Influence of SiO2, TiO2 and Fe2O3 nanoparticles on the properties of fly ash blended cement mortars

This study explores the effects of different types of nanoparticles, namely nano-SiO2 (NS), nano-TiO2 (NT), and nano-Fe2O3 (NF) on the fresh properties, mechanical properties, and microstructure of cement mortar containing fly ash as a supplementary cementitious material. These nanoparticles existed in powder form and were incorporated into the mortar at the dosages of 1%, 3%, and 5% wt.% of cement. Also, fly ash has been added into in mortars with a constant dosage of 30% wt.% of cement. Compressive and flexural strength tests were performed to evaluate the mechanical properties of the mortar specimens with different nanoparticles at three curing ages, 7, 14, and 28 days. Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) tests were conducted to study the microstructure and the hydration products of the mortars. To elucidate the effects of nanoparticles on the binder phase, additional experiments were performed on accompanying cement pastes: nanoindentation and open porosity measurements. The study shows that, if added in appropriate amounts, all nanoparticles investigated can result in significantly improved mechanical properties compared to the reference materials. However, exceeding of the optimal concentration results in clustering of the nanoparticles and reduces the mechanical properties of the composites, which is accompanied with increasing the porosity. This study provides guidelines for further improvement of concretes with blended cements through use of nanoparticles

Assessment of the self-healing capacity of cementitious materials through active thin sections

Since self-healing of cementitious materials can theoretically improve the service-life of concrete structures, it has gathered significant attention from both researchers and industry during the last two decades. Many researchers have proposed different methods to assess and quantify the self-healing capacity (i.e. the ability of cementitious materials to heal cracks) that is generated in concrete autogenously as well as autonomously. Even though many methodologies can be found in the literature, a way to accurately quantify the healing products produced by any self-healing mechanism has not been yet achieved. In this study, a methodology is proposed to observe and to quantify in-time formation of healing products based on active thin sections. Thin sections of Portland cement paste have been prepared with no epoxy impregnation to facilitate reactions between the cement matrix and the surrounding environment. Artificial cracks (260 μm wide) were induced at 28 days of age and the crystal growth was continuously monitored up to 28 days of self-healing. Through image analysis of the micrographs, it was calculated that the autogenous self-healing capacity of paste (triggered by portlandite carbonation in uncontrolled indoor conditions) was around 55% after 28 days of self-healing. Healing products were further characterised through Environmental Scanning Electron Microscope analysis. Based on the results obtained in this study, the proposed methodology seems to be promising to compare the self-healing mechanisms triggered by different healing agents.Materials and Environmen

Modelling of capillary water absorption in sound and cracked concrete using a dual-lattice approach: Computational aspects

Lattice models have been used to simulate mass transport to predict durability of cementitious materials. In particular, the use of dual lattice meshes allows for the coupling of fracture and transport processes, which commonly occur at the same time in these materials. Literature has shown good agreement between simulations and experimental results. Nevertheless, work regarding relevant computational aspects of the numerical model are scarce. In this study, a Voronoi-discretized lattice model is used to simulate unsaturated moisture transport in cement-base materials through the Richards equation. First, investigations regarding the choice of elemental volume approximation, time-stepping procedure and quadrature are evaluated. After validation of the approximations, simulated moisture transport in sound concrete was compared to experiments and mesh and time step sensitivity were discussed. A new approach to model capillary absorption of water in cracked concrete was also proposed and its advantages with respect to existing approaches are discussed by comparing to experimental measurements. The results confirm that the model can accurately predict the transport processes for the earlier stage of capillary absorption. Furthermore, moisture ingress in cracked concrete is simulated for different crack configurations and the use of different approaches is suggested accordingly. Finally, guidelines regarding the approximations used for optimization of the computations are presented.Applied MechanicsMaterials and EnvironmentMaterials- Mechanics- Management & Desig

Induction healing of concrete reinforced by bitumen-coated steel fibres

Cracking in concrete structures compromises the durability and functionality of the structures themselves. Different kinds of self-healing concretes, less or more sophisticated, have been developed in the past ten years to overcome early cracks in structures. An experimental study of a novel self-healing concrete is presented. Bitumen, used as the healing agent, is introduced in fresh fibre-reinforced concrete as the coating of steel fibres. The mechanism exploits induction energy to heat up the steel fibres inside the cracked concrete matrix; the bitumen then melts and finally flows into the cracks, sealing them. The aim of the research is to set up the main parameter affecting the performance of the healing mechanism as well as its efficiency. In order to achieve this goal, the microstructure of healed specimens has been studied through Light Microscope. Mechanical behaviour and permeability of the samples, before and after healing, were also checked. Fiber content is studied in the paper amongst the many parameters affecting the mechanism. Results point out the potential of the proposed self-healing mechanism to contrast early cracking (i.e. due to shrinkage). Presence of a certain amount of fibres bridging the crack highly influenced the healing efficiency, and so a uniform distribution inside the concrete matrix, which was directly related to fibre amount and its optimum concrete matrix.Materials and Environmen

