Flexible synthesis of polyfunctionalised 3-fluoropyrroles

An efficient and selective approach for the synthesis of polyfunctionalised 3-fluoropyrroles has been developed starting from commercial aldehydes. The methodology is concise, efficient and allows for the modular and systematic assembly of polysubstituted 3-fluoropyrroles. This synthesis provides an alternative and highly convergent strategy for the generation of these chemically and biologically important units

Scaling behavior of jamming fluctuations upon random sequential adsorption

It is shown that the fluctuations of the jamming coverage upon Random Sequential Adsorption ($\sigma_{\theta_J}$), decay with the lattice size according to the power-law $\sigma_{\theta_J} \propto L^{-1 / \nu_J}$, with $\nu_{J} = 2 / (2D - d_f)$, where $D$ is the dimension of the substrate and $d_{\rm f}$ is the fractal dimension of the set of sites belonging to the substrate where the RSA process actually takes place. This result is in excellent agreement with the figure recently reported by Vandewalle {\it et al} ({\it Eur. Phys. J.} B. {\bf 14}, 407 (2000)), namely $\nu_J = 1.0 (1)$ for the RSA of needles with $D = 2$ and $d_f = 2$, that gives $\nu_J = 1$. Furthermore, our prediction is in excellent agreement with different previous numerical results. The derived relationships are also confirmed by means of extensive numerical simulations applied to the RSA of dimers on both stochastic and deterministic fractal substrates.Comment: 8 pages, 2 figures. To appear in Eur. Phys. J. B (Rapid note) (2003

Anomalous scaling in a non local growth model in the Kardar-Parisi-Zhang universality class

We study the interface dynamics of a discrete model to quantitatively describe electrochemical deposition experiments. Extensive numerical simulations indicate that the interface dynamics is unstable at early times, but asymptotically displays the scaling of the Kardar-Parisi-Zhang universality class. During the time interval in which the surface is unstable, its power spectrum is anomalous; hence the behaviors at length scales smaller than or comparable with the system size are described by different roughness exponents. These results are expected to apply to a wide range of electrochemical deposition experiments.Comment: REVTEX (4 pages) and three figures (postscript), to be published in PRE (rapid communication, March, 1998

Dimensional reduction of the CPT-even electromagnetic sector of the Standard Model Extension

The CPT-even abelian gauge sector of the Standard Model Extension is represented by the Maxwell term supplemented by $(K_{F})_{\mu\nu\rho\sigma}F^{\mu\nu}F^{\rho\sigma}$, where the Lorentz-violating background tensor, $(K_{F})_{\mu\nu\rho\sigma}$, possesses the symmetries of the Riemann tensor. In the present work, we examine the planar version of this theory, obtained by means of a typical dimensional reduction procedure to $(1+2)$ dimensions. The resulting planar electrodynamics is composed of a gauge sector containing six Lorentz-violating coefficients, a scalar field endowed with a noncanonical kinetic term, and a coupling term that links the scalar and gauge sectors. The dispersion relation is exactly determined, revealing that the six parameters related to the pure electromagnetic sector do not yield birefringence at any order. In this model, the birefringence may appear only as a second order effect associated with the coupling tensor linking the gauge and scalar sectors.The equations of motion are written and solved in the stationary regime. The Lorentz-violating parameters do not alter the asymptotic behavior of the fields but induce an angular dependence not observed in the Maxwell planar theory.Comment: 13 pages, revtex style, no figures, to appear in Physical Review D(2011

Short and efficient synthesis of fluorinated δ-lactams

The diastereoselective synthesis of fluorinated δ-lactams has been achieved through an efficient five step process. The route can tolerate a range of functionalities, and provides a quick route for the generation of new fluorinated medicinal building blocks

Quantum transport through single and multilayer icosahedral fullerenes

We use a tight-binding Hamiltonian and Green functions methods to calculate the quantum transmission through single-wall fullerenes and bilayered and trilayered onions of icosahedral symmetry attached to metallic leads. The electronic structure of the onion-like fullerenes takes into account the curvature and finite size of the fullerenes layers as well as the strength of the intershell interactions depending on to the number of interacting atom pairs belonging to adjacent shells. Misalignment of the symmetry axes of the concentric icosahedral shells produces breaking of the level degeneracies of the individual shells, giving rise some narrow quasi-continuum bands instead of the localized discrete peaks of the individual fullerenes. As a result, the transmission function for non symmetrical onions are rapidly varying functions of the Fermi energy. Furthermore, we found that most of the features of the transmission through the onions are due to the electronic structure of the outer shell with additional Fano-like antiresonances arising from coupling with or between the inner shells.Comment: 16 pages, 5 figur