1,6-Diazabicyclo[4.4.4]tetradecane and its lnside-protonated lon: Changes in Space Groups

The crystal structures of 1,6-diazabicyclo[4.4.4]tetradecane (1) and of its inside-protonated ion (2), which were originally described in space group C2/c, should be described instead in trigonal space groups, (1) in R3c and (2) in P31c; both moieties have crystallographically imposed point symmetry D_3 rather than C_2

Test of the gravitational redshift with stable clocks in eccentric orbits: application to Galileo satellites 5 and 6

The Einstein Equivalence Principle (EEP) is one of the foundations of the theory of General Relativity and several alternative theories of gravitation predict violations of the EEP. Experimental constraints on this fundamental principle of nature are therefore of paramount importance. The EEP can be split in three sub-principles: the Universality of Free Fall (UFF), the Local Lorentz Invariance (LLI) and the Local Position Invariance (LPI). In this paper we propose to use stable clocks in eccentric orbits to perform a test of the gravitational redshift, a consequence of the LPI. The best test to date was performed with the Gravity Probe A (GP-A) experiment in 1976 with an uncertainty of $1.4\times10^{-4}$. Our proposal considers the opportunity of using Galileo satellites 5 and 6 to improve on the GP-A test uncertainty. We show that considering realistic noise and systematic effects, and thanks to a highly eccentric orbit, it is possible to improve on the GP-A limit to an uncertainty around $(3-4)\times 10^{-5}$ after one year of integration of Galileo 5 and 6 data.Comment: 13 pages, 5 figures, accepted in Classical and Quantum Gravity as a Fast Track Communicatio

Aeroacoustic effects of reduced aft tip speed at constant thrust for a model counterrotation turboprop at takeoff conditions

A model high-speed, advanced counterrotation propeller, F7/A7, was tested in the anechoic wind tunnel at simulated takeoff and approach conditions of Mach 0.2. The propeller was operated in a baseline configuration with the forward and aft rotor blade setting angles and forward and aft rotational speeds essentially equal. Two additional configurations were tested with the aft rotor at increased blade setting angles and the rotational speed reduced to achieve overall performance similar to that of the baseline configuration. Acoustic data were taken with an axially translating microphone probe that was attached to the tunnel floor. Concurrent aerodynamic data were taken to define propeller operating conditions

Coherent spin control by electrical manipulation of the magnetic anisotropy

High-spin paramagnetic manganese defects in polar piezoelectric zinc oxide exhibit a simple almost axial anisotropy and phase coherence times of the order of a millisecond at low temperatures. The anisotropy energy is tunable using an externally applied electric field. This can be used to control electrically the phase of spin superpositions and to drive spin transitions with resonant microwave electric fields

Noise of a model counterrotation propeller with simulated fuselage and support pylon at takeoff/approach conditions

Two modern high-speed advanced counterrotation propellers, F7/A7 and F7/A3 were tested in the NASA Lewis Research Centers's 9- by 15-foot Anechoic Wind Tunnel at simulated takeoff/approach conditions of 0.2 Mach number. Both rotors were of similar diameter on the F7/A7 propeller, while the aft rotor diameter of the F7/A3 propeller was 85 percent of the forward propeller to reduce tip vortex-aft rotor interaction. The two propellers were designed for similar performance. The propellers were tested in both the clean configuration, and installed configuration consisting of a simulated upstream nacelle support pylon and fuselage section. Acoustic measurements were made with an axially translating microphone probe, and with a polar microphone probe which was fixed to the propeller nacelle and could make both sideline and circumferential acoustic surveys. Aerodynamic measurements were also made to establish propeller operating conditions. The propellers were run at blade setting angles (fron angle/rear angle) of 41.1/39.4 deg for the F7/A7 propeller, and 41.1/46.4 deg for the F7/A3 propeller. The forward rotors were tested over a range of tip speeds from 165 to 259 m/sec (540 to 850 ft/sec), and both propellers were tested at the maximum rotor-rotor spacing, based on pitch change axis separation, of 14.99 cm (5.90 in.). The data presented in this paper are for 0 deg propeller axis angle of attack. Results are presented for the baseline, pylon-alone, and strut + fuselage configurations. The presence of the simulated fuselage resulted in higher rotor-alone tone levels in a direction normal to the advancing propeller blade near the fuselage. A corresponding rotor-alone tone reduction was often observed 180 deg circumferentially from this region of increased noise. A significant rotor-alone increase for both rotors was observed diametrically opposite the fuselage. In some cases, interaction tone levels were likewise affected by the simulated installation

