10 research outputs found
Hepatoblastoma in an Adult with Biliary Obstruction and Associated Portal Venous Thrombosis
We present a case of adult hepatoblastoma. This young female presented with severe acute
cholangitis. Preoperative diagnosis was common bile duct (CBD) obstruction with portal vein
thrombosis. On exploration she had a tumor mass in the CBD. The unusual features of this case
are discussed in this report
Microwave-assisted crystallization for improved process control during crystallization
status: publishe
Microwave assisted direct nucleation control for batch crystallization: Crystal size control with reduced batch time
© 2015 American Chemical Society. Direct nucleation control (DNC) is a feedback control strategy, based on an in situ measurement of the number of particles. In batch cooling crystallization processes, the DNC approach utilizes temperature cycling to control the supersaturation profile during the batch. As a result of this cycling, product crystals with a large mean size and a narrow size distribution can be achieved due to the dissolution of undesired fines. However, implementing the temperature cycles may come at the expense of significantly prolonged batch times due to conventional heat transfer limitations and practical limitations for implementing actuation for both conventional heating and cooling. In this work, microwave heating in combination with DNC is presented to eliminate limitations of conventional heating and further improve the effectiveness of DNC. The results show a very rapid response when using microwave heating, which allowed for improved effectiveness of DNC. In particular, batch times under DNC could be reduced by 50% using microwave heating compared to conventional heating, producing crystals with a narrow distribution similar to experiments with conventionally heated DNC.status: publishe
Novel Design Integrating a Microwave Applicator into a Crystallizer for Rapid Temperature Cycling. A Direct Nucleation Control Study
Extracellular polymeric substances govern the surface charge of biogenic elemental selenium nanoparticles
International audienc
Multiparameter Investigation of Laser-Induced Nucleation of Supersaturated Aqueous KCl Solutions
Various
mechanisms have been proposed to explain the nonphotochemical
laser-induced nucleation (NPLIN). Identifying the dominant mechanism
requires addressing a large set of experimental parameters with a
statistically significant number of samples, forced by the stochastic
nature of nucleation. In this study, with aqueous KCl system, we focus
on the nucleation probability as a function of laser wavelength, laser
intensity, and sample supersaturation, whereas the influence of filtration
and the laser-induced radiation pressure on NPLIN activity is also
studied. To account for the nucleation stochasticity, we used 80–100
samples. The NPLIN probability showed an increase with increasing
laser intensity. The results are different from the previous report,
as a supersaturation independent intensity threshold is not observed.
No dependence of the NPLIN probability on the laser wavelength (355,
532, and 1064 nm) was observed. Filtration of samples reduced the
nucleation probability suggesting a pronounced role of impurities
on NPLIN. The magnitude and the propagation velocity of the laser-induced
radiation pressure were quantified using a pressure sensor under laser
intensities ranging from 0.5 to 80 MW/cm<sup>2</sup>. No correlation
was found between the radiation pressure and NPLIN at our unfocused
laser beam intensities ruling out the radiation pressure as a possible
cause for nucleation
Extracellular Polymeric Substances Govern the Surface Charge of Biogenic Elemental Selenium Nanoparticles
The origin of the organic layer covering
colloidal biogenic elemental
selenium nanoparticles (BioSeNPs) is not known, particularly in the
case when they are synthesized by complex microbial communities. This
study investigated the presence of extracellular polymeric substances
(EPS) on BioSeNPs. The role of EPS in capping the extracellularly
available BioSeNPs was also examined. Fourier transform infrared (FT-IR)
spectroscopy and colorimetric measurements confirmed the presence
of functional groups characteristic of proteins and carbohydrates
on the BioSeNPs, suggesting the presence of EPS. Chemical synthesis
of elemental selenium nanoparticles in the presence of EPS, extracted
from selenite fed anaerobic granular sludge, yielded stable colloidal
spherical selenium nanoparticles. Furthermore, extracted EPS, BioSeNPs,
and chemically synthesized EPS-capped selenium nanoparticles had similar
surface properties, as shown by ζ-potential versus pH profiles
and isoelectric point measurements. This study shows that the EPS
of anaerobic granular sludge form the organic layer present on the
BioSeNPs synthesized by these granules. The EPS also govern the surface
charge of these BioSeNPs, thereby contributing to their colloidal
properties, hence affecting their fate in the environment and the
efficiency of bioremediation technologies