Ultrafast field-driven monochromatic photoemission from carbon nanotubes

Ultrafast electron pulses, combined with laser-pump and electron-probe technologies, allow for various forms of ultrafast microscopy and spectroscopy to elucidate otherwise challenging to observe physical and chemical transitions. However, the pursuit of simultaneous ultimate spatial and temporal resolution has been largely subdued by the low monochromaticity of the electron pulses and their poor phase synchronization to the optical excitation pulses. State-of-the-art photon-driven sources have good monochromaticity but poor phase synchronization. In contrast, field-driven photoemission has much higher light phase synchronization, due to the intrinsic sub-cycle emission dynamics, but poor monochromaticity. Such sources suffer from larger electron energy spreads (3 - 100 eV) attributed to the relatively low field enhancement of the conventional metal tips which necessitates long pump wavelengths (> 800 nm) in order to gain sufficient ponderomotive potential to access the field-driven regime. In this work, field-driven photoemission from ~1 nm radius carbon nanotubes excited by a femtosecond laser at a short wavelength of 410 nm has been realized. The energy spread of field-driven electrons is effectively compressed to 0.25 eV outperforming all conventional ultrafast electron sources. Our new nanotube-based ultrafast electron source opens exciting prospects for attosecond imaging and emerging light-wave electronics

Career-Specific Parenting Practices and Career Decision-Making Self-Efficacy Among Chinese Adolescents: The Interactive Effects of Parenting Practices and the Mediating Role of Autonomy

This study examined the unique and interactive effects of various career-specific parenting practices (i.e., parental career support, interference, and lack of engagement) on Chinese high school students’ career decision-making self-efficacy (CDSE) as well as the mediating role of autonomy in such associations. Based on data from 641 Chinese high school students (47.6% male; mean age = 15.28 years old, SD = 0.49) in 2016, two moderated mediating effects were identified. Higher level of parental career engagement strengthened the positive association between parental career support and adolescents’ autonomy, which in turn, was associated positively with adolescents’ CDSE. Parental career interference related negatively with adolescents’ CDSE via autonomy when lack of parental career engagement was low, but related positively with adolescents’ CDSE via autonomy when lack of parental career engagement was high. These findings advance our understanding of the underlying processes between career-specific parenting practices and adolescents’ CDSE. Implications for practices were discussed

Controlling Alzheimer's Disease Through the Deep Brain Stimulation to Thalamic Relay Cells

Experimental and clinical studies have shown that the technique of deep brain stimulation (DBS) plays a potential role in the regulation of Alzheimer’s disease (AD), yet it still desires for ongoing studies including clinical trials, theoretical approach and action mechanism. In this work, we develop a modified thalamo-cortico-thalamic (TCT) model associated with AD to explore the therapeutic effects of DBS on AD from the perspective of neurocomputation. First, the neuropathological state of AD resulting from synapse loss is mimicked by decreasing the synaptic connectivity strength from the Inter-Neurons (IN) neuron population to the Thalamic Relay Cells (TRC) neuron population. Under such AD condition, a specific deep brain stimulation voltage is then implanted into the neural nucleus of TRC in this TCT model. The symptom of AD is found significantly relieved by means of power spectrum analysis and nonlinear dynamical analysis. Furthermore, the therapeutic effects of DBS on AD are systematically examined in different parameter space of DBS. The results demonstrate that the controlling effect of DBS on AD can be efficient by appropriately tuning the key parameters of DBS including amplitude A, period P and duration D. This work highlights the critical role of thalamus stimulation for brain disease, and provides a theoretical basis for future experimental and clinical studies in treating AD.Peer Reviewe

Antarctic Snowmelt Detected by Diurnal Variations of AMSR-E Brightness Temperature

