Surface site density, silicic acid retention and transport properties of compacted magnetite powder

International audienc

Modeling the complexation properties of mineral-bound organic polyelectrolyte: An attempt at comprehension using the model system alumina/polyacrylic acid/M (M = Eu, Cm, Gd)

International audienceThis paper contributes to the comprehension of kinetic and equilibrium phenomena governing metal ion sorption on organic-matter-coated mineral particles. Sorption and desorption experiments were carried out with Eu ion and polyacrylic acid (PAA)-coated alumina colloids at pH 5 in 0.1 M NaClO4 as a function of the metal ion loading. Under these conditions, M interaction with the solid is governed by sorbed PAA (PAAads). The results were compared with spectroscopic data obtained by time-resolved laser-induced fluorescence spectroscopy (TRLFS) with Cm and Gd. The interaction between M and PAAads was characterized by a kinetically controlled process: after rapid metal adsorption within less than 1 min, the speciation of complexed M changed at the particle surface till an equilibrium was reached after about 4 days. At equilibrium, one part of complexed M was shown to be not exchangeable. This process was strongly dependent on the ligand-to-metal ratio. Two models were tested to explain the data. In model 1, the kinetically controlled process was described through successive kinetically controlled reactions that follow the rapid metal ion adsorption. In model 2, the organic layer was considered as a porous medium: the kinetic process was explained by the diffusion of M from the surface into the organic layer. Model 1 allowed a very good description of equilibrium and kinetic experimental data. Model 2 could describe the data at equilibrium but could not explain the kinetic data accurately. In spite of this disagreement, model 2 appeared more realistic considering the results of the TRLFS measurements

Endomorphisms of superelliptic jacobians

Let K be a field of characteristic zero, n>4 an integer, f(x) an irreducible polynomial over K of degree n, whose Galois group is doubly transitive simple non-abelian group. Let p be an odd prime, Z[\zeta_p] the ring of integers in the p-th cyclotomic field, C_{f,p}:y^p=f(x) the corresponding superelliptic curve and J(C_{f,p}) its jacobian. Assuming that either n=p+1 or p does not divide n(n-1), we prove that the ring of all endomorphisms of J(C_{f,p}) coincides with Z[\zeta_p].Comment: Several typos have been correcte

Midwave infrared InAs/GaSb superlattice photodiode with a dopant-free p–n junction

Midwave infrared (MWIR) InAs/GaSb superlattice (SL) photodiode with a dopant-free p–n junction was fabricated by molecular beam epitaxy on GaSb substrate. Depending on the thickness ratio between InAs and GaSb layers in the SL period, the residual background carriers of this adjustable material can be either n-type or p-type. Using this flexibility in residual doping of the SL material, the p–n junction of the device is made with different non-intentionally doped (nid) SL structures. The SL photodiode processed shows a cut-off wavelength at 4.65 μm at 77 K, residual carrier concentration equal to 1.75 × 1015 cm−3, dark current density as low as 2.8 × 10−8 A/cm2 at 50 mV reverse bias and R0A product as high as 2 × 106 Ω cm2. The results obtained demonstrate the possibility to fabricate a SL pin photodiode without intentional doping the pn junction

Encoding multistate charge order and chirality in endotaxial heterostructures

Intrinsic resistivity changes associated with charge density wave (CDW) phase transitions in 1T-TaS$_2$ hold promise for non-volatile memory and computing devices based on the principle of phase change memory (PCM). High-density PCM storage is proposed for materials with multiple intermediate resistance states, which have been observed in 1T-TaS$_2$. However, the metastability responsible for this behavior makes the presence of multistate switching unpredictable in 1T-TaS$_2$ devices. Here, we demonstrate the synthesis of nanothick verti-lateral 1H-TaS$_2$/1T-TaS$_2$ heterostructures in which the number of endotaxial metallic 1H-TaS$_2$ monolayers dictates the number of high-temperature resistance transitions in 1T-TaS$_2$ lamellae. Further, we also observe optically active heterochirality in the CDW superlattice structure, which is modulated in concert with the resistivity steps. This thermally-induced polytype conversion nucleates at folds and kinks where interlayer translations that relax local strain favorably align 1H and 1T layers. This work positions endotaxial TaS$_2$ heterostructures as prime candidates for non-volatile device schemes implementing coupled switching of structure, chirality, and resistance

