Dynamics of confined water reconstructed from inelastic x-ray scattering measurements of bulk response functions

Nanoconfined water and surface-structured water impacts a broad range of fields. For water confined between hydrophilic surfaces, measurements and simulations have shown conflicting results ranging from “liquidlike” to “solidlike” behavior, from bulklike water viscosity to viscosity orders of magnitude higher. Here, we investigate how a homogeneous fluid behaves under nanoconfinement using its bulk response function: The Green's function of water extracted from a library of S(q,ω) inelastic x-ray scattering data is used to make femtosecond movies of nanoconfined water. Between two confining surfaces, the structure undergoes drastic changes as a function of surface separation. For surface separations of ≈9 Å, although the surface-associated hydration layers are highly deformed, they are separated by a layer of bulklike water. For separations of ≈6 Å, the two surface-associated hydration layers are forced to reconstruct into a single layer that modulates between localized “frozen’ and delocalized “melted” structures due to interference of density fields. These results potentially reconcile recent conflicting experiments. Importantly, we find a different delocalized wetting regime for nanoconfined water between surfaces with high spatial frequency charge densities, where water is organized into delocalized hydration layers instead of localized hydration shells, and are strongly resistant to `freezing' down to molecular distances (<6 Å)

Tourism Professionals Profile: Theme Park Managers

Theme park managers are a unique group of tourism managers. Their perspectives on effective tourism management skills and abilities differ from some public sector tourism managers. The authors present the results of a study focusing on theme park managers and compare these results with those of other tourism manager group

Investigation of turbines for driving supersonic compressors II : performance of first configuration with 2.2 percent reduction in nozzle flow area / Warner L. Stewart, Harold J. Schum, Robert Y. Wong

The experimental performance of a modified turbine for driving a supersonic compressor is presented and compared with the performance of the original configuration to illustrate the effect of small changes in the ratio of nozzle-throat area to rotor-throat area. Performance is based on the performance of turbines designed to operate with both blade rows close to choking. On the basis of the results of this investigation, the ratio of areas is concluded to become especially critical in the design of turbines such as those designed to drive high-speed, high-specific weight-flow compressors where the turbine nozzles and rotor are both very close to choking