The Red Giant Branch Bump

We present a comparison between theoretical models and the observed magnitude difference between the horizontal branch and the red giant branch bump for a sample of 53 clusters. We find a general agreement, though some discrepancy is still present at the two extremes of the metallicity range of globular clusters.Comment: 2 pages, 1 figure, A.S.P. Conf. Ser., in press in Vol. 296, 200

Explosion of a massive, He-rich star at z=0.16

We present spectroscopic and photometric data of the peculiar SN 2001gh, discovered by the 'Southern inTermediate Redshift ESO Supernova Search' (STRESS) at a redshift z=0.16. SN 2001gh has relatively high luminosity at maximum (M_B = -18.55 mag), while the light curve shows a broad peak. An early-time spectrum shows an almost featureless, blue continuum with a few weak and shallow P-Cygni lines that we attribute to HeI. HeI lines remain the only spectral features visible in a subsequent spectrum, obtained one month later. A remarkable property of SN 2001gh is the lack of significant spectral evolution over the temporal window of nearly one month separating the two spectra. In order to explain the properties of SN 2001gh, three powering mechanism are explored, including radioactive decays of a moderately large amount of 56Ni, magnetar spin-down, and interaction of SN ejecta with circumstellar medium. We favour the latter scenario, with a SN Ib wrapped in a dense, circumstellar shell. The fact that no models provide an excellent fit with observations, confirms the troublesome interpretation of the nature of SN 2001gh. A rate estimate for SN 2001gh-like event is also provided, confirming the intrinsic rarity of these objects.Comment: 11 pages, 8 figures, 3 tables. Accepted by MNRA

The impact of recurrent Covid-19 waves on patients with Functional Movement Disorders: A follow-up study

Background: Functional Movement Disorders (FMDs) might exacerbate in stressful conditions. As the global health emergency due to Covid-19 rise and multiple waves hit the Italian population, the recurrent severe restrictions' periods imposed could represent important triggers and worsen the symptoms of FMDs. Through a follow-up study, we compare results on Motor Symptoms (MS), Non-Motor Symptoms (NMS), and Global Health Status (GHS) of two surveys, one referred to the first Covid-19 wave and the other to the third Covid-19 wave. Methods: 60 FMDs patients responded to an online survey after the first and the third Covid-19 waves in Italy. Questions regarding sociodemographic, clinical and Covid-19 information, MS, NMS, and GHS were collected to assess severity of symptoms and changes in comparison to a period with less severe social restrictions. Results: Patients showed minimal to mild motor symptoms' severity, and substantial stability through time in all collected measures, both for severity and changes of MS, NMS, and GHS in comparison at two time points (p > 0.050). The worsening of pain resulted as predictor factor for the worsening of Motor Symptoms (p = 0.042). Conclusions: Patients did not show a vulnerability due to the recurrent restrictions' periods: MS, NMS and GHS did not vary in comparison to the first wave, confirming the previous results and highlighting the role of the social context in those disorders. Further investigations are required to better disentangle the relationship between stressful events, motor symptoms, and pain

HST color-magnitude diagrams of 74 galactic globular clusters in the HST F439W and F555W bands

We present the complete photometric database and the color-magnitude diagrams for 74 Galactic globular clusters observed with the HST/WFPC2 camera in the F439W and F555W bands. A detailed discussion of the various reduction steps is also presented, and of the procedures to transform instrumental magnitudes into both the HST F439W and F555W flight system and the standard Johnson B and V systems. We also describe the artificial star experiments which have been performed to derive the star count completeness in all the relevant branches of the color magnitude diagram. The entire photometric database and the completeness function will be made available on the Web immediately after the publication of the present paper.Comment: 21 pages, 77 figures. High resolution version of this paper can be retrived at http://dipastro.pd.astro.it/globular

Photometric metallicity for 694233 Galactic giant stars from Gaia DR3 synthetic Stromgren photometry. Metallicity distribution functions of halo sub-structures

We use the calibrations by Calamida et al. and by Hilker et al., and the standardised synthetic photometry in the v, b, and y Stromgren passbands from Gaia DR3 BP/RP spectra, to obtain photometric metallicities for a selected sample of 694233 old Galactic giant stars having |b|>20.0 and parallax uncertainties lower than 10%. The zero point of both sets of photometric metallicities has been shifted to to ensure optimal match with the spectroscopic [Fe/H] values for 44785 stars in common with APOGEE DR17, focusing on the metallicity range where they provide the highest accuracy. The metallicities derived in this way from the Calamida et al. calibration display a typical accuracy of ~0.1 dex and 1 sigma precision ~0.2 dex in the range -2.2 <=[Fe/H]<= -0.4, while they show a systematic trend with [Fe/H] at higher metallicity, beyond the applicability range of the relation. Those derived from the Hilker et al. calibration display, in general, worse precision, and lower accuracy in the metal-poor regime, but have a median accuracy < 0.05 dex for [Fe/H]>= -0.8. These results are confirmed and, consequently, the metallicities validated, by comparison with large sets of spectroscopic metallicities from various surveys. The newly obtained metallicities are used to derive metallicity distributions for several previously identified sub-structures in the Galactic halo with an unprecedented number of stars. The catalogue including both sets of metallicities and the associated uncertainties is made publicly available.Comment: Accepted for publication by Astronomy & Astrophysics. Latex. 20 pages, 21 color figures. The catalogue will be publicly available at CDS. In the meanwhile it is available upon request to the first autho