Modular symbols in Iwasawa theory

This survey paper is focused on a connection between the geometry of $\mathrm{GL}_d$ and the arithmetic of $\mathrm{GL}_{d-1}$ over global fields, for integers $d \ge 2$. For $d = 2$ over $\mathbb{Q}$, there is an explicit conjecture of the third author relating the geometry of modular curves and the arithmetic of cyclotomic fields, and it is proven in many instances by the work of the first two authors. The paper is divided into three parts: in the first, we explain the conjecture of the third author and the main result of the first two authors on it. In the second, we explain an analogous conjecture and result for $d = 2$ over $\mathbb{F}_q(t)$. In the third, we pose questions for general $d$ over the rationals, imaginary quadratic fields, and global function fields.Comment: 43 page

Denominators of Eisenstein cohomology classes for GL_2 over imaginary quadratic fields

We study the arithmetic of Eisenstein cohomology classes (in the sense of G. Harder) for symmetric spaces associated to GL_2 over imaginary quadratic fields. We prove in many cases a lower bound on their denominator in terms of a special L-value of a Hecke character providing evidence for a conjecture of Harder that the denominator is given by this L-value. We also prove under some additional assumptions that the restriction of the classes to the boundary of the Borel-Serre compactification of the spaces is integral. Such classes are interesting for their use in congruences with cuspidal classes to prove connections between the special L-value and the size of the Selmer group of the Hecke character.Comment: 37 pages; strengthened integrality result (Proposition 16), corrected statement of Theorem 3, and revised introductio

Equidistribution of Heegner Points and Ternary Quadratic Forms

We prove new equidistribution results for Galois orbits of Heegner points with respect to reduction maps at inert primes. The arguments are based on two different techniques: primitive representations of integers by quadratic forms and distribution relations for Heegner points. Our results generalize one of the equidistribution theorems established by Cornut and Vatsal in the sense that we allow both the fundamental discriminant and the conductor to grow. Moreover, for fixed fundamental discriminant and variable conductor, we deduce an effective surjectivity theorem for the reduction map from Heegner points to supersingular points at a fixed inert prime. Our results are applicable to the setting considered by Kolyvagin in the construction of the Heegner points Euler system

Towards the empowered commuter : exploring information behaviour of informal public transport users

Papers presented virtually at the 41st International Southern African Transport Conference on 10-13 July 2023.Information is emerging as one of the key dimensions of mobility, and as an important lever through which sustainable access can be promoted in Sub-Saharan African (SSA) cities. Information acts as an enabler of transport, by allowing travellers to make informed decisions on whether, when, and how they travel. The lack of information can also act as a barrier to accessing desired services, with consequences for the attainment of equity and human development goals. Little is known about what information passengers need and how they find and use information. This paper reports on a qualitative mixed-methods study to explore information behaviour amongst informal transport passengers in Tshwane, South Africa. We use the theory and methods of information science (with information behaviour as a subdiscipline) to provide a lens for the investigation. We collected mobility data through travel diaries, user-submitted photos of the travel context and voice messages to explain these, and in-depth individual interviews combined with drawings of situations where respondents used information and its sources (called information horizon mappings). The drawings and interviews revealed the information-poor environment within which informal transport operates, and the strong reliance on other people as well as tacit embedded knowledge for gaining access to information. The paper concludes by offering directions for further research around digital information

Endomorphism algebras of Abelian varieties with special reference to superelliptic Jacobians

This is (mostly) a survey article. We use an information about Galois properties of points of small order on an Abelian variety in order to describe its endomorphism algebra over an algebraic closure of the ground field. We discuss in detail applications to jacobians of cyclic covers of the projective line