Modeling water absorption in cement-based composites with SAP additions

The ability of Superabsorbent Polymers (SAP) to block water flow along cracks in cement-based materials has become an attractive feature of these admixtures. The diminution of fl w rates in such composites are attributed to the capacity of the SAPs to absorb water and swell in the crack, but no evidence exists in literature that indicates one or the other cause. On the other hand, the SAPs present in the bulk matrix might act as distributed sinks through which water is absorbed (water that otherwise would have continued its path into the matrix). In this paper a preliminary effort is made to numerically model the effect of SAPs on the water absorption by mortar. A lattice-type model is proposed to predict both the bulk water absorption and the resulting penetration depth of water into the cementitious matrix. The results of the simulations point out the mechanisms of water absorption in mortar containing SAPs.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen

3D Concrete Printing for Structural Applications

Recent years have seen a rapid growth of additive manufacturing methods for concrete construction. Potential advantages include reduced material use and cost, reduced labor, mass customization and CO2 footprint reduction. None of these methods, however, has yet been able to produce additively manufactured concrete with material properties suitable for structural applications, i.e. ductility and (flexural) tensile strength. In order to make additive manufacturing viable as a production method for structural concrete, a quality leap had to be made. In the project ‘3D Concrete Printing for Structural Applications’, 3 concepts have been explored to achieve the required structural performance: applying steel fiber reinforcement to an existing printable concrete mortar, developing a strain-hardening cementitious composite based on PVA fibers, and embedding high strength steel cable as reinforcement in the concrete filament. Whereas the former produced only an increase in flexural tensile strength, but limited post-peak resistance, the latter two provided promising strain hardening behavior, thus opening the road to a wide range of structural applications of 3D printed concrete.Energy Innovation #5: 4TU.BOUW Lighthouse projects + PDEng ISBN 978-94-6366-246-8Materials and Environmen

Modelling strategies for the study of crack self-sealing in mortar with superabsorbent polymers

In this work, a numerical model is presented to predict the self-sealing effect provided by superabsorbent polymers (SAP) admixtures in mortar. Firstly, the use of a law of absorption kinetics for SAP embedded in a cementitious matrix was validated with experimental results available in literature. Secondly, two extreme strategies are considered for the swelling of SAP in the crack regarding the variation in its deformation capacity under constraint. The results show the appropriateness of the SAP absorption law and explain the mechanisms of water absorption of mortar with such admixtures. Furthermore, the influence of the deformation capacity of SAP on the water penetration in cracks is studied parametrically.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen

Plutonic Rocks as Protection Layers to Concrete Exposed to Ultra-High Temperature

Concrete structures perform poorly when withstanding thermal shock events, usually requiring repair or replacement after one single instance. In certain industries (such as petrol, metallurgic and ceramics), these events are not only likely but frequent, which represents a considerable financial burden. One option to solve this issue would be to decrease the heating rate imposed onto the concrete material through the use of a protective surface layer. In this work, the suitability of dunite and microgabbro as protective materials is explored through X-ray diffraction, thermal dilation, optical microscopy, X-ray microtomography, thermo-gravimetric analysis and a compressive test. Further, the thermal dilation was used as an input to simulate a composite concrete-rock wall and the respective stresses caused by a thermal shock event. The dehydration of chrysotile in dunite and the decomposition of analcime, chamosite and pumpellyite in microgabbro were both favourable for the performance of the stones in the desired application. The thermal stability and deformation were found in the range of what can be applied directly on concrete; however, it was clear that pre-heating treatment results in a far more durable system in a cyclic thermal load situation.Materials and Environmen

Surface effects of molten slag spills on calcium aluminate cement paste

Industries such as metal, ceramics and petrochemicals suffer from high temperature spills. Such events exert a unique form of loading in concrete structures that cannot be accurately simulated by heating of samples in an oven. Calcium aluminate cement (CAC) based concrete is the industry standard for such environment, and while much is known regarding its heating, literature considering hot spills on concrete surfaces is scarce. In this paper, slag is heated up to the same temperature as in a steel factory and then poured on top of cement paste samples with W/C ratios of 0.20 and 0.40. A combination of FEM, TGA, XRD and SEM/EDS was used to investigate the effects of hot spill on the samples. The rapid expansion caused by the thermal shock generated cracks in only some of the samples, while the high temperature environment and unidirectional escape of water caused chemical changes in all samples.Materials and Environmen

Assessing strain rate sensitivity of cement paste at the micro-scale through micro-cantilever testing

This study presents an experimental investigation of the rate-dependent mechanical properties of cement paste at the microscale. With the use of a nanoindenter, micro-cantilever beams with the size of 300 μm × 300 μm × 1650 μm were loaded at five different strain rates from around 10−6/s to 10−2/s until failure. It is found that with increasing strain rate, the stress-strain curves show less and delayed pre-peak nonlinearity. Both the flexural strength and the elastic modulus of beams increase with increasing strain rate, while the strain at peak stress exhibits an opposite trend. Examination of the fracture surface indicates that with increasing strain rate the possibility of a crack to pass through stronger components of the hydration products is increased. The experimental observations and possible mechanisms leading to changes in mechanical responses are discussed. It is suggested that at least two micromechanical processes, namely creep and Stéfan effect, are mainly responsible for the rate-dependent behaviour of cement paste within the investigated strain rate range and their dominances seem to vary with the strain rate. At lower strain rate, the strain rate sensitivity of cement paste is thought to be dominated by the creep effect, while at higher strain rate the Stéfan effect appears to be the governing factor.Materials and Environmen