Antarctic surface snowmelt is sensitive to the polar climate. The ascending and descending passes of the Advanced Microwave Scanning Radiometer for Earth Observing System Sensor (AMSR-E) observed the Antarctic ice sheet in the afternoon (the warmest period) and at midnight (a cold period), enabling us to make full use of the diurnal amplitude variations (DAV) in brightness temperature (Tb) to detect snowmelt. The DAV in vertically polarized 36.5 GHz Tb (DAV36V) is extremely sensitive to liquid water and can reduce the effects of the structural changes in snowpacks during melt seasons. A set of controlled experiments based on the microwave emission model of layered snow (MEMLS) were conducted to study the changes of the vertically polarized 36.5 GHz Tb (Δ36V) during the transitions from dry to wet snow regimes. Results of the experiments suggest that 9 K can be used as a DAV36V threshold to recognize snowmelt. The analyses of snowmelt suggest that the Antarctic ice sheet began to melt in November and became almost completely frozen in late March of the following year. The total cumulative melt area from 2002 to 2011 was 2.44 × 106 km2, i.e., 17.58% of the Antarctic ice sheet. The annual cumulative melt area showed considerable fluctuations, with a significant (above 90% confidence level) drop of 5.24 × 104 km2/year in the short term. Persistent snowmelt (i.e., melt that continues for at least three days) detected by AMSR-E and hourly air temperatures (Tair) were very consistent. Though melt seasons became longer in the western Antarctic Peninsula and the Shackleton Ice Shelf, Antarctica was subjected to considerable decreases in duration and melting days in stable melt areas, i.e., −0.64 and −0.81 days/year, respectively. Surface snowmelt in Antarctica decreased temporally and spatially from 2002 to 2011

Greenhouse Gas Emissions Analysis Working toward Zero-Waste and Its Indication to Low Carbon City Development

Low carbon city development and greenhouse gas (GHG) emission mitigation in urban communities are urgent. There is great potential to improve the GHG inventory at the community level. Meanwhile, building zero-waste cities and improving waste treatment efficiency have been significant environmental issues due to the rapid increase of waste generation. This research aims to develop a community-scale GHG emission inventory of the waste sector and improve its accuracy and consistency through applying the bottom-up approach. This study covers both direct and indirect emissions categories of the waste sector with the goal of building a zero-waste community. Honjo Waseda community, located in Japan, was used as a case study community. Energy consumption waste treatment sectors were evaluated and calculated through first-hand field data. GHG emission estimation of the waste sector included waste incineration, residential wastewater, and waste transport. The highest emissions originated from Beisiagate supermarket due to the large waste amount produced, and the CO2-biomass carbon emissions reached approximately 50% of the total emissions. Furthermore, a quantitative analysis of the implementation of new technologies was also conducted. This study created proposals for GHG emission reduction toward a zero-waste community through the comparison of three cases. Case 1 was business as usual; Case 2 proposed a combination of incineration bio-gasification (MBT); Case 3 introduced a combination of solid recovered fuel (SRF) and a bio-gasification system. SRF contributed the most to emission reduction, and Case 3 exhibited the highest energy recovery. Furthermore, comparing the GHG emissions produced by the use of SRF for power generation and heat supply revealed that using SRF as a heat supply reduced more GHG emissions than using SRF for power generation

Arabidopsis ribosomal proteins control vacuole trafficking and developmental programs through the regulation of lipid metabolism

The vacuole is the most prominent compartment in plant cells and is important for ion and protein storage. In our effort to search for key regulators in the plant vacuole sorting pathway, ribosomal large subunit 4 (rpl4d) was identified as a translational mutant defective in both vacuole trafficking and normal development. Polysome profiling of the rpl4d mutant showed reduction in polysome-bound mRNA compared with wild-type, but no significant change in the general mRNA distribution pattern. Ribsomal profiling data indicated that genes in the lipid metabolism pathways were translationally down-regulated in the rpl4d mutant. Live imaging studies by Nile red staining suggested that both polar and nonpolar lipid accumulation was reduced in meristem tissues of rpl4d mutants. Pharmacological evidence showed that sterol and sphingolipid biosynthetic inhibitors can phenocopy the defects of the rpl4d mutant, including an altered vacuole trafficking pattern. Genetic evidence from lipid biosynthetic mutants indicates that alteration in the metabolism of either sterol or sphingolipid biosynthesis resulted in vacuole trafficking defects, similar to the rpl4d mutant. Tissue-specific complementation with key enzymes from lipid biosynthesis pathways can partially rescue both vacuole trafficking and auxin-related developmental defects in the rpl4d mutant. These results indicate that lipid metabolism modulates auxin-mediated tissue differentiation and endomembrane trafficking pathways downstream of ribosomal protein function

