5,620 research outputs found
Multidimensional spectroscopy with a single broadband phase-shaped laser pulse
We calculate the frequency-dispersed nonlinear transmission signal of a
phase-shaped visible pulse to fourth order in the field. Two phase profiles, a
phase-step and phase-pulse, are considered. Two dimensional signals obtained by
varying the detected frequency and phase parameters are presented for a three
electronic band model system. We demonstrate how two-photon and stimulated
Raman resonances can be manipulated by the phase profile and sign, and selected
quantum pathways can be suppressed.Comment: 26 pages, 15 figure
Nitric oxide and iron signaling cues have opposing effects on biofilm development in Pseudomonas aeruginosa
© 2019 American Society for Microbiology. While both iron and nitric oxide (NO) are redox-active environmental signals shown to regulate biofilm development, their interaction and roles in regulating biofilms have not been fully elucidated. In this study, exposure of Pseudomonas aeruginosa biofilms to exogenous NO inhibited the expression of iron acquisition-related genes and the production of the siderophore pyoverdine. Furthermore, supplementation of the culture medium with high levels of iron (100μM) counteracted NO-induced biofilm dispersal by promoting the rapid attachment of planktonic cells. In the presence of iron, biofilms were found to disperse transiently to NO, while the freshly dispersed cells reattached rapidly within 15 min. This effect was not due to the scavenging of NO by free iron but involved a cellular response induced by iron that led to the elevated production of the exopolysaccharide Psl. Interestingly, most Psl remained on the substratum after treatment with NO, suggesting that dispersal involved changes in the interactions between Psl and P. aeruginosa cells. Taken together, our results suggest that iron and NO regulate biofilm development via different pathways, both of which include the regulation of Psl-mediated attachment. Moreover, the addition of an iron chelator worked synergistically with NO in the dispersal of biofilms
The cross-sectional and longitudinal relationship between overgeneral autobiographical memory and adolescent depression in a UK population-based cohort
Background: Overgeneral autobiographical memory (OGM), the tendency to recall fewer specific memories and recall more repeated or extended events, is associated with subsequent adult depression. However, prospective associations are only found in adolescents with additional risk factors for depression (e.g. OGM for negative material is associated with subsequent depression in females and those at familial risk of depression) and not in community samples. It remains unclear whether OGM is associated with subsequent depression in population-based adolescent samples or just in high-risk adolescents.
Methods: We examined the relationship between OGM for negative cues (age 13) and adolescent depressive symptoms in a population-based cohort - the Avon Longitudinal Study of Parents and Children. Regression models investigated the association of OGM for negative cues with depressive symptoms at age 12.5 years (n = 3,145) and age 16.5 years (n = 2,345). Associations with alternative measures of OGM were also explored. Gender and maternal depression were examined as potential moderators of these relationships.
Results: OGM for negative cues was associated with both contemporaneous and prospective depressive symptoms. Only OGM for negative cues and total OGM were prospectively associated with depressive symptoms. There was no evidence of moderation by gender or maternal depression
Theory for high spin systems with orbital degeneracy
High-spin systems with orbital degeneracy are studied in the large spin
limit. In the absence of Hund's coupling, the classical spin model is mapped
onto disconnected orbital systems with spins up and down, respectively. The
ground state of the isotropic model is an orbital valence bond state where each
bond is an orbital singlet with parallel spins, and neighbouring bonds interact
antiferromagnetically. The possible relevance to the transition metal oxides
are discussed.Comment: 4 page, three figures, to appear in Phys. Rev. Let
Uncovering predictability in the evolution of the WTI oil futures curve
Accurately forecasting the price of oil, the world's most actively traded
commodity, is of great importance to both academics and practitioners. We
contribute by proposing a functional time series based method to model and
forecast oil futures. Our approach boasts a number of theoretical and practical
advantages including effectively exploiting underlying process dynamics missed
by classical discrete approaches. We evaluate the finite-sample performance
against established benchmarks using a model confidence set test. A realistic
out-of-sample exercise provides strong support for the adoption of our approach
with it residing in the superior set of models in all considered instances.Comment: 28 pages, 4 figures, to appear in European Financial Managemen
Accelerator Design for the CHESS-U Upgrade
During the summer and fall of 2018 the Cornell High Energy Synchrotron Source
(CHESS) is undergoing an upgrade to increase high-energy flux for x-ray users.
The upgrade requires replacing one-sixth of the Cornell Electron Storage Ring
(CESR), inverting the polarity of half of the CHESS beam lines, and switching
to single-beam on-axis operation. The new sextant is comprised of six
double-bend achromats (DBAs) with combined-function dipole-quadrupoles.
Although the DBA design is widely utilized and well understood, the constraints
for the CESR modifications make the CHESS-U lattice unique. This paper
describes the design objectives, constraints, and implementation for the CESR
accelerator upgrade for CHESS-U
Anomalous acoustic reflection on a sliding interface or a shear band
We study the reflection of an acoustic plane wave from a steadily sliding
planar interface with velocity strengthening friction or a shear band in a
confined granular medium. The corresponding acoustic impedance is utterly
different from that of the static interface. In particular, the system being
open, the energy of an in-plane polarized wave is no longer conserved, the work
of the external pulling force being partitioned between frictional dissipation
and gain (of either sign) of coherent acoustic energy. Large values of the
friction coefficient favor energy gain, while velocity strengthening tends to
suppress it. An interface with infinite elastic contrast (one rigid medium) and
V-independent (Coulomb) friction exhibits spontaneous acoustic emission, as
already shown by M. Nosonovsky and G.G. Adams (Int. J. Ing. Sci., {\bf 39},
1257 (2001)). But this pathology is cured by any finite elastic contrast, or by
a moderately large V-strengthening of friction.
We show that (i) positive gain should be observable for rough-on-flat
multicontact interfaces (ii) a sliding shear band in a granular medium should
give rise to sizeable reflection, which opens a promising possibility for the
detection of shear localization.Comment: 13 pages, 10 figure
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