Modification of Amorphous Mesoporous Zirconia Nanoparticles with Bisphosphonic Acids: A Straightforward Approach for Tailoring the Surface Properties of the Nanoparticles

The use of readily prepared bisphosphonic acids obtained in few steps through a thio-Michael addition of commercially available thiols on tetraethyl vinylidenebisphosphonate enables the straightforward surface modification of amorphous mesoporous zirconia nanoparticles. Simple stirring of the zirconia nanoparticles in a buffered aqueous solution of the proper bisphosphonic acid leads to the surface functionalization of the nanoparticles with different kinds of functional groups, charge and hydrophobic properties. Formation of both chemisorbed and physisorbed layers of the bisphosphonic acid take place, observing after extensive washing a grafting density of 1.1 molecules/nm2 with negligible release in neutral or acidic pH conditions, demonstrating stronger loading compared to monophosphonate derivatives. The modified nanoparticles were characterized by IR, XPS, ζ-potential analysis to investigate the loading of the bisphosphonic acid, FE-SEM to investigate the size and morphologies of the nanoparticles and 31P and 1H MAS NMR to investigate the coordination motif of the phosphonate units on the surface. All these analytical techniques demonstrated the strong affinity of the bisphosphonic moiety for the Zr(IV) metal centers. The functionalization with bisphosphonic acids represents a straightforward covalent approach for tailoring the superficial properties of zirconia nanoparticles, much straightforward compared the classic use of trisalkoxysilane or trichlorosilane reagents typically employed for the functionalization of silica and metal oxide nanoparticles. Extension of the use of bisphosphonates to other metal oxide nanoparticles is advisable

An Intermediate Redshift Supernova Search at ESO: Reduction Tools and Efficiency Tests

We present the reduction and archiving tools developed for our search for supernovae at intermediate redshifts at ESO as well as the efficiency tests performed. The data reduction recipes developed for the SN candidates selection are described. All the variable sources detected are stored using a MySQL database which enables the identification of previously detected variable sources during past observational runs. Finally, experiments performed with artificial stars have shown that seeing plays a crucial role for the limiting magnitude of detection. Crucial is also the detection threshold used by Sextractor.Comment: Poster presented at the ESO/MPA/MPE Workshop "From Twilight to Highlight, The Physics of Supernovae", Garching, Jul 29-31, 2002, to be published in the Conference Proceeding

Nanoscale effects on the ionic conductivity of highly doped bulk nanometric cerium oxide

Nanometric ceria powders doped with 30 mol % samaria are consolidated by a high-pressure spark plasma sintering (HP-SPS) method to form > 99 % dense samples with a crystallite size as small as 16.5 nm. A conductivity dependence on grain size was noted: when the grain size was less than 20 nm, only one semicircle in the AC impedance spectra was observed and was attributed to bulk conductivity. In contrast to previous observations on pure ceria, the disappearance of the grain-boundary blocking effect is not associated with mixed conductivity. With annealing and concomitant grain growth, the samples show the presence of a grain-boundary effect

Two-dimensional core–shell donor–acceptor assemblies at metal–organic interfaces promoted by surface-mediated charge transfer

Organic charge transfer (CT) complexes obtained by combining molecular electron donors and acceptors have attracted much interest due to their potential applications in organic opto-electronic devices. In order to work, these systems must have an electronic matching – the highest occupied molecular orbital (HOMO) of the donor must couple with the lowest unoccupied molecular orbital (LUMO) of the acceptor – and a structural matching, so as to allow direct intermolecular CT. Here it is shown that, when molecules are adsorbed on a metal surface, novel molecular organizations driven by surface-mediated CT can appear that have no counterpart in condensed phase non-covalent assemblies of donor and acceptor molecules. By means of scanning tunneling microscopy and spectroscopy it is demonstrated that the electronic and self-assembly properties of an electron acceptor molecule can change dramatically in the presence of an additional molecular species with marked electron donor character, leading to the formation of unprecedented core–shell assemblies. DFT and classical force-field simulations reveal that this is a consequence of charge transfer from the donor to the acceptor molecules mediated by the metallic substrate