1,534 research outputs found
Spectral, mineralogical, and geochemical variations across Home Plate, Gusev Crater, Mars indicate high and low temperature alteration
Over the last ~ 3 years in Gusev Crater, Mars, the Spirit rover observed coherent variations in color, mineralogy, and geochemistry across Home Plate, an ~ 80 m-diameter outcrop of basaltic tephra. Observations of Home Plate from orbit and from the summit of Husband Hill reveal clear differences in visible/near-infrared (VNIR) colors between its eastern and western regions that are consistent with mineralogical compositions indicated by Mössbauer spectrometer (MB) and by Miniature Thermal Emission Spectrometer (Mini-TES). Pyroxene and magnetite dominate the east side, while olivine, nanophase Fe oxide (npOx) and glass are more abundant on the western side. Alpha Particle X-Ray Spectrometer (APXS) observations reveal that eastern Home Plate has higher Si/Mg, Al, Zn, Ni, and K, while Cl and Br are higher in the west. We propose that these variations are the result of two distinct alteration regimes that may or may not be temporally related: a localized, higher temperature recrystallization and alteration of the east side of Home Plate and lower temperature alteration of the western side that produced npOx
Mineralogy and chemistry of altered Icelandic basalts: Application to clay mineral detection and understanding aqueous environments on Mars
We used a suite of techniques, including those emulating compositional data sets obtained from Mars orbit and obtainable at the Mars surface, to examine aqueous alteration of basaltic rocks from Iceland as a mineralogic and geochemical analog for Noachian environments on Mars. A sample suite was collected for laboratory measurement of (1) whole-rock visible/near-infrared (VNIR) reflectance and thermal infrared (TIR) emission spectra; (2) VNIR and TIR reflectance spectra of particle-size separates derived from the bulk rock and from materials extracted from fractures/vesicles; (3) X-ray diffraction (XRD) patterns for determination of quantitative modal mineralogy; (4) major element chemistry using flux fusion of whole-rock powders; and (5) electron microprobe analyses of minerals in thin sections. Conclusions about aqueous alteration can be influenced by technique. For these basalts, whole-rock chemical data showed scant evidence for chemical fractionation, but TIR, VNIR, and XRD measurements identified distinctive assemblages of hydrous silicate minerals, differing by sample. XRD provided the most complete and accurate quantitative determination of sample mineralogy. However, VNIR spectroscopy was the technique most useful for determining composition of low-abundance smectite clays, and TIR spectroscopy was the most useful for recognizing hydrated silicates in thin surface coatings. High spatial resolution mineralogical and chemical data sets were useful for understanding the texture and distribution of alteration products and variations in fluid chemistry. No single approach provides a complete assessment of the environment of alteration, demonstrating the importance of employing multiple, synergistic mineralogical and geochemical techniques and instruments in exploration of rock strata from aqueous paleoenvironments on Mars
Evidence for a Noachian-Aged Ephemeral Lake in Gusev Crater, Mars
Gusev crater was selected as the landing site for the Spirit rover because of the likelihood that it contained an ancient lake. Although outcrops rich in Mg-Fe carbonate dubbed Comanche were discovered in the Noachian-aged Columbia Hills, they were inferred to result from volcanic hydrothermal activity. Spirit encountered other mineral and chemical indicators of aqueous activity, but none was recognized as definitive evidence for a former lake in part because none was associated with obvious lacustrine sedimentary deposits. However, water discharge into Martian crater basins like Gusev may have been episodic, producing only small amounts of sediment and shallow ephemeral lakes. Evaporative precipitation from such water bodies has been suggested as a way of producing the Mg- and Fe-rich carbonates found in ALH84001 and carbonates and salts in some nakhlites a hypothesis we examine for the Comanche carbonate
Quantifying the Complete Mineral Assemblages in Rocks of GUSEV Crater, Mars
Determining the complete mineralogy of Mars rocks by remote sensing has remained a challenge, because of inherent limitations in the minerals that can be detected and uncertainties in spectral modeling. A subset of the igneous rocks of Gusev crater provide a unique opportunity to determine modal mineralogy, because of limited alteration and the analytical capabilities of the Athena instrument package. Here we estimate the absolute (wt. %) abundances of Fe-bearing minerals from Moessbauer spectra (previously reported only as "areas for component subspectra"), and compare these results to the normative mineralogy calculated from APXS elemental analyses. We also test our preferred mineralogy by comparison of Mini-TES spectra with synthetic thermal emission spectra
Profiling the interface electron gas of LaAlO3/SrTiO3 heterostructures by hard X-ray photoelectron spectroscopy
The conducting interface of LaAlO/SrTiO heterostructures has been
studied by hard X-ray photoelectron spectroscopy. From the Ti~2 signal and
its angle-dependence we derive that the thickness of the electron gas is much
smaller than the probing depth of 4 nm and that the carrier densities vary with
increasing number of LaAlO overlayers. Our results point to an electronic
reconstruction in the LaAlO overlayer as the driving mechanism for the
conducting interface and corroborate the recent interpretation of the
superconducting ground state as being of the Berezinskii-Kosterlitz-Thouless
type.Comment: 4 pages, 4 figure
Two-Spinon and Orbital Excitations of the Spin-Peierls System TiOCl
We combine high-resolution resonant inelastic x-ray scattering with cluster
calculations utilizing a recently derived effective magnetic scattering
operator to analyze the polarization, excitation energy, and momentum dependent
excitation spectrum of the low-dimensional quantum magnet TiOCl in the range
expected for orbital and magnetic excitations (0 - 2.5 eV). Ti 3d orbital
excitations yield complete information on the temperature-dependent
crystal-field splitting. In the spin-Peierls phase we observe a dispersive
two-spinon excitation and estimate the inter- and intra-dimer magnetic exchange
coupling from a comparison to cluster calculations
Absence of anomalous negative lattice-expansion for polycrystalline sample of Tb2Ti2O7
High resolution X-ray powder-diffraction experiments on a well-characterized
polycrystalline sample of the spin liquid Tb2Ti2O7 reveal that it shows normal
positive thermal-expansion above 4 K, which does not agree with the intriguing
anomalous negative thermal-expansion due to a magneto-elastic coupling reported
for a single crystal sample below 20 K. We also performed a Rietveld profile
refinement of a powder-diffraction pattern taken at a room temperature, and
confirmed that it is consistent with the fully ordered cubic pyrochlore
structure.Comment: 2 pages, 3 figure
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