Synthesis, structure, and opto-electronic properties of organic-based nanoscale heterojunctions

Enormous research effort has been put into optimizing organic-based opto-electronic systems for efficient generation of free charge carriers. This optimization is mainly due to typically high dissociation energy (0.1-1 eV) and short diffusion length (10 nm) of excitons in organic materials. Inherently, interplay of microscopic structural, chemical, and opto-electronic properties plays crucial role. We show that employing and combining advanced scanning probe techniques can provide us significant insight into the correlation of these properties. By adjusting parameters of contact- and tapping-mode atomic force microscopy (AFM), we perform morphologic and mechanical characterizations (nanoshaving) of organic layers, measure their electrical conductivity by current-sensing AFM, and deduce work functions and surface photovoltage (SPV) effects by Kelvin force microscopy using high spatial resolution. These data are further correlated with local material composition detected using micro-Raman spectroscopy and with other electronic transport data. We demonstrate benefits of this multi-dimensional characterizations on (i) bulk heterojunction of fully organic composite films, indicating differences in blend quality and component segregation leading to local shunts of photovoltaic cell, and (ii) thin-film heterojunction of polypyrrole (PPy) electropolymerized on hydrogen-terminated diamond, indicating covalent bonding and transfer of charge carriers from PPy to diamond

A Synthesis of the Dibble et al. Controlled Experiments into the Mechanics of Lithic Production

Archaeologists have explored a wide range of topics regarding archaeological stone tools and their connection to past human lifeways through experimentation. Controlled experimentation systematically quantifies the empirical relationships among different flaking variables under a controlled and reproducible setting. This approach offers a platform to generate and test hypotheses about the technological decisions of past knappers from the perspective of basic flaking mechanics. Over the past decade, Harold Dibble and colleagues conducted a set of controlled flaking experiments to better understand flake variability using mechanical flaking apparatuses and standardized cores. Results of their studies underscore the dominant impact of exterior platform angle and platform depth on flake size and shape and have led to the synthesis of a flake formation model, namely the EPA-PD model. However, the results also illustrate the complexity of the flake formation process through the influence of other parameters such as core surface morphology and force application. Here we review the work of Dibble and colleagues on controlled flaking experiments by summarizing their findings to date. Our goal is to synthesize what was learned about flake variability from these controlled experiments to better understand the flake formation process. With this paper, we are including all of the data produced by these prior experiments and an explanation of the data in the Supplementary Information

Initial Upper Palaeolithic humans in Europe had recent Neanderthal ancestry

Modern humans appeared in Europe by at least 45,000 years ago1–5, but the extent of their interactions with Neanderthals, who disappeared by about 40,000 years ago6, and their relationship to the broader expansion of modern humans outside Africa are poorly understood. Here we present genome-wide data from three individuals dated to between 45,930 and 42,580 years ago from Bacho Kiro Cave, Bulgaria1,2. They are the earliest Late Pleistocene modