Spectroscopy and CW first laser operation of Yb-doped Gd_3(Al_05Ga_05)_5O_12 crystal

We present the spectroscopic characterization and laser operation of a 2%at. Yb doped Gd3(Al0.5Ga0.5)5O12 (Yb:GAGG) crystal, grown with the Czochralski method. We determined the absorption and the emission spectrum, the upper level lifetime, and the thermal conductivity. The internal disordered structure determines a significant broadening of the emission band (12.1 nm FWHM) with respect to the parent composition Yb:GGG (8 nm FWHM). The laser performances were evaluated on an end pumped cavity, using a CW semiconductor laser as the pump source. We obtained a maximum slope efficiency of 60.8% and an optical to optical efficiency of 46.0%, with a maximum output power of 4 W, limited only by the available pump power. The tuning range extends from 995 nm to 1050 nm. To our knowledge this is the first spectroscopic investigation and the first assessment of the laser performance of an Yb:GAGG crystal with this composition (i.e. Al/Ga balance = 0.5/0.5)

Broadband near-infrared luminescence in lead germanate glass triply doped with Yb3+/Er3+/Tm3+

This paper deals with broadband near-infrared luminescence properties of lead germanate glass triply doped with Yb3+/Er3+/Tm3+. Samples were excited at 800 nm and 975 nm. Their emission intensities and lifetimes depend significantly on Er3+ and Tm3+ concentrations. For samples excited at 800 nm, broadband emissions corresponding to the overlapped 3H4 ! 3F4 (Tm3+) and 4I13/2 ! 4I15/2 (Er3+) transitions centered at 1.45 m and 1.5 m was identified. Measurements of decay curves confirm reduction of 3H4 (Tm3+), 2F5/2 (Yb3+) and 4I13/2 (Er3+) luminescence lifetimes and the presence of energy-transfer processes. The maximal spectral bandwidth equal to 269 nm for the 3F4 ! 3H6 transition of Tm3+ suggests that our glass co-doped with Yb3+/Er3+/Tm3+ is a good candidate for broadband near-infrared emission. The energy transfer from 4I13/2 (Er3+) to 3F4 (Tm3+) and cross-relaxation processes are responsible for the enhancement of broadband luminescence near 1.8 m attributed to the 3F4 !3H6 transition of thulium ions in lead germanate glass under excitation of Yb3+ ions at 975 nm

Spectroscopic characterization of CaNb2O6 single crystal doped with samarium ions

Spectroscopic measurements of the calcium niobate CaNb2O6 single crystal doped with samarium ions were performed. Polarized absorption and emission spectra as well as luminescence decay curves of this material were recorded as a function of temperature in the 5–300 K temperature region. Analysis of low temperature spectra made it possible to determine energies of crystal field components of Sm3+ multiplets involved in the excitation and luminescence phenomena. Number of crystal field levels derived implies that Sm3+ ions in the CaNb2O6 host are accommodated in several different sites. Radiative lifetime of the 4G5/2 metastable level determined based on the Judd–Ofelt analysis of room temperature absorption spectra amounts to 777 μs, a value close to that of luminescence lifetime determined from luminescence decay curve. Energy transfer between the NbO6 group and samarium ions was observed in wide temperature range. Intense luminescence related to the 4G5/2→6H7/2 and 4G5/2→6H9/2 transitions centered at 610 nm and 660 nm, respectively, combined with strong absorption band near 404 nm that matches perfectly the pump light provided by commercial InGaN/GaN diode lasers points at a potential of CaNb2O6:Sm3+ for the design of all-solid-state visible lasers

Silica-based oxyfluoride glass and glass-ceramic doped with Tm3+Tm^{3+} and Yb3+Yb^{3+} -VUV-VIS-NIR spectroscopy and optical thermometry

Optical, structural and morphological properties of Tm3+/Yb3+ co-doped NaYF4-based nano-glass-ceramic and a precursor glass have been investigated. The controlled heat-treatment of multicomponent oxyfluoride glass at 640 °C for 2 h was used to obtain crystalline precipitations. The differences in optical characteristics have been discussed analysing spectra recorded within wide VUV–VIS–NIR spectral range and considering relaxation dynamic of involved excited states. Optical spectra and luminescence decay curves were measured as a function of temperature in the range of 295–725 K. Based on up-converted emission spectra excited at 975 nm, temperature sensing properties of glass-ceramic were verified. The fluorescence intensity ratio between the up-converted emission bands located at around 795 nm (Tm3+:3H4–3H6) and 695 nm (Tm3+:3F3,2–3H6) was studied. The maximum relative temperature sensitivity was determined to be 0.35% K−1 at 445 K

Examining the Spectroscopic and Thermographic Qualities of Er3+-doped Oxyfluoride Germanotellurite Glasses

Novel ternary fluoro-germano-tellurite (GTS) glasses doped with Er3+ ions with 0.5 mol% and 1.0 mol% were fabricated by a conventional melt and quenching method and investigated using methods of optical spectroscopy. The room-temperature absorption spectrum was recorded and analyzed to determine radiative transition rates, radiative lifetimes, and branching ratios of Er3+ luminescence. Decay curves of Er3+ luminesccence were recorded and analyzed. Temperature dependences of emission spectra and absorption spectra in the region from RT (room-temperature) up to 675 K were studied in detail. The contribution of competing radiative and nonradiative processes to the relaxation of luminescent levels of Er3+ was assessed. Absolute and relative sensitivity were established utilizing the comprehensive model based on thermally coupled 2H11/2/4S3/2 excited states of erbium. The high quantum efficiency of the first erbium-excited state and value of gain coefficient indicate that GTS:Er glass system can be considered as conceivable NIR (near infrared) laser material as well

Phonon Sideband Analysis and Near-Infrared Emission in Heavy Metal Oxide Glasses

In this work, spectroscopic properties of europium and erbium ions in heavy metal oxide glasses have been studied. The phonon energy of the glass host was determined based on Eu3+ excitation spectra measurements. Near-IR emission spectra at 1550 nm related to 4I13/2 → 4I15/2 transition of erbium in heavy metal glasses were examined with special regards to luminescence bandwidth and measured lifetime. In particular, correlation between phonon energy and the measured lifetime 4I13/2 (Er3+) was proposed. The luminescence lifetime for the 4I13/2 upper laser state of erbium decreases with increasing phonon energy in glass matrices. Completely different results were obtained glass samples with europium ions, where the 5D0 lifetime increases with increasing phonon energy. Our investigations suggest that the values of measured 5D0 lifetime equal to radiative lifetimes for all heavy metal oxide glasses