34 research outputs found
Measuring monetary policy and its impact on the bond market of an emerging economy
In view of multiple instruments used by many central banks in emerging market economies, we derive a composite measure of monetary policy for India and assess its impact on the yield curve. Our results show that while monetary policy has the dominant impact among macroeconomic variables on the entire term structure, it is particularly strong at the shorter end and on credit spreads. Shifts in the level of the government yield curve and credit spreads also lead to changes in monetary policy. In terms of robustness, our measure performs better than a narrative based measure of monetary policy available in the literature
Measuring monetary policy and its impact on the bond market of an emerging economy
In view of multiple instruments used by many central banks in emerging market economies, we derive a composite measure of monetary policy for India and assess its impact on the yield curve. Our results show that while monetary policy has the dominant impact among macroeconomic variables on the entire term structure, it is particularly strong at the shorter end and on credit spreads. Shifts in the level of the government yield curve and credit spreads also lead to changes in monetary policy. In terms of robustness, our measure performs better than a narrative based measure of monetary policy available in the literature
Equation of State of Fluid Methane from First Principles with Machine Learning Potentials.
The predictive simulation of molecular liquids requires potential energy surface (PES) models that are not only accurate but also computationally efficient enough to handle the large systems and long time scales required for reliable prediction of macroscopic properties. We present a new approach to the systematic approximation of the first-principles PES of molecular liquids using the GAP (Gaussian Approximation Potential) framework. The approach allows us to create potentials at several different levels of accuracy in reproducing the true PES and thus to determine the level of quantum chemistry that is necessary to accurately predict macroscopic properties. We test the approach by building a series of many-body potentials for liquid methane (CH4), which is difficult to model from first principles because its behavior is dominated by weak dispersion interactions with a significant many-body component. The increasing accuracy of the potentials in predicting the bulk density correlates with their fidelity to the true PES, whereas the trend with the empirical potentials tested is surprisingly the opposite. We conclude that an accurate, consistent prediction of its bulk density across wide ranges of temperature and pressure requires not only many-body dispersion but also quantum nuclear effects to be modeled accurately
An alternate model for magnetization plateaus in the molecular magnet V_15
Starting from an antiferromagnetic Heisenberg Hamiltonian for the fifteen
spin-1/2 ions in V_15, we construct an effective spin Hamiltonian involving
eight low-lying states (spin-1/2 and spin-3/2) coupled to a phonon bath. We
numerically solve the time-dependent Schrodinger equation of this system, and
obtain the magnetization as a function of temperature in a time-dependent
magnetic field. The magnetization exhibits unusual patterns of hysteresis and
plateaus as the field sweep rate and temperature are varied. The observed
plateaus are not due to quantum tunneling but are a result of thermal
averaging. Our results are in good agreement with recent experimental
observations.Comment: Revtex, 4 pages, 5 eps figure
Properties of a mixed-valent iron compound with the kagomélattice
An organically templated iron sulfate of the formula [HN(CH2)6NH][FeIIIFe2IIF6(SO4)2]·[H3O] possessing the kagomé lattice has been prepared and characterized by single-crystal crystallography and other techniques. This mixed-valent iron compound shows complex magnetic properties including spin-glass behavior and magnetic hysteresis. The low-temperature specific heat data show deviation from the T2 behavior found in two-dimensional frustrated systems. Simple calculations have been carried out to understand the properties of this kagomé compound
Properties of low-lying states in some high-nuclearity Mn, Fe and V clusters: Exact studies of Heisenberg models
Using an efficient numerical scheme that exploits spatial symmetries and spin
parity, we have obtained the exact low-lying eigenstates of exchange
Hamiltonians for the high nuclearity spin clusters, Mn_{12}, Fe_8 and V_{15}.
The largest calculation involves the Mn_{12} cluster which spans a Fock space
of a hundred million. Our results show that the earlier estimates of the
exchange constants need to be revised for the Mn_{12} cluster to explain the
level ordering of low-lying eigenstates. In the case of the Fe_8 cluster,
correct level ordering can be obtained which is consistent with the exchange
constants for the already known clusters with butterfly structure. In the
V_{15} cluster, we obtain an effective Hamiltonian that reproduces exactly, the
eight low-lying eigenvalues of the full Hamiltonian.Comment: Revtex, 12 pages, 16 eps figures; this is the final published versio
Exchange Interaction in Binuclear Complexes with Rare Earth and Copper Ions: A Many-Body Model Study
We have used a many-body model Hamiltonian to study the nature of the
magnetic ground state of hetero-binuclear complexes involving rare-earth and
copper ions. We have taken into account all diagonal repulsions involving the
rare-earth 4f and 5d orbitals and the copper 3d orbital. Besides, we have
included direct exchange interaction, crystal field splitting of the rare-earth
atomic levels and spin-orbit interaction in the 4f orbitals. We have identified
the inter-orbital repulsion, U and crystal field parameter,
as the key parameters involved in controlling the type of exchange
interaction between the rare earth and copper 3d spins. We have explored
the nature of the ground state in the parameter space of U, ,
spin-orbit interaction strength and the filling n. We find
that these systems show low-spin or high-spin ground state depending on the
filling of the levels of the rare-earth ion and ground state spin is
critically dependent on U and . In case of half-filling
(Gd(III)) we find a reentrant low-spin state as U is increased, for
small values of , which explains the recently reported apparent
anomalous anti-ferromagnetic behaviour of Gd(III)-radical complexes. By varying
U we also observe a switch over in the ground state spin for other
fillings . We have introduced a spin-orbit coupling scheme which goes beyond
L-S or j-j coupling scheme and we find that spin-orbit coupling does not
significantly alter the basic picture.Comment: 22 pages, 11 ps figure