Mercury deposition/accumulation rates in the vicinity of a lead smelter as recorded by a peat deposit

. Recent findings show that Hg records from peat tend to overestimate historical levels of Hg deposition. Therefore we used the mass loss compensation factor (MLCF) to normalize Hg accumulation rates. These corrected Hg accumulation rates were significantly lower (maximum 129 mg m À2 yr À1 ) and better corresponded to changes in historical smelter emissions, which were highest in the 1960s. The agreement between the corrected Hg accumulation rates in the uppermost peat sections (2-38 mg m À2 yr À1 ) and biomonitoring of atmospheric deposition by mosses in several recent years (4.7-34.4 mg m À2 yr À1 ) shows the usefulness of MLCF application on Hg accumulation in peat archives. However, the MLCF correction was unsuitable for Pb. The recent Pb deposition rates obtained by an independent biomonitoring study using mosses (0.5-127 mg m À2 yr À1 ) were better correlated with net Pb accumulation rates recorded in peat (7-145 mg m À2 yr À1 ) than with corrected rates obtained by the MLCF approach (1-28 mg m À2 yr À1 )

Priprava a studium komplexu azamakrocyklickych fosfinovych kyselin s lanthanoidy.

Available from STL, Prague, CZ / NTK - National Technical LibrarySIGLECZCzech Republi

Mercury Speciation Analysis on Model Samples

Mercury speciation on model samples of iron oxyhydroxides, aluminum oxyhydroxides and layered materials (montmorillonite) was studied using ICP-EOS-TD technique. The TD curves obtainedare used for interpretation of data measured on real samples

Uranyl Minerals from Abandoned Podgórze Mine (Sudetes Mountains, SW Poland) and Their REE Content

The Podgórze uranium deposit is located near Kowary in the Sudetes Mountains, SW Poland. The mine is located in the Karkonosze-Izera block, largely comprising Cambrian to Devonian metamorphic rocks intruded by the Variscan Karkonosze granite. Uranyl minerals from the Podgórze mine can be divided into three assemblages. The first one is associated with heavily ventilated mining galleries. The next assemblage is related to the outflow of water from fissures in the walls of the mine galleries. The last assemblage appears in the mine dump, where there is increased activity of other weathering products. The main purpose of this paper is to determine the mineralogical characteristics of uranyl minerals from the abandoned Podgórze uranium mine and reconstruct the physicochemical crystallization conditions based on the concentrations of rare earth elements (REEs) in these minerals. The results of thermodynamic modeling show that the aqueous species of uranyl ion in the mine water are represented by UO2HAsO4 (aq), UO2CO3(OH)3−, UO2CO3 (aq), and UO2OH+. The content of REEs and their distribution patterns were used to determine the crystallization conditions of uranyl minerals. Uranyl carbonates and arsenates have generally low concentrations of REEs compared to uranyl silicates, phosphates, and hydroxides, which have higher concentrations. The differences in REE concentration patterns may be related with the oxidizing nature of water circulating in the subsurface part of the deposit

Uranyl Minerals from Abandoned Podgórze Mine (Sudetes Mountains, SW Poland) and Their REE Content

The Podgórze uranium deposit is located near Kowary in the Sudetes Mountains, SW Poland. The mine is located in the Karkonosze-Izera block, largely comprising Cambrian to Devonian metamorphic rocks intruded by the Variscan Karkonosze granite. Uranyl minerals from the Podgórze mine can be divided into three assemblages. The first one is associated with heavily ventilated mining galleries. The next assemblage is related to the outflow of water from fissures in the walls of the mine galleries. The last assemblage appears in the mine dump, where there is increased activity of other weathering products. The main purpose of this paper is to determine the mineralogical characteristics of uranyl minerals from the abandoned Podgórze uranium mine and reconstruct the physicochemical crystallization conditions based on the concentrations of rare earth elements (REEs) in these minerals. The results of thermodynamic modeling show that the aqueous species of uranyl ion in the mine water are represented by UO2HAsO4 (aq), UO2CO3(OH)3−, UO2CO3 (aq), and UO2OH+. The content of REEs and their distribution patterns were used to determine the crystallization conditions of uranyl minerals. Uranyl carbonates and arsenates have generally low concentrations of REEs compared to uranyl silicates, phosphates, and hydroxides, which have higher concentrations. The differences in REE concentration patterns may be related with the oxidizing nature of water circulating in the subsurface part of the deposit

Lessons Learnt from the Revitalisation of Chemical Factory in Marktredwitz and River Banks Downstream: When ‘Renaturation’ Can Be Harmful

Our study addressed mercury contamination hotspots that originated from Chemical Factory Marktredwitz, Germany. The factory was abandoned in 1985 but its legacy has been persistently endangering the river ecosystem of the Ohře River, a Labe (Elbe) River tributary in the Czech Republic. We identified the timing for the peak contamination of fine sediments entering the Skalka Reservoir located on the Ohře River downstream of the Czech German boundary. Age constraints for the reservoir sediments were obtained using gamma spectrometry analyses of 137Cs and unsupported (excess) 210Pb. We also summarised historical and current Hg concentrations in suspended particulate matter in the Kössein–Röslau–Ohře river system and recent Hg concentrations in aquatic plants. Secondary contamination and its transfer to the Czech stretch of the Ohře River and the Skalka Reservoir through severely contaminated suspended material peaked during the period of factory closure and the start of remediation. The Hg contamination import to the Czech Republic is not likely to improve if the river is left without traditional management of bank reinforcement. This case study highlights a gap in safety regulations for the management of severely contaminated rivers and demonstrates the need to consider the role of historical contamination in river ‘renaturation’