1 research outputs found
A Lithium Amide Protected Against Protonation in the Gas Phase: Unexpected Effect of LiCl
In
cold THF and in the presence of LiCl, a lithium pyrrolidinylamide
forms a 1:1 mixed aggregate, which is observed directly by ESI-MS.
Gas-phase protonation of this species leads to selective transfer
of H<sup>+</sup> to the chlorine, suggesting that LiCl shields the
amide nitrogen and prevents its direct protonation