Quantitative optical spectroscopy of 87^{87}Rb vapour in the Voigt geometry in DC magnetic fields up to 0.4T

We present a detailed spectroscopic investigation of a thermal ⁸⁷Rb atomic vapour in magnetic fields up to 0.4T in the Voigt geometry. We fit experimental spectra with our theoretical model ElecSus and find excellent quantitative agreement, with RMS errors of backsim0.3%. We extract the magnetic field strength and the angle between the polarisation of the light and the magnetic field from the atomic signal and find excellent agreement to within backsim1% with a commercial Hall probe. Finally, we present an investigation of the relative sensitivity of this technique to variations in the field strength and angle with a view to enabling atom-based high-field vector magnetometry

Preparation of amino-substituted indenes and 1,4-dihydronaphthalenes using a one-pot multireaction approach: total synthesis of oxybenzo[c]phenanthridine alkaloids

Allylic trichloroacetimidates bearing a 2-vinyl or 2-allylaryl group have been designed as substrates for a one-pot, two-step multi-bond-forming process leading to the general preparation of aminoindenes and amino-substituted 1,4-dihydronaphthalenes. The synthetic utility of the privileged structures formed from this one-pot process was demonstrated with the total synthesis of four oxybenzo[c]phenanthridine alkaloids, oxychelerythrine, oxysanguinarine, oxynitidine, and oxyavicine. An intramolecular biaryl Heck coupling reaction, catalyzed using the Hermann–Beller palladacycle was used to effect the key step during the synthesis of the natural products