Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode

Anionic redox reaction (ARR) in lithium- and sodium-ion batteries is under hot discussion, mainly regarding how oxygen anion participates and to what extent oxygen can be reversibly oxidized and reduced. Here, a P3-type Na0.6[Li0.2Mn0.8]O2 with reversible capacity from pure ARR was studied. The interlayer O-O distance (peroxo-like O-O dimer, 2.506(3) Å), associated with oxidization of oxygen anions, was directly detected by using a neutron total scattering technique. Different from Li2RuO3 or Li2IrO3 with strong metal-oxygen (M-O) bonding, for P3-type Na0.6[Li0.2Mn0.8]O2 with relatively weak Mn-O covalent bonding, crystal structure factors might play an even more important role in stabilizing the oxidized species, as both Li and Mn ions are immobile in the structure and thus may inhibit the irreversible transformation of the oxidized species to O2 gas. Utilization of anionic redox reaction (ARR) on oxygen has been considered as an effective way to promote the charge-discharge capacity of the layered oxide cathodes for lithium- or sodium-ion batteries. The detailed mechanism of ARR, in particular how crystal structure affects and coordinates with the ARR, is not yet well understood. In the present work, a combination of X-ray and neutron total scattering measurements has been performed to study the structure of the prototype P3-type layered Na0.6[Li0.2Mn0.8]O2 with pure ARR. Unique structural characteristics, rather than prevailing knowledge of covalency of metal-oxygen, enable the stabilization of the crystal structure of Na0.6[Li0.2Mn0.8]O2 along with the ARR. This work suggests that reversible ARR can be manipulated by proper structure designs, thus to achieve high lithium or sodium storage in layered oxide cathodes. For P3-type Na0.6[Li0.2Mn0.8]O2 with relatively weak Mn-O covalent bonding, crystal structure factors play an important role in stabilizing the oxidized species, inhibiting the irreversible transformation of the oxidized species to O2 gas. The finding is important for better design of layered oxide positive materials with higher reversible capacity via the introduction of a reversible anionic redox reaction

A Unified Approach to the Classical Statistical Analysis of Small Signals

We give a classical confidence belt construction which unifies the treatment of upper confidence limits for null results and two-sided confidence intervals for non-null results. The unified treatment solves a problem (apparently not previously recognized) that the choice of upper limit or two-sided intervals leads to intervals which are not confidence intervals if the choice is based on the data. We apply the construction to two related problems which have recently been a battle-ground between classical and Bayesian statistics: Poisson processes with background, and Gaussian errors with a bounded physical region. In contrast with the usual classical construction for upper limits, our construction avoids unphysical confidence intervals. In contrast with some popular Bayesian intervals, our intervals eliminate conservatism (frequentist coverage greater than the stated confidence) in the Gaussian case and reduce it to a level dictated by discreteness in the Poisson case. We generalize the method in order to apply it to analysis of experiments searching for neutrino oscillations. We show that this technique both gives correct coverage and is powerful, while other classical techniques that have been used by neutrino oscillation search experiments fail one or both of these criteria.Comment: 40 pages, 15 figures. Changes 15-Dec-99 to agree more closely with published version. A few small changes, plus the two substantive changes we made in proof back in 1998: 1) The definition of "sensitivity" in Sec. V(C). It was inconsistent with our actual definition in Sec. VI. 2) "Note added in proof" at end of the Conclusio

Observation of Y(2175) in J/ψ→ηϕf0(980)J/\psi\to \eta\phi f_0(980)

The decays of $J/\psi\to \eta\phi f_0(980) (\eta\to \gamma\gamma, \phi \to K^+K^-, f_0(980)\to\pi^+\pi^-)$ are analyzed using a sample of $5.8 \times 10^{7}$ $J/\psi$ events collected with the BESII detector at the Beijing Electron-Positron Collider (BEPC). A structure at around $2.18$GeV/$c^2$ with about $5\sigma$ significance is observed in the $\phi f_0(980)$ invariant mass spectrum. A fit with a Breit-Wigner function gives the peak mass and width of $m=2.186\pm 0.010 (stat)\pm 0.006 (syst)$GeV/$c^2$ and $\Gamma=0.065\pm 0.023 (stat)\pm 0.017 (syst)$GeV/$c^2$, respectively, that are consistent with those of Y(2175), observed by the BABAR collaboration in the initial-state radiation (ISR) process $e^+e^-\to\gamma_{ISR}\phi f_0(980)$. The production branching ratio is determined to be $Br(J/\psi\to\eta Y(2175))\cdot Br(Y(2175)\to\phi f_0(980))\cdot Br(f_0(980)\to\pi^+\pi^-)=(3.23\pm 0.75 (stat)\pm0.73 (syst))\times 10^{-4}$, assuming that the Y(2175) is a $1^{--}$ state.Comment: 5 pages, 4 figures, accepted by Phys. Rev. Let

