3 research outputs found
Assessment of Fullerene Derivatives as Rolling Journals in a Finite Carbon Nanotube Bearing
Conformance assessment of rolling journals in a molecular bearing has been carried out with a combination of fullerenes and finite single-wall carbon nanotube molecules through quantitative analysis of the binding affinities. Endohedral fullerenes were applicable to three-body molecular bearings with slightly weaker binding affinities. Exohedral shaft moieties on C<sub>60</sub> journals affected the binding affinities to reduce the binding constants to a considerable extent, and oval-spherical C<sub>70</sub> journals were superior in tolerating bulky shaft attachments
Asymmetric Autocatalysis Initiated by Finite Single-Wall Carbon Nanotube Molecules with Helical Chirality
An asymmetric autocatalysis reaction
was initiated by a finite
single-wall carbon nanotube molecule with helical chirality. The asymmetric
induction was initiated by the chiral environment arising from the
planar chirality of the tubular polyaromatic hydrocarbons
Photoinduced Electron Transfer in a Dynamic Supramolecular System with Curved π‑Structures
Photoinduced electron-transfer
processes in a carbonaceous supramolecular
combination of a tubular host and a C<sub>60</sub> guest were investigated
with time-resolved transient absorption spectra upon laser flash photolysis.
Following the formation of triplet charge-separated species via electron
transfer from the host to the guest, a rapid back electron transfer
proceeded to afford triplet C<sub>60</sub>