Mars Encounters cause fresh surfaces on some near-Earth asteroids

All airless bodies are subject to the space environment, and spectral differences between asteroids and meteorites suggest many asteroids become weathered on very short (<1My) timescales. The spectra of some asteroids, particularly Q-types, indicate surfaces that appear young and fresh, implying they have been recently been exposed. Previous work found that Earth encounters were the dominant freshening mechanism and could be responsible for all near-Earth object (NEO) Q-types. In this work we increase the known NEO Q-type sample of by a factor of three. We present the orbital distributions of 64 Q-type near-Earth asteroids, and seek to determine the dominant mechanisms for refreshing their surfaces. Our sample reveals two important results: i) the relatively steady fraction of Q-types with increasing semi-major axis and ii) the existence of Q-type near-Earth asteroids with Minimum Orbit Intersection Distances (MOID) that do not have orbit solutions that cross Earth. Both of these are evidence that Earth-crossing is not the only scenario by which NEO Q-types are freshened. The high Earth-MOID asteroids represent 10% of the Q-type population and all are in Amor orbits. While surface refreshing could also be caused by Main Belt collisions or mass shedding from YORP spinup, all high Earth-MOID Q-types have the possibility of encounters with Mars indicating Mars could be responsible for a significant fraction of NEOs with fresh surfaces.Comment: Accepted for publication in Icarus -- 14 pages, 8 figures, 1 table, 2 appendice

Strong lensing time delay: a new way of measuring cosmic shear

The phenomenon of cosmic shear, or distortion of images of distant sources unaccompanied by magnification, is an effective way of probing the content and state of the foreground Universe, because light rays do not have to pass through mass structures in order to be sheared. It is shown that the delay in the arrival times between two simultaneously emitted photons that appear to be arriving from a pair of images of a strongly lensed cosmological source contains not only information about the Hubble constant, but also the long range gravitational effect of galactic scale mass clumps located away from the light paths in question. This is therefore also a method of detecting shear. Data on time delays among a sample of strongly lensed sources can provide crucial information about whether extra dynamics beyond gravity and dark energy are responsible for the global flatness of space. If the standard $\Lambda CDM$ model is correct, there should be a large dispersion in the value of $H_0$ as inferred from the delay data by (the usual procedure of) ignoring the effect of all other mass clumps except the strong lens itself. The fact that there has not been any report of a significant deviation from the $h =$ 0.7 mark during any of the $H_0$ determinations by this technique may already be pointing to the absence of the random effect discussed here.Comment: ApJ in pres

What was a mortarium used for? Organic residues and cultural change in Iron Age and Roman Britain.

The Romans brought the mortarium to Britain in the first century AD, and there has long been speculation on its actual purpose. Using analysis of the residues trapped in the walls of these ‘kitchen blenders’ and comparing them with Iron Age and Roman cooking pots, the authors show that it wasn't the diet that changed — just the method of preparing certain products: plants were being ground in the mortarium as well as cooked in the pot. As well as plants, the mortars contained animal fats, including dairy products. The question that remains, however, is why these natural products were being mixed together in mortaria. Were they for food, pharmaceuticals or face creams?</jats:p

Environment assisted degradation mechanisms in advanced light metals

The general goals of the research program are to characterize alloy behavior quantitatively and to develop predictive mechanisms for environmental failure modes. Successes in this regard will provide the basis for metallurgical optimization of alloy performance, for chemical control of aggressive environments, and for engineering life prediction with damage tolerance and long term reliability