Vibrational state dependence of ionic rotational branching ratios in resonance enhanced multiphoton ionization of CH

We show that rapid evolution of a Rydberg orbital with internuclear distance in a resonance enhanced multiphoton ionization (REMPI) process can have a profound influence on the production of molecular ions in alternative rotational states. This is illustrated by calculations of ionic rotational branching ratios for (2+1′) REMPI via the O11 (20.5) branch of the E′ ^2Σ^+(3pσ) Rydberg state of CH. The rotational propensity rule for ionization changes from ΔN=odd (ΔN=N_+−N_i) at lower vibrational excitation, as expected from the ΔN+l=odd selection rule, to ΔN=even at higher vibrational levels. This effect is expected to be quite general and should be most readily observable in diatomic hydrides

Contextuality under weak assumptions

The presence of contextuality in quantum theory was first highlighted by Bell, Kochen and Specker, who discovered that for quantum systems of three or more dimensions, measurements could not be viewed as deterministically revealing pre-existing properties of the system. More precisely, no model can assign deterministic outcomes to the projectors of a quantum measurement in a way that depends only on the projector and not the context (the full set of projectors) in which it appeared, despite the fact that the Born rule probabilities associated with projectors are independent of the context. A more general, operational definition of contextuality introduced by Spekkens, which we will term "probabilistic contextuality", drops the assumption of determinism and allows for operations other than measurements to be considered contextual. Even two-dimensional quantum mechanics can be shown to be contextual under this generalised notion. Probabilistic noncontextuality represents the postulate that elements of an operational theory that cannot be distinguished from each other based on the statistics of arbitrarily many repeated experiments (they give rise to the same operational probabilities) are ontologically identical. In this paper, we introduce a framework that enables us to distinguish between different noncontextuality assumptions in terms of the relationships between the ontological representations of objects in the theory given a certain relation between their operational representations. This framework can be used to motivate and define a "possibilistic" analogue, encapsulating the idea that elements of an operational theory that cannot be unambiguously distinguished operationally can also not be unambiguously distinguished ontologically. We then prove that possibilistic noncontextuality is equivalent to an alternative notion of noncontextuality proposed by Hardy. Finally, we demonstrate that these weaker noncontextuality assumptions are sufficient to prove alternative versions of known "no-go" theorems that constrain ψ-epistemic models for quantum mechanics

Children's opinions on effective strategies to cope with bullying: the importance of bullying role and perspective

In order to find out what children would suggest as useful interventions to stop bullying, we designed a questionnaire administered to 311 children (155 boys and 156 girls; mean age = 11 years). Thirty-six items were employed to ask children how effective, in their opinion, retaliation, nonchalance and assertiveness could be in stopping bullying. Items were presented to children from three different perspectives (imagine you are the victim, the bully or a witness). We used peer reports to assess children's role in bullying. Children were grouped into bullies, followers of the bully, defenders of the victims, outsiders, victims and those not involved. The strategy most frequently chosen by all children was to cope with bullying through assertiveness. Bullies considered retaliation effective more often than their classmates, especially when they adopted the perspective of the victim or witness. Bullies did not consider assertive strategies as efficient in stopping the bully. Defenders, outsiders, victims and children not involved, on the other hand, were very much in favour of strategies aimed at solving the conflict through nonchalance or assertiveness, especially when they imagined being the bully. Girls chose assertive strategies more often than boys and younger children preferred nonchalance more often than older children, who tended to choose retaliation more often. Suggestions for intervention are made. © 2005 NFER

The effects of the exhaust plume on the lightning triggering conditions for launch vehicles

Apollo 12 and Atlas Centaur 67 are two launch vehicles that have experienced triggered lightning strikes. Serious consequences resulted from the events; in the case of Atlas Centaur 67, the vehicle and the payload were lost. These events indicate that it is necessary to develop launch rules which would prevent such occurrences. In order to develop valid lightning related rules, it is necessary to understand the effects of the plume. Some have assumed that the plume can be treated as a perfect conductor, and have computed electric field enhancement factors on that basis. The authors have looked at the plume, and believe that these models are not correct, because they ignore the fluid motion of the conducting plates. The authors developed a model which includes this flow character. In this model, the external field is excluded from the plume as it would be for any good conductor, but, in addition, the charge must distribute so that the charge density is zero at some location in the exhaust. When this condition is included in the calculation of triggering enhancement factors, they can be two to three times larger than calculated by other methods which include a conductive plume but don't include the correct boundary conditions. Here, the authors review the relevant features of rocket exhausts for the triggered lightning problem, present an approach for including flowing conductive gases, and present preliminary calculations to demonstrate the effect that the plume has on enhancement factors

Boson Sampling from Gaussian States

We pose a generalized Boson Sampling problem. Strong evidence exists that such a problem becomes intractable on a classical computer as a function of the number of Bosons. We describe a quantum optical processor that can solve this problem efficiently based on Gaussian input states, a linear optical network and non-adaptive photon counting measurements. All the elements required to build such a processor currently exist. The demonstration of such a device would provide the first empirical evidence that quantum computers can indeed outperform classical computers and could lead to applications

Pituophis ruthveni

Number of Pages: 16Geological SciencesIntegrative Biolog