2,100 research outputs found
A low-metallicity massive contact binary undergoing slow Case A mass transfer: A detailed spectroscopic and orbital analysis of SSN 7 in NGC 346 in the SMC
Most massive stars are believed to be born in close binary systems where they
can exchange mass, which impacts the evolution of both binary components. Their
evolution is of great interest in the search for the progenitors of
gravitational waves. However, there are unknowns in the physics of mass
transfer as observational examples are rare, especially at low metallicity.
Nearby low-metallicity environments are particularly interesting hunting
grounds for interacting systems as they act as the closest proxy for the early
universe where we can resolve individual stars. Using multi-epoch spectroscopic
data, we complete a consistent spectral and orbital analysis of the early-type
massive binary SSN 7 hosting a ON If+O5.5 V((f)) star. Using these
detailed results, we constrain an evolutionary scenario that can help us to
understand binary evolution in low metallicity. We were able to derive reliable
radial velocities of the two components from the multi-epoch data, which were
used to constrain the orbital parameters. The spectroscopic data covers the UV,
optical, and near-IR, allowing a consistent analysis with the stellar
atmosphere code, PoWR. Given the stellar and orbital parameters, we interpreted
the results using binary evolutionary models. The two stars in the system have
comparable luminosities of and for the primary and secondary, respectively, but have
different temperatures ( and
). The primary () is less massive than
the secondary (), suggesting mass exchange. The mass estimates
are confirmed by the orbital analysis. The revisited orbital period is
. Our evolutionary models also predict mass exchange. Currently,
the system is a contact binary undergoing a slow Case A phase, making it the
most massive [Abridged]Comment: 20 page
Magnetic Flux Braiding: Force-Free Equilibria and Current Sheets
We use a numerical nonlinear multigrid magnetic relaxation technique to
investigate the generation of current sheets in three-dimensional magnetic flux
braiding experiments. We are able to catalogue the relaxed nonlinear force-free
equilibria resulting from the application of deformations to an initially
undisturbed region of plasma containing a uniform, vertical magnetic field. The
deformations are manifested by imposing motions on the bounding planes to which
the magnetic field is anchored. Once imposed the new distribution of magnetic
footpoints are then taken to be fixed, so that the rest of the plasma must then
relax to a new equilibrium configuration. For the class of footpoint motions we
have examined, we find that singular and nonsingular equilibria can be
generated. By singular we mean that within the limits imposed by numerical
resolution we find that there is no convergence to a well-defined equilibrium
as the number of grid points in the numerical domain is increased. These
singular equilibria contain current "sheets" of ever-increasing current
intensity and decreasing width; they occur when the footpoint motions exceed a
certain threshold, and must include both twist and shear to be effective. On
the basis of these results we contend that flux braiding will indeed result in
significant current generation. We discuss the implications of our results for
coronal heating.Comment: 13 pages, 12 figure
The homotopy theory of dg-categories and derived Morita theory
The main purpose of this work is the study of the homotopy theory of
dg-categories up to quasi-equivalences. Our main result provides a natural
description of the mapping spaces between two dg-categories and in
terms of the nerve of a certain category of -bimodules. We also prove
that the homotopy category is cartesian closed (i.e. possesses
internal Hom's relative to the tensor product). We use these two results in
order to prove a derived version of Morita theory, describing the morphisms
between dg-categories of modules over two dg-categories and as the
dg-category of -bi-modules. Finally, we give three applications of our
results. The first one expresses Hochschild cohomology as endomorphisms of the
identity functor, as well as higher homotopy groups of the \emph{classifying
space of dg-categories} (i.e. the nerve of the category of dg-categories and
quasi-equivalences between them). The second application is the existence of a
good theory of localization for dg-categories, defined in terms of a natural
universal property. Our last application states that the dg-category of
(continuous) morphisms between the dg-categories of quasi-coherent (resp.
perfect) complexes on two schemes (resp. smooth and proper schemes) is
quasi-equivalent to the dg-category of quasi-coherent complexes (resp. perfect)
on their product.Comment: 50 pages. Few mistakes corrected, and some references added. Thm.
