of a Pr3+-doped (500 ppmw of Pr3+ i.e. 9.47 x 1019 Pr3+ ions cm-3) GeAsGaSe host-glass is presented, after numerically removing the underlying, extrinsic vibrational absorption due to [H-Se-] contamination of the host-glass

True mid-infrared Pr3+ absorption cross-section in a selenide-chalcogenide host-glass

The mid-infrared (MIR) spans the 3-25 m wavelength range. Rare-earth-ion doped selenide-chalcogenide glasses are being developed for direct-emission MIR fibre lasers. The true Pr3+ absorption cross-section in the 3.5-6 µm wavelength region of a Pr3+-doped (500 ppmw of Pr3+ i.e. 9.47 x 1019 Pr3+ ions cm-3) GeAsGaSe host-glass is presented, after numerically removing the underlying, extrinsic vibrational absorption due to [H-Se-] contamination of the host-glass

Characterising refractive index dispersion in chalcogenide glasses

Much effort has been devoted to the study of glasses that contain the chalcogen elements (sulfur, selenium and tellurium) for photonics’ applications out to MIR wavelengths. In this paper we describe some techniques for determining the refractive index dispersion characteristics of these glasses. Knowledge of material dispersion is critical in delivering step-index fibres including with high numerical aperture for mid-infrared supercontinuum generation

Numerical modelling of Tb3+ doped selenide-chalcogenide multimode fibre based spontaneous emission sources

A model is developed of a terbium (III) ion doped selenide chalcogenide glass fibre source that provides spontaneous emission within the mid-infrared (MIR) wavelength range. Three numerical algorithms are used to calculate the solution and compare their properties

Experimental investigation of mid-infrared laser action from DY3+ doped fluorozirconate fiber

Efficient continuous-wave laser operation at 2.982 μm is achieved with a Dy3:fluoride fiber pumped using an inhouse-built 1.1 μm ytterbium (III) fiber laser. The laser output power reached is 554 mW, with a maximum slope efficiency of 18% with respect to the launched pump power. Additionally, the measured spontaneous luminescence within the visible wavelength range, under 1.1 μm pumping, is presented and attributed to excited state absorption (ESA). The influence of the ESA on the laser performance is discussed. The results confirm that high output powers from Dy: fluoride fiber laser pumped at 1.1 μm are possible

Numerical modeling of lathanide-ion doped fibre lasers operating within mid-infrared wavelength region

We discuss the numerical modelling of lanthanide-ion doped chalcogenide glass fibre lasers for operation in the mid-infrared wavelength region. We extract the modelling parameters from emission and absorption measurements using Judd-Ofelt and McCumber theory. Numerical algorithms are developed based on the experimentally extracted fibre parameters. The simulation results predict lasing with slope efficiency of at least 20 % provided, that the fibre loss can be kept at the level of 1 dB/m or less

Modelling of multimode selenide-chalcogenide glass fibre based MIR spontaneous emission sources

Chalcogenide glass fibres have been demonstrated as a suitable medium for the realisation of spontaneous emission sources for mid-infrared photonics applications with a particular emphasis on sensor technology. Such sources give a viable alternative to other solutions due to their potentially low cost, high reliability and robustness when pumped using commercially available semiconductor lasers. We present a comprehensive analysis of the properties of selenide-chalcogenide glass fibres applied as spontaneous emission sources. We extract the modelling parameters from measurements using in house fabricated bulk glass and fibre samples. We apply the well-established rate equations approach to determine the level populations, the distribution of the photon intensity within the fibre and the output power levels. We compare the modelling results with experiment

Raspberry pomace alters cecal microbial activity and reduces secondary bile acids in rats fed a high-fat diet

The profile of bile acids (BA) largely depends on the enzymatic activity of the microbiota, but this can be modulated by the dietary addition of biologically active compounds, e.g., polyphenols and polyunsaturated fatty acids. The aim of this study was to examine the effect of dietary raspberry pomace as a rich source of biologically active compounds on microbial activity and the BA profile in the caecum of rats fed a high-fat diet. Wistar rats were fed the standard diet AIN-93, a high-fat diet or a modified high-fat diet enriched with 7% different types of processed raspberry pomaces produced by standard grinding and fine grinding, with or without seeds. Rats fed the high-fat diet for eight weeks showed some disorders in liver function and cecal BA, as manifested by an increased concentration of cholesterol, total BA in the liver and cholic, deoxycholic, and β-muricholic acids in the cecal digesta. In general, irrespective of the type of raspberry pomace, these dietary preparations decreased liver cholesterol, hepatic fibroblast growth factor receptor 4, peroxisome proliferator-activated receptor alpha, cecal ammonia and favorable changed BA profile in the cecum. However, among all dietary pomaces, the finely ground preparation containing seeds had the greatest beneficial effect on the caecum by modulating bacterial activity and reducing the levels of secondary BA

Modeling of resonantly pumped mid-infrared Pr3+-doped chalcogenide fiber amplifier with different pumping schemes

We propose a model for resonantly pumped Pr3+-doped chalcogenide fiber amplifiers which includes excited state absorption and the full spectral amplified spontaneous emission spanning from 2 μm to 6 μm. Based on this model, the observed near- and mid-infrared photoluminescence generated from Pr3+-doped chalcogenide fiber is explained. Then the output properties of a 4.1 μm resonantly pumped Pr3+-doped chalcogenide fiber amplifier are simulated in both co- and counter-pumping schemes. Results show that the 4.1 μm counter-pumped fiber amplifier can achieve a power conversion efficiency (PCE) of over 62.8 % for signal wavelengths ranging from 4.5 μm to 5.3 μm. This is, to our best knowledge, the highest simulated PCE for a Pr3+-doped chalcogenide fiber amplifier