Fresco Paintings: Development of an Aging Model from 1064 nm Excited Raman Spectra

In this study, we proposed a preliminary kinetic model applied to the carbonation process of fresh lime with the intention to realize a diagnostic tool for aged fresco paintings. The model can be useful, in particular, in the fields of conservation and restoration of ancient lime wall paintings. The dating procedure was achieved through the analysis of 1064 nm excited Raman spectra collected on artificially aged lime samples in addition to ancient samples taken from literature and covering a period of two thousand years. The kinetic model was developed monitoring the concentration of emitting defective centers related to the intensity of 780 cm−1 calcium hydroxide band as a function of the time and depth. This preliminary model shows how Raman spectroscopy, especially NIR micro-Raman, is advantageous for diagnostics and conservation in the cultural heritage field

The medical historical cultural foundations of western nasal surgery from ancient greece to the middle ages

The manuscript aims to clarify the origins of Western rhinosurgery through the ancient texts of the greatest physicians of the past, up to the Byzantine Era, focusing on the "exchange of knowledge" between peoples. This excursus is carried out by quoting the texts of the greatest doctors of the past, such as Hippocrates, Galen and Celsus and by analysing the works of Byzantine authors such as Oribasius, Aetius, Antillus, which, more than others, represent the moment of fusion and interpenetration of Ancient Medical knowledge, paving the way for the Medieval Scholae Medicae in the West. The aim, therefore, is to fill that sort of "great gap" (from the foundation of Constantinople in the 4th century AD to the early Arab culture in the 11th century AD) due to the fact that figures such as Branca, Vianeo and, finally, Tagliacozzi, are considered direct actors of a recovery of the "ancient knowledge" of classic authors. This literature tends to less evaluate, instead, that important and huge cultural exchange -literally osmotic- in medical and surgical knowledge between peoples and civilizations, that find a trait d'union in the application of medical knowledge and surgical practical techniques matured in the Byzantine, Arab and Early Medieval period. In final analysis, through the History of Rhinosurgery, this paper aims to highlight how Western medical knowledge is made up of the ensemble of cultures which are apparently distant and different from each other, which merge themselves in a truly universal and transcultural knowledge: the Medical knowledge

Optimizing the Mechanoluminescent Properties of CaZnOS:Tb via Microwave-Assisted Synthesis: A Comparative Study with Conventional Thermal Methods

Recent developments in lighting and display technologies have led to an increased focus on materials and phosphors with high efficiency, chemical stability, and eco-friendliness. Mechanoluminescence (ML) is a promising technology for new lighting devices, specifically in pressure sensors and displays. CaZnOS has been identified as an efficient ML material, with potential applications as a stress sensor. This study focuses on optimizing the mechanoluminescent properties of CaZnOS:Tb through microwave-assisted synthesis. We successfully synthesized CaZnOS doped with Tb3+ using this method and compared it with samples obtained through conventional solid-state methods. We analyzed the material's characteristics using various techniques to investigate their structural, morphological, and optical properties. We then studied the material's mechanoluminescent properties through single impacts with varying energies. Our results show that materials synthesized through microwave methods exhibit similar optical and, primarily, mechanoluminescent properties, making them suitable for use in photonics applications. The comparison of the microwave and conventional solid-state synthesis methods highlights the potential of microwave-assisted methods to optimize the properties of mechanoluminescent materials for practical applications

The complex surgical management of the first case of severe combined immunodeficiency and multiple intestinal atresias surviving after the fourth year of life

Severe combined immunodeficiency (SCID) is a life-threatening syndrome of recurrent infections and gastrointestinal alterations due to severe compromise of T cells and B cells. Clinically, most patients present symptoms before the age of 3 months and without intervention SCID usually results in severe infections and death by the age of 2 years. Its association with intestinal anomalies as multiple intestinal atresias (MIA) is rare and worsens the prognosis, resulting lethal. We describe the case of a four year-old boy with SCID-MIA. He presented at birth with meconium peritonitis, multiple ileal atresias and underwent several intestinal resections. A targeted Sanger sequencing revealed a homozygous 4-bp deletion (c.313ΔTATC; p.Y105fs) in tetratricopeptide repeat domain 7A (TTC7A). He experienced surgical procedures including resection and stricturoplasty. Despite parenteral nutrition-associated liver disease, the patient is surviving at the time of writing the report. Precocious immune system assessment, scrutiny of TTC7A mutations and prompt surgical procedures are crucial in the management

Pyogenic Granuloma of the Sigmoid Colon causing Intussusception in an Infant

Pyogenic granuloma is a benign vascular tumor that may affect the gastrointestinal tract. This report describes a rare case of sigmoid-colon pyogenic granuloma in a 4-month-old boy causing intussusception. Resection and anastomosis were curative. The mother had history of high dose of progesterone exposure during initial weeks of conception for vaginal bleeding. This may point towards etiology of the lesion

Interpreting Psychophysiological States Using Unobtrusive Wearable Sensors in Virtual Reality

One of the main challenges in the study of human be- havior is to quantitatively assess the participants’ affective states by measuring their psychophysiological signals in ecologically valid conditions. The quality of the acquired data, in fact, is often poor due to artifacts generated by natural interactions such as full body movements and gestures. We created a technology to address this problem. We enhanced the eXperience Induction Machine (XIM), an immersive space we built to conduct experiments on human behavior, with unobtrusive wearable sensors that measure electrocardiogram, breathing rate and electrodermal response. We conducted an empirical validation where participants wearing these sensors were free to move in the XIM space while exposed to a series of visual stimuli taken from the International Affective Picture System (IAPS). Our main result consists in the quan- titative estimation of the arousal range of the affective stimuli through the analysis of participants’ psychophysiological states. Taken together, our findings show that the XIM constitutes a novel tool to study human behavior in life-like conditions

GIANO and HARPS-N together: towards an Earth-mass detection instrument

This article describes the works we are doing for modifying the interface between the high resolution infrared spectrograph GIANO (0.97-2.4 micron) and the TNG telescope, passing from a fiber feed configuration to the original design of a direct light-feeding from the telescope to the spectrograph. So doing the IR spectrograph, GIANO, will work in parallel to HARPS-N spectrometer (0.38-0.70 micron), the visible high resolution spectrograph, thanks to a new telescope interface based on a dichroic window that simultaneously feeds the two instrumentes: this is GIARPS (GIAno and haRPS). The scientific aims of this project are to improve the radial velocity accuracy achievable with GIANO, down to a goal of 1 m/s, the value necessary to detect Earth-mass planets on habitable orbits around late-M stars, to implement simultaneous observations with Harps-N and GIANO optimizing the study of planets around cool stars. The very broad wavelengths range is particularly important to discriminate false radial velocity signals caused by stellar activity. We therefore include several absorption cells with different mixtures of gases and a stabilized Fabry Perot cavity, necessary to have absorption lines over the 0.97-2.4 microns range covered by GIANO. The commissioning of GIARPS is scheduled by the end of 2016

Investigation of scaling laws for magnetically shielded Hall thrusters

Osservazioni intorno alla scalatura dei motori a effetto Hall (HETs)utilizzati nella propulsione spaziale a bassa spinta, con speciale riferimento alla tipologia di motori schermati magneticamente ad evitare l'erosione delle pareti del canale in materiale ceramico contenente il plasma