8.15 is new. Minor corrections. Final version, to appear in Inventione
Generalizing Optical Geometry
We show that by employing the standard projected curvature as a measure of
spatial curvature, we can make a certain generalization of optical geometry
(Abramowicz and Lasota 1997, Class. Quantum Grav. 14 (1997) A23). This
generalization applies to any spacetime that admits a hypersurface orthogonal
shearfree congruence of worldlines. This is a somewhat larger class of
spacetimes than the conformally static spacetimes assumed in standard optical
geometry. In the generalized optical geometry, which in the generic case is
time dependent, photons move with unit speed along spatial geodesics and the
sideways force experienced by a particle following a spatially straight line is
independent of the velocity. Also gyroscopes moving along spatial geodesics do
not precess (relative to the forward direction). Gyroscopes that follow a
curved spatial trajectory precess according to a very simple law of
three-rotation. We also present an inertial force formalism in coordinate
representation for this generalization. Furthermore, we show that by employing
a new sense of spatial curvature (Jonsson, Class. Quantum Grav. 23 (2006) 1)
closely connected to Fermat's principle, we can make a more extensive
generalization of optical geometry that applies to arbitrary spacetimes. In
general this optical geometry will be time dependent, but still geodesic
photons move with unit speed and follow lines that are spatially straight in
the new sense. Also, the sideways experienced (comoving) force on a test
particle following a line that is straight in the new sense will be independent
of the velocity.Comment: 19 pages, 1 figure. A more general analysis is presented than in the
former version. See also the companion papers arXiv:0708.2493,
arXiv:0708.2533 and arXiv:0708.253
Influence of arsenic on iron sulfide transformations
The association of arsenate, As(V), and arsenite, As(III), with disordered mackinawite, FeS, was studied in sulfide-limited (Fe:S = 1:1) and excess-sulfide (Fe:S = 1:2) batch experiments. In the absence of arsenic, the sulfide-limited experiments produce disordered mackinawite while the excess-sulfide experiments yield pyrite with trace amounts of mackinawite. With increasing initially added As(V) concentrations the transformation of FeS to mackinawite and pyrite is retarded. At S:As = 1:1 and 2:1, elemental sulfur and green rust are the end products. As(V) oxidizes S(-II) in FeS and (or) in solution to S(0), and Fe(II) in the solid phase to Fe(III). Increasing initially added As(III) concentrations inhibit the transformation of FeS to mackinawite and pyrite and no oxidation products of FeS or sulfide, other than pyrite, were observed. At low arsenic concentrations, sorption onto the FeS surface may be the reaction controlling the uptake of arsenic into the solid phase. Inhibition of iron(II) sulfide transformations due to arsenic sorption suggests that the sorption sites are crucial not only as sorption sites, but also in iron(II) sulfide transformation mechanisms
Inertial forces and the foundations of optical geometry
Assuming a general timelike congruence of worldlines as a reference frame, we
derive a covariant general formalism of inertial forces in General Relativity.
Inspired by the works of Abramowicz et. al. (see e.g. Abramowicz and Lasota,
Class. Quantum Grav. 14 (1997) A23), we also study conformal rescalings of
spacetime and investigate how these affect the inertial force formalism. While
many ways of describing spatial curvature of a trajectory has been discussed in
papers prior to this, one particular prescription (which differs from the
standard projected curvature when the reference is shearing) appears novel. For
the particular case of a hypersurface-forming congruence, using a suitable
rescaling of spacetime, we show that a geodesic photon is always following a
line that is spatially straight with respect to the new curvature measure. This
fact is intimately connected to Fermat's principle, and allows for a certain
generalization of the optical geometry as will be further pursued in a
companion paper (Jonsson and Westman, Class. Quantum Grav. 23 (2006) 61). For
the particular case when the shear-tensor vanishes, we present the inertial
force equation in three-dimensional form (using the bold face vector notation),
and note how similar it is to its Newtonian counterpart. From the spatial
curvature measures that we introduce, we derive corresponding covariant
differentiations of a vector defined along a spacetime trajectory. This allows
us to connect the formalism of this paper to that of Jantzen et. al. (see e.g.
