Liquid-liquid coexistence in the phase diagram of a fluid confined in fractal porous materials

Multicanonical ensemble sampling simulations have been performed to calculate the phase diagram of a Lennard-Jones fluid embedded in a fractal random matrix generated through diffusion limited cluster aggregation. The study of the system at increasing size and constant porosity shows that the results are independent from the matrix realization but not from the size effects. A gas-liquid transition shifted with respect to bulk is found. On growing the size of the system on the high density side of the gas-liquid coexistence curve it appears a second coexistence region between two liquid phases. These two phases are characterized by a different behaviour of the local density inside the interconnected porous structure at the same temperature and chemical potential.Comment: 5 pages, 4 figures. To be published in Europhys. Letter

Crowdsourcing in the Quaternary sea level community: insights from the Pliocene

In order to establish the ‘fingerprint’ of past sea level changes, many field measurements of paleo sea level from globally distributed locations are needed. It is because this problem requires a geographically expansive database that it becomes an ideal candidate for crowdsourcing techniques. In order to crowdsource sea level data from the Mid-Pliocene Warm Period, we developed three tools: PlioWiki, RSLcalc and RSLmap. PlioWiki is a web portal, open to contributions, where investigators can share knowledge on Pliocene to Quaternary relative sea levels. RSLcalc is a standardized, ready-to-use tool for field geologists to log their own sea level field observations and, if they desire, submit new data to an open access database of relative sea level markers. RSLmap allows one to visualize and query the database built with RSLcalc on a Google Map interface. Here we describe these tools and discuss the advantages of crowdsourcing, relative to traditional approaches, for the creation of sea level databases for any time period

Thermodynamic behaviour and structural properties of an aqueous sodium chloride solution upon supercooling

We present the results of a molecular dynamics simulation study of thermodynamic and structural properties upon supercooling of a low concentration sodium chloride solution in TIP4P water and the comparison with the corresponding bulk quantities. We study the isotherms and the isochores for both the aqueous solution and bulk water. The comparison of the phase diagrams shows that thermodynamic properties of the solution are not merely shifted with respect to the bulk. Moreover, from the analysis of the thermodynamic curves, both the spinodal line and the temperatures of maximum density curve can be calculated. The spinodal line appears not to be influenced by the presence of ions at the chosen concentration, while the temperatures of maximum density curve displays both a mild shift in temperature and a shape modification with respect to bulk. Signatures of the presence of a liquid-liquid critical point are found in the aqueous solution. By analysing the water-ion radial distribution functions of the aqueous solution we observe that upon changing density, structural modifications appear close to the spinodal. For low temperatures additional modifications appear also for densities close to that corresponding to a low density configurational energy minimum.Comment: 10 pages, 13 figures, 2 tables. To be published in J. Chem. Phy

Assessment of radiative heating errors in Tropical Atmosphere Ocean array marine air temperature measurements

We assess the radiative heating error affecting marine air temperature (MAT) measurements in the Tropical Atmosphere Ocean array. The error in historical observations is found to be ubiquitous across the array, spatially variable and approximately stationary in time. The error induces spurious warming during daytime hours, but does not affect night-time temperatures. The range encompassing the real, unknown daily- and monthly-mean values is determined using daytime and night-time mean temperatures as upper and lower limits. The uncertainty in MAT is less than or equal to 0.5 °C and 0.2 °C for 95% of daily and monthly estimates, respectively. Uncertainties impact surface turbulent heat flux estimates, with potentially significant influences on the quantification of coupled ocean-atmosphere processes

On the interchangeability of sea-surface and near-surface air temperature anomalies in climatologies

On global and hemispheric scales, sea-surface temperature (SST) anomalies are assumed to be good surrogates for near-surface marine air temperature (MAT) anomalies. In fact, global gridded temperature datasets commonly blend SST and near-surface air temperature anomalies to overcome the lack of geographically homogeneous and reliable MAT observations. Here, we show that SST and MAT anomalies differ regarding crucial statistical properties such as multiannual trends and probabilistic distributions of daily and monthly averages. We provide evidence of the lack of interchangeability from an array of moored buoys in the tropical Pacific Ocean. We identify statistically significant discrepancies between SST and MAT anomalies for single as well as groups of such buoys. Thus, caution is required when characterizing and interpreting MAT variability through SST observations, especially at shorter than decadal timescale

Stretched exponential relaxation in a diffusive lattice model

We studied the single dimer dynamics in a lattice diffusive model as a function of particle density in the high densification regime. The mean square displacement is found to be subdiffusive both in one and two dimensions. The spatial dependence of the self part of the van Hove correlation function displays as function of $r$ a single peak and signals a dramatic slow down of the system for high density. The self intermediate scattering function is fitted to the Kohlrausch-Williams-Watts law. The exponent $\beta$ extracted from the fits is density independent while the relaxation time $\tau$ follows a scaling law with an exponent 2.5.Comment: 5 pages, 3 figures, to be published in Phys. Rev.

The Mid-Pliocene sea-level conundrum: Glacial isostasy, eustasy and dynamic topography

Determining eustatic sea level during the Mid-Pliocene warm period (~ 3.3 to 2.9 Ma) has been a central but elusive goal in the study of past warm climates. Estimates of eustatic sea level based on geologic data span a broad range; variation that we now recognize is due in part to geographically varying post-depositional displacement caused by glacial isostatic adjustment and dynamic topography. In this study, we combine field observations and glacial isostatic adjustment modeling to estimate the dynamic topography signal in three areas that are important to paleo-sea level studies of the Mid-Pliocene warm period (South Africa, West Australia and southeastern United States). We show that dynamic topography played a significant role in the post-depositional displacement of Pliocene, and even younger Pleistocene, shorelines. In this regard, we provide a robust paleo-sea level elevation data set, corrected for glacial isostatic adjustment, that can be used to evaluate predictions from mantle flow models of dynamic topography

Tides in the Last Interglacial: insights from notch geometry and palaeo tidal models in Bonaire, Netherland Antilles

The study of past sea levels relies largely on the interpretation of sea-level indicators. Palaeo tidal notches are considered as one of the most precise sea-level indicators as their formation is closely tied to the local tidal range. We present geometric measurements of modern and palaeo (Marine Isotope Stage (MIS) 5e) tidal notches on Bonaire (southern Caribbean Sea) and results from two tidal simulations, using the present-day bathymetry and a palaeo-bathymetry. We use these two tools to investigate changes in the tidal range since MIS 5e. Our models show that the tidal range changes most significantly in shallow areas, whereas both, notch geometry and models results, suggest that steeper continental shelves, such as the ones bordering the island of Bonaire, are less affected to changes in tidal range in conditions of MIS 5e sea levels. We use our data and results to discuss the importance of considering changes in tidal range while reconstructing MIS 5e sea level histories, and we remark that it is possible to use hydrodynamic modelling and notch geometry as first-order proxies to assess whether, in a particular area, tidal range might have been different in MIS 5e with respect to today