Photoinduced Electron Transfer in a Dynamic Supramolecular
System with Curved π‑Structures
- Publication date
- Publisher
Abstract
Photoinduced electron-transfer
processes in a carbonaceous supramolecular
combination of a tubular host and a C<sub>60</sub> guest were investigated
with time-resolved transient absorption spectra upon laser flash photolysis.
Following the formation of triplet charge-separated species via electron
transfer from the host to the guest, a rapid back electron transfer
proceeded to afford triplet C<sub>60</sub>