Bini et. al., Int. J. Mod. Phys. D 6 (1997) 143).Comment: 42 pages, 7 figure
The CRI v2.2 reduced degradation scheme for isoprene
The reduced representation of isoprene degradation in the Common Representative Intermediates (CRI) mechanism has been systematically updated, using the Master Chemical Mechanism (MCM v3.3.1) as a reference benchmark, with the updated mechanism being released as CRI v2.2. The complete isoprene degradation mechanism in CRI v2.2 consists of 186 reactions of 56 closed shell and free radical species, this being an order of magnitude reduction in size compared with MCM v3.3.1. The chemistry initiated by reaction with OH radicals, NO3 radicals and ozone (O3) is treated. An overview of the updates is provided, within the context of reported kinetic and mechanistic information. The revisions mainly relate to the OH-initiated chemistry, which tends to dominate under atmospheric conditions, although these include updates to the chemistry of products that are also generated from the O3- and NO3-initiated oxidation. The revisions have impacts in a number of key areas, including recycling of HOx and NOx. The performance of the CRI v2.2 isoprene mechanism has been compared with those of the preceding version (CRI v2.1) and the reference MCM v3.3.1 over a range of relevant conditions, using a box model of the tropical forested boundary layer. In addition, tests are carried out to ensure that the performance of MCM v3.3.1 remains robust to more recently reported information. CRI v2.2 has also been implemented into the STOCHEM chemistry-transport model, with a customized close-variant of CRI v2.2 implemented into the EMEP MSC-W chemistry-transport model. The results of these studies are presented and used to illustrate the global-scale impacts of the mechanistic updates on HOx radical concentrations
Torsion pairs and simple-minded systems in triangulated categories
Let T be a Hom-finite triangulated Krull-Schmidt category over a field k.
Inspired by a definition of Koenig and Liu, we say that a family S of pairwise
orthogonal objects in T with trivial endomorphism rings is a simple-minded
system if its closure under extensions is all of T. We construct torsion pairs
in T associated to any subset X of a simple-minded system S, and use these to
define left and right mutations of S relative to X. When T has a Serre functor
\nu, and S and X are invariant under \nu[1], we show that these mutations are
again simple-minded systems. We are particularly interested in the case where T
is the stable module category of a self-injective algebra \Lambda. In this
case, our mutation procedure parallels that introduced by Koenig and Yang for
simple-minded collections in the derived category of \Lambda. It follows that
the mutation of the set of simple \Lambda-modules relative to X yields the
images of the simple \Gamma-modules under a stable equivalence between \Gamma\
and \Lambda, where \Gamma\ is the tilting mutation of \Lambda\ relative to X.Comment: Minor corrections. To appear in Applied Categorical Structures. The
final publication is available at springerlink.com:
http://link.springer.com/article/10.1007%2Fs10485-014-9365-
Nanoparticulate nickel sulfides formed in low temperature aqueous solutions
The nature of the nickel sulfides formed in low temperature
aqueous solutions is not well-understood. The material has some
intrinsic interest to mineralogy, geochemistry and materials science
as well as to biogeochemisty, especially as a possible catalyst
involved in the origin and early evolution of life.
We synthesized Ni sulfide under anoxic conditions at 25 C: (1)
chemically, by the addition of 50 mL of 0.1 M NiSO4Æ7H2O to
100 mL of 0.05M Na2SÆ9H2O; (2) electrochemically, with a Ni
foil and H2S gas. At pH 6 5, millerite (b-NiS) was produced electrochemically
and NiS mixtures, including heazlewoodite (Ni3S2)
and polydymite (Ni3S4), were obtained chemically. At pH >11, a-
NiS was obtained from the chemical reaction. At pH 6–9, the
product produced only two broad peaks (d = ca. 2.7 and 1.8 )
with conventional and synchrotron XRPD which could be
assigned to a number of Ni sulfides. It has previously been
referred to as ‘‘amorphous NiS’’ Jeong and Manthiram, 2001.
Eight SAED reflections were collected which identified the material
as godlevskite, orthorhombic NiS. HRTEM shows that the
godlevskite particles are ca. 30 nm in diameter and plate-like.
SAXS analyses show that the material is 6–8.5 nm thick.
Godlevskite is structurally related to makinawite, tetragonal
FeS, and is found naturally in similar parageneses-associated with
the monosulfide solid solution products of high temperature nickel
ores. Mackinawite is the black FeS precipitate from the reaction
between Fe(II) and S(-II) in aqueous solution. It appears that,
geochemically, godlevskite is the Ni analogue of mackinawite
Measuring Relations Between Concepts In Conceptual Spaces
The highly influential framework of conceptual spaces provides a geometric
way of representing knowledge. Instances are represented by points in a
high-dimensional space and concepts are represented by regions in this space.
Our recent mathematical formalization of this framework is capable of
representing correlations between different domains in a geometric way. In this
paper, we extend our formalization by providing quantitative mathematical
definitions for the notions of concept size, subsethood, implication,
similarity, and betweenness. This considerably increases the representational
power of our formalization by introducing measurable ways of describing
relations between concepts.Comment: Accepted at SGAI 2017 (http://www.bcs-sgai.org/ai2017/). The final
publication is available at Springer via
https://doi.org/10.1007/978-3-319-71078-5_7. arXiv admin note: substantial
text overlap with arXiv:1707.05165, arXiv:1706.0636
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