23 research outputs found
[Review] Cian Duffy (2014) My purpose was humbler, but also higher: Thomas De Quinceyâs 'System of the heavensâ, popular science and the sublime
Review of article: Duffy Cian, Romanticism, Volume 20 Issue 1, Page 1-14, ISSN 1354-991x Available Online Mar 201
Reading Redaction: Symptomatic Metadata, Erasure Poetry, and Mark Blacklockâs Iâm Jack
In this article, through a reading of Mark Blacklockâs 2015 novel, Iâm Jack, alongside the history of erasure poetry, I suggest that an apt literary-critical metaphor for reading redaction in contemporary literature comes from the term âmetadataâ. The article schematizes the ways in which redaction can work in literary contexts and points to the modalities through which supposedly blank surfaces are, in fact, textured depths that can be read
From Relics to Remains: Wordsworthâs âThe Thornâ and the Emergence of Secular History
In their recurrent focus on the relationship between narrative and experience, âtestimonyâ and ârelics,â the Lyrical Ballads show Wordsworth to be our first truly archaeological poet, the first to take seriously the notion of âpre-historyâ as a mode of encountering the material world in the present, and not just a way of designating a material world that pre-dates written records. Wordsworthâs reading in Druid history, and specifically William Stukeleyâs accounts of barrow excavations near Stonhenge and Avebury, helped to shape the poetâs understanding of âpre-historyâ in this sense. âThe Thornâ, with its reiterations of measurement and spatial orientation relative to the site of a mound that may or may not be âan infantâs grave,â reflects the specific influence of Stukeleyâs accounts, as well as Wordsworthâs preoccupation with the mystery of how whatever âremainsâ in the present manages to make present, in the space and time of a universal history, the historian or poetic âpre-historianâ who has encountered it
Formaldehyde-Induced Deactivation of ZSM5 Catalysts during the Methanol-to-Hydrocarbons Conversion
Formaldehyde productivity and reactivity over zeolite catalysts are suggested to influence their selectivity and stability in the methanol-to-hydrocarbons (MTH) conversion. However, details of these relationships have yet to be established. In this study, we applied photoelectron photoion coincidence spectroscopy to examine the productivity of this intermediate over unpromoted and zinc-loaded ZSM-5 catalysts. Formaldehyde is the primary MTH product. Its production over unpromoted catalysts proceeds mainly via hydrogen transfer between methanol molecules, the rate of which is proportional to the concentration of strong Br & oslash;nsted acid sites. In zinc-promoted ZSM-5, formaldehyde is mainly derived via methanol dehydrogenation, which provides up to a 12x higher productivity of this intermediate. The cumulative turnover capacity of the catalyst displays a strong negative correlation with its formaldehyde evolution activity. Formaldehyde evolution is enhanced at higher methanol concentrations and reaction temperatures, which are conditions also leading to enhanced coking. Complementary formaldehyde cofeeding experiments demonstrate that this intermediate enhances the formation of ethene and methylbenzenes over C3+ alkenes, which is in agreement with high selectivities to the products of the arene cycle over the catalysts with high formaldehyde productivity. The addition of formaldehyde promotes most substantially the deactivation of the most stable ZSM-5 catalysts displaying inherently low productivity of this intermediate, rendering their lifetimes comparable to those of their less stable counterparts. Operando diffuse-reflectance UV-vis spectra show that small amounts of formaldehyde greatly promote the conversion of cyclopentadienyl and methylated benzenyl intermediates into bicyclic and polycyclic aromatics. Consistent with this, formaldehyde cofeeding results in increased coke accumulation in more stable catalysts, especially in their micropores, as supported by X-ray diffraction and photoelectron spectroscopy analysis. These findings represent direct evidence that the stability and product distribution of ZSM-5 catalysts are strongly governed by their formaldehyde evolution activity.ISSN:2155-543
'"Intermitting Power": De Quincey's Sublime Identifications'
In an ambivalent reception, Thomas De Quinceyâs writings identify with and parody Kantâs sublime in the 'Critique of Judgment' (1790). In his essays on the 'aesthetics' of murder, De Quincey mocks Kantâs rational sublime as itself murderous, but he also embraces that sublime as a phantasm of power. The essay argues that by embodying Kantian sublimity in a series of 'intermitting' identifications, De Quincey dramatises the sublime as a theatre of conflict. In this situation, De Quincey himself is empowered and disempowered, and made a subject of elevation and abjection; this means that his work throws into sharp relief the discordant politics of the sublime. Via Kant, De Quincey identifies with both potency and privation, the twin poles of the sublime, with the result that in the fields of philosophy, murder, autobiography, nationality, politics and modernity his writings enact and anatomise the ideological dissonances of sublime power. The essay shows how De Quincey exposes and dramatizes the conflicts of sublime power in his 'Confessions of an English Opium-Eater' (1821, 1856), 'Suspiria de Profundis' (1845), his essays on murder (1827, 1839, 1854), his commentaries on Kant, and his accounts of the âliterature of power.â In his writings on the antithetical effects of opium, we find a self variously empowered and disempowered, elevated and prostrated â both an imperial and a âpariahâ subject. De Quinceyâs texts, in this sense, show how the sublime heights of Kantian idealism are collapsed by the compulsive return of what they try to repress - in De Quinceyâs case, violence, murder, nightmare, dependency, materiality, the body, modernity, the Oriental âother.