7 research outputs found
Dislocation core structures in Si-doped GaN
Aberration-corrected scanning transmission electron microscopy was used to investigate the core structures of threading dislocations in plan-view geometry of GaN films with a range of Si-doping levels and dislocation densities ranging between (5 ± 1) × 108 and (10 ± 1) × 109 cm−2. All a-type (edge) dislocation core structures in all samples formed 5/7-atom ring core structures, whereas all (a + c)-type (mixed) dislocations formed either double 5/6-atom, dissociated 7/4/8/4/9-atom, or dissociated 7/4/8/4/8/4/9-atom core structures. This shows that Si-doping does not affect threading dislocation core structures in GaN. However, electron beam damage at 300 keV produces 4-atom ring structures for (a + c)-type cores in Si-doped GaN.This work was funded in part by the Cambridge Commonwealth trust, St. John's College, British Federation of Women Graduates and the EPSRC. M.A.M. acknowledges the support from the Royal Society through a University Research Fellowship. Additional support was provided by the EPSRC through the UK National Facility for Aberration-Corrected STEM (SuperSTEM).This is the author accepted manuscript. The final version is available from AIP via http://dx.doi.org/10.1063/1.493745
Segregation of In to dislocations in InGaN.
Dislocations are one-dimensional topological defects that occur frequently in functional thin film materials and that are known to degrade the performance of InxGa1-xN-based optoelectronic devices. Here, we show that large local deviations in alloy composition and atomic structure are expected to occur in and around dislocation cores in InxGa(1-x)N alloy thin films. We present energy-dispersive X-ray spectroscopy data supporting this result. The methods presented here are also widely applicable for predicting composition fluctuations associated with strain fields in other inorganic functional material thin films.This work was funded in part by the Cambridge Commonwealth trust, St. John’s College and
the EPSRC. SKR is funded through the Cambridge-India Partnership Fund and Indian Institute
of Technology Bombay via a scholarship. MAM acknowledges support from the Royal Society
through a University Research Fellowship. Additional support was provided by the EPSRC
through the UK National Facility for Aberration-Corrected STEM (SuperSTEM). The Titan 80-
200kV ChemiSTEMTM was funded through HM Government (UK) and is associated with the
capabilities of the University of Manchester Nuclear Manufacturing (NUMAN) capabilities. SJH
acknowledges funding from the Defence Treat Reduction Agency (DTRA) USA (grant number
HDTRA1-12-1-0013).This is the accepted manuscript. The final version is available at http://pubs.acs.org/doi/abs/10.1021/nl5036513
Atomic resolution imaging of dislocations in algan and the efficiency of UV LEDs
[Abstract not available
Dislocations in AlGaN: Core Structure, Atom Segregation and Optical Properties
We conducted a comprehensive investigation of dislocations in Al0.46Ga0.54N. Using aberration-corrected scanning transmission electron microscopy and energy dispersive X-ray spectroscopy, the atomic structure and atom distribution at the dislocation core have been examined. We report that the core configuration of dislocations in AlGaN is consistent with that of other materials in the III-Nitride system. However, we observed that the dissociation of mixed-type dislocations is impeded by alloying GaN with AlN, which is confirmed by our experimental observation of Ga and Al atom segregation in the tensile and compressive parts of the dislocations, respectively. Investigation of the optical properties of the dislocations shows that the atom segregation at dislocations has no significant effect on the intensity recorded by cathodoluminescence in the vicinity of the dislocations. These results are in contrast with the case of dislocations in In0.09Ga0.91N where segregation of In and Ga atoms also occurs but results in carrier localization limiting non-radiative recombination at the dislocation. This study therefore sheds light on why InGaN-based devices are generally more resilient to dislocations than their AlGaN-based counterparts
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Research data supporting "Carrier Localization in the Vicinity of Dislocations in InGaN"
FIG. 1. AFM (a), SEM (b), panchromatic CL (c), and ADF-STEM (d) performed on the same micrometre-scale area. To guide the eye, a few dislocations are indicated by arrows in each picture. (e) High-resolution (HR) STEM image of the dislocation indicated by a square in (a)-(d), enabling the identification of the core structure (here dissociated 7/4/8/5-atom ring), and (f) geometric phase analysis (GPA) showing the e_xx strain component of the dislocation core region.
FIG. 2. Schematic showing the electron probe in the SEM-CL scanning across a V-pit. The scale of the schematic, although indicative, is representative of the experimental conditions in which the experiment was conducted. Distance to nearest neighbor dependence of the intensity ratio (a)(c) and energy shift (b)(d) measured at the center (a)(b) and facet (c)(d) of the V-pits.
FIG. 3. (a) Histogram of the number of In-N chains as a function of the number of indium atoms in the chains, located within a 10 A radius centered on the dislocation, in the case of a random distribution of indium (i.e. initial configuration of the simulation) or segregation of indium (i.e. equilibrium configuration of the simulation). Abstract representation of the data in (a), in the case of a random distribution (b) or segregation (c) of indium atoms.
FIG. 4. ADF-STEM image of the clustered dislocations 26 (a) and 87 (b). The white strain-related contrast between the neighboring dislocations is indicated by an arrow. Aberration-corrected HAADF-STEM image of the core of dislocation 26 (dissociated 7/4/8/4/9-atom ring)(c) and 87 (undissociated double 5/6-atom ring)(d). An ABSF-filter (Average Background Subtraction Filter) has been applied to (c) and (d) in order to remove noise from the images.
FIG. 5. 16K CL integrated intensity (a)(c) and peak emission energy (b)(d) maps of isolated
(a)(b) and clustered (c)(d) dislocations. To guide the eye, the position of the bright spots, directly observable in (a) and (c), is indicated by circles in all the maps. To emphasize the relative variations in intensity and energy between isolated and clustered configurations, a common color scale is used in (a) and (c) and in (b) and (d).This work was supported by the EC [FP7/2007-2013 279361], EPSRC, ESTEEM2 and Cambridge Philosophical Society