Measurement of the branching fractions of psi(2S) -> 3(pi+pi-) and J/psi -> 2(pi+pi-)

Using data samples collected at sqrt(s) = 3.686GeV and 3.650GeV by the BESII detector at the BEPC, the branching fraction of psi(2S) -> 3(pi+pi-) is measured to be [4.83 +- 0.38(stat) +- 0.69(syst)] x 10^-4, and the relative branching fraction of J/psi -> 2(pi+pi-) to that of J/psi -> mu+mu- is measured to be [5.86 +- 0.19(stat) +- 0.39(syst)]% via psi(2S) -> (pi+pi-)J/psi, J/psi -> 2(pi+pi-). The electromagnetic form factor of 3(pi+pi-) is determined to be 0.21 +- 0.02 and 0.20 +- 0.01 at sqrt(s) = 3.686GeV and 3.650GeV, respectively.Comment: 17pages, 7 figures, submitted to Phys. Rev.

Measurement of the chi_{c2} Polarization in psi(2S) to gamma chi_{c2}

The polarization of the chi_{c2} produced in psi(2S) decays into gamma chi_{c2} is measured using a sample of 14*10^6 psi(2S) events collected by BESII at the BEPC. A fit to the chi_{c2} production and decay angular distributions in psi(2S) to gamma chi_{c2}, chi_{c2} to pi pi and KK yields values x=A_1/A_0=2.08+/-0.44 and y=A_2/A_0=3.03 +/-0.66, with a correlation rho=0.92 between them, where A_{0,1,2} are the chi_{c2} helicity amplitudes. The measurement agrees with a pure E1 transition, and M2 and E3 contributions do not differ significantly from zero.Comment: 6 pages, 4 figures, 1 tabl

Measurement of \psip Radiative Decays

Using 14 million psi(2S) events accumulated at the BESII detector, we report first measurements of branching fractions or upper limits for psi(2S) decays into gamma ppbar, gamma 2(pi^+pi^-), gamma K_s K^-pi^++c.c., gamma K^+ K^- pi^+pi^-, gamma K^{*0} K^- pi^+ +c.c., gamma K^{*0}\bar K^{*0}, gamma pi^+pi^- p pbar, gamma 2(K^+K^-), gamma 3(pi^+pi^-), and gamma 2(pi^+pi^-)K^+K^- with the invariant mass of hadrons below 2.9GeV/c^2. We also report branching fractions of psi(2S) decays into 2(pi^+pi^-) pi^0, omega pi^+pi^-, omega f_2(1270), b_1^\pm pi^\mp, and pi^0 2(pi^+pi^-) K^+K^-.Comment: 5 pages, 4 figure

Measurement of the cross section for e^+e^- -> ppbar at center-of-mass energies from 2.0 to 3.07 GeV

Cross sections for e^+e^- -> ppbar have been measured at 10 center-of-mass energies from 2.0 to 3.07 GeV by the BESII experiment at the BEPC, and proton electromagnetic form factors in the time-like region have been determined.Comment: 6 pages, 3 figure

Partial Wave Analysis of χc0→π+π−K+K−\chi_{c0}\to\pi^+\pi^-K^+K^-

A partial wave analysis of $\chi_{c0}\to\pi^+\pi^-K^+K^-$ in $\psi(2S)\to\gamma\chi_{c0}$ decay is presented using a sample of 14 million $\psi(2S)$ events accumulated by the BES II detector. The data are fitted to the sum of relativistic covariant tensor amplitudes for intermediate resonant decay modes. From the fit, significant contributions to $\chi_{c0}$ decays from the channels $f_0(980)f_0(980)$, $f_0(980)f_0(2200)$, $f_0(1370)f_0(1710)$, $K^*(892)^0\bar K^*(892)^0$, $K^*_0(1430)\bar K^*_0(1430)$, $K^*_0(1430)\bar K^*_2(1430) + c.c.$, and $K_1(1270)K$ are found. Flavor-SU(3)-violating $K_1(1270)-K_1(1400)$ asymmetry is observed. Values obtained for the masses and widths of the resonances $f_0(1710)$, $f_0(2200)$, $f_0(1370)$, and $K^*_0(1430)$ are presented.Comment: 16 pages, 9 figures, and 4 table

Measurements of J/psi decays into phi pi^0, phi eta, and phi eta^prime

Based on 5.8x10^7 J/psi events detected in BESII, the branching fractions of J/psi--> phi eta and phi eta^prime are measured for different eta and eta^prime decay modes. The results are significantly higher than previous measurements. An upper limit on B(J/psi--> phi pi^0) is also obtained.Comment: 9 pages, 10 figure