10,017 research outputs found
Strain Hardening in Polymer Glasses: Limitations of Network Models
Simulations are used to examine the microscopic origins of strain hardening
in polymer glasses. While traditional entropic network models can be fit to the
total stress, their underlying assumptions are inconsistent with simulation
results. There is a substantial energetic contribution to the stress that rises
rapidly as segments between entanglements are pulled taut. The thermal
component of stress is less sensitive to entanglements, mostly irreversible,
and directly related to the rate of local plastic arrangements. Entangled and
unentangled chains show the same strain hardening when plotted against the
microscopic chain orientation rather than the macroscopic strain.Comment: 4 pages, 3 figure
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Methods for treating bone deficit conditions with benzothiazole
" Compounds containing two aromatic systems covalently linked through a linker containing one or more atoms, or ""linker"" defined as including a covalent bond per se so as to space the aromatic systems at a distance 1.5-15 .ANG., are effective in treating conditions associated with bone deficits. The compounds can be administered to vertebrate subjects alone or in combination with additional agents that promote bone growth or that inhibit bone resorption. They can be screened for activity prior to administration by assessing their ability to effect the transcription of a reporter gene coupled to a promoter associated with a bone morphogenetic protein and/or their ability to stimulate calvarial growth in model animal systems. "Board of Regents, University of Texas Syste
Dynamic sea surface topography, gravity and improved orbit accuracies from the direct evaluation of SEASAT altimeter data
A method for the simultaneous solution of dynamic ocean topography, gravity and orbits using satellite altimeter data is described. A GEM-T1 based gravitational model called PGS-3337 that incorporates Seasat altimetry, surface gravimetry and satellite tracking data has been determined complete to degree and order 50. The altimeter data is utilized as a dynamic observation of the satellite's height above the sea surface with a degree 10 model of dynamic topography being recovered simultaneously with the orbit parameters, gravity and tidal terms in this model. PGS-3337 has a geoid uncertainty of 60 cm root-mean-square (RMS) globally, with the uncertainty over the altimeter tracked ocean being in the 25 cm range. Doppler determined orbits for Seasat, show large improvements, with the sub-30 cm radial accuracies being achieved. When altimeter data is used in orbit determination, radial orbital accuracies of 20 cm are achieved. The RMS of fit to the altimeter data directly gives 30 cm fits for Seasat when using PGS-3337 and its geoid and dynamic topography model. This performance level is two to three times better than that achieved with earlier Goddard earth models (GEM) using the dynamic topography from long-term oceanographic averages. The recovered dynamic topography reveals the global long wavelength circulation of the oceans with a resolution of 1500 km. The power in the dynamic topography recovery is now found to be closer to that of oceanographic studies than for previous satellite solutions. This is attributed primarily to the improved modeling of the geoid which has occurred. Study of the altimeter residuals reveals regions where tidal models are poor and sea state effects are major limitations
Improving Predictions for Helium Emission Lines
We have combined the detailed He I recombination model of Smits with the
collisional transitions of Sawey & Berrington in order to produce new accurate
helium emissivities that include the effects of collisional excitation from
both the 2 (3)S and 2 (1) S levels. We present a grid of emissivities for a
range of temperature and densities along with analytical fits and error
estimates.
Fits accurate to within 1% are given for the emissivities of the brightest
lines over a restricted range for estimates of primordial helium abundance. We
characterize the analysis uncertainties associated with uncertainties in
temperature, density, fitting functions, and input atomic data. We estimate
that atomic data uncertainties alone may limit abundance estimates to an
accuracy of 1.5%; systematic errors may be greater than this. This analysis
uncertainty must be incorporated when attempting to make high accuracy
estimates of the helium abundance. For example, in recent determinations of the
primordial helium abundance, uncertainties in the input atomic data have been
neglected.Comment: ApJ, accepte
Yield conditions for deformation of amorphous polymer glasses
Shear yielding of glassy polymers is usually described in terms of the
pressure-dependent Tresca or von Mises yield criteria. We test these criteria
against molecular dynamics simulations of deformation in amorphous polymer
glasses under triaxial loading conditions that are difficult to realize in
experiments. Difficulties and ambiguities in extending several standard
definitions of the yield point to triaxial loads are described. Two
definitions, the maximum and offset octahedral stresses, are then used to
evaluate the yield stress for a wide range of model parameters. In all cases,
the onset of shear is consistent with the pressure-modified von Mises
criterion, and the pressure coefficient is nearly independent of many
parameters. Under triaxial tensile loading, the mode of failure changes to
cavitation.Comment: 9 pages, 8 figures, revte
Fcc-bcc transition for Yukawa interactions determined by applied strain deformation
Calculations of the work required to transform between bcc and fcc phases
yield a high-precision bcc-fcc transition line for monodisperse point Yukawa
(screened-Couloumb) systems. Our results agree qualitatively but not
quantitatively with previously published simulations and phenomenological
criteria for the bcc-fcc transition. In particular, the bcc-fcc-fluid triple
point lies at a higher inverse screening length than previously reported.Comment: RevTex4, 9 pages, 6 figures. Discussion of phase coexistence
extended, a few other minor clarifications added, referencing improved.
Accepted for publication by Physical Review
Deer ticks (Ixodes scapularis) and the agents of Lyme disease and human granulocytic ehrlichiosis in a New York City park.
Rodent trapping and drag sampling in Van Cortlandt Park, New York City, yielded all stages of Ixodes scapularis, the deer tick vector of Lyme disease and human granulocytic ehrlichiosis (HGE). Polymerase chain reaction analyses of the ticks showed Borrelia burgdorferi and the Ehrlichia sp. that causes HGE
Resolving singular forces in cavity flow: Multiscale modeling from atoms to millimeters
A multiscale approach for fluid flow is developed that retains an atomistic
description in key regions. The method is applied to a classic problem where
all scales contribute: The force on a moving wall bounding a fluid-filled
cavity. Continuum equations predict an infinite force due to stress
singularities. Following the stress over more than six decades in length in
systems with characteristic scales of millimeters and milliseconds allows us to
resolve the singularities and determine the force for the first time. The
speedup over pure atomistic calculations is more than fourteen orders of
magnitude. We find a universal dependence on the macroscopic Reynolds number,
and large atomistic effects that depend on wall velocity and interactions.Comment: 4 pages,3 figure
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