Simple Preparation of LaPO4:Ce, Tb Phosphors by an Ionic-Liquid-Driven Supported Liquid Membrane System

In this work, LaPO4:Ce, Tb phosphors were prepared by firing a LaPO4:Ce, Tb precipitate using an ionic-liquid-driven supported liquid membrane system. The entire system consisted of three parts: a mixed rare earth ion supply phase, a phosphate supply phase, and an ionic-liquid-driven supporting liquid membrane phase. This method showed the advantages of a high flux, high efficiency, and more controllable reaction process. The release rate of PO43− from the liquid film under different types of ionic liquid, the ratio of the rare earth ions in the precursor mixture, and the structure, morphology, and photoluminescence properties of LaPO4:Ce, Tb were investigated by inductively coupled plasma-atomic emission spectroscopy, X-ray diffraction, Raman spectra, scanning electron microscopy, and photoluminescence emission spectra methods. The results showed that a pure phase of lanthanum orthophosphate with a monoclinic structure can be formed. Due to differences in the anions in the rare earth supply phase, the prepared phosphors showed micro-spherical (when using rare earth sulfate as the raw material) and nanoscale stone-shape (when using rare earth nitrate as the raw material) morphologies. Moreover, the phosphors prepared by this method had good luminescent properties, reaching a maximum emission intensity under 277 nm excitation with a predominant green emission at 543 nm which corresponded to the 5D4-7F5 transition of Tb3+

Multi-domain versus single-domain: a magnetic field is not a must for promoting spin-polarized water oxidation

The reaction kinetics of spin-polarized oxygen evolution reaction (OER) can be enhanced by ferromagnetic (FM) catalysts under an external magnetic field. However, applying a magnetic field necessitates additional energy consumption and creates design difficulties for OER. Herein, we demonstrate that a single-domain FM catalyst without external magnetic fields exhibits a similar OER increment to its magnetized multi-domain one. The evidence is given by comparing the pH-dependent increment of OER on multi- and single-domain FM catalysts with or without a magnetic field. The intrinsic activity of a single-domain catalyst is higher than that of a multi-domain counterpart. The latter can be promoted to approach the former by the magnetization effect. Reducing the FM catalyst size into the single-domain region, the spin-polarized OER performance can be achieved without a magnetic field, illustrating an external magnetic field is not a requirement to reap the benefits of magnetic catalysts.Ministry of Education (MOE)National Research Foundation (NRF)Submitted/Accepted versionThis work is supported by the Singapore MOE Tier 2 grant (MOE-T2EP10220-0001) and the Singapore National Research Foundation under its Campus for Research Excellence and Technological Enterprise (CREATE) programme

Antiferromagnetic Inverse Spinel Oxide LiCoVO 4

Exploring highly efficient catalysts for the oxygen evolution reaction (OER) is essential for water electrolysis. Cost-effective transition-metal oxides with reasonable activity are raising attention. Recently, OER reactants' and products' differing spin configurations have been thought to cause slow reaction kinetics. Catalysts with magnetically polarized channels could selectively remove electrons with opposite magnetic moment and conserve overall spin during OER, enhancing triplet state oxygen molecule evolution. Herein, antiferromagnetic inverse spinel oxide LiCoVO4 is found to contain d7 Co2+ ions that can be stabilized under active octahedral sites, possessing high spin states S = 3/2 (t2g 5 eg 2 ). With high spin configuration, each Co2+ ion has an ideal magnetic moment of 3 µB , allowing the edge-shared Co2+ octahedra in spinel to be magnetically polarized. Density functional theory simulation results show that the layered antiferromagnetic LiCoVO4 studied contains magnetically polarized channels. The average magnetic moment (µave ) per transition-metal atom in the spin conduction channel is around 2.66 µB . Such channels are able to enhance the selective removal of spin-oriented electrons from the reactants during the OER, which facilitates the accumulation of appropriate magnetic moments for triplet oxygen molecule evolution. In addition, the LiCoVO4 reported has been identified as an oxide catalyst with excellent OER activity.Ministry of Education (MOE).R.C. and Y.S. contributed equally to this work. This work was supported by the Singapore Ministry of Education Tier 2 Grant (MOE2017-T2-1-009) and Tier 1 Grant (RG3/18 (S)