Capillary-Enhanced Immobilization of Nanoparticles

The contact between a spherical nanoparticle and a planar substrate is surrounded by an annular wedge cavity. In adsorption processes, this acts like a small pore. Interfacial/capillarity effects lead to an accumulation of adsorbate in this region (“capillary condensation”). This effectively increases the contact area between the particles and the substrate. Thus, capillary-enhanced adsorbate accumulation increases the adhesion between the nanoparticles and the planar surface, which effectively immobilizes the particles

Self-Assembly of Ultralong Aligned Dipeptide Single Crystals

Oriented arrangement of single crystals plays a key role in improving the performance of their functional devices. Herein we describe a method for the exceptionally fast fabrication (mm/min) of ultralong aligned dipeptide single crystals (several centimeters). It combines an induced nucleation step with a continuous withdrawal of substrate, leading to specific evaporation/composition conditions at a three-phase contact line, which makes the growth process controllable. These aligned dipeptide fibers possess a uniform cross section with active optical waveguiding properties that can be used as waveguiding materials. The approach provides guidance for the controlled arrangement of organic single crystals, a family of materials with considerable potential applications in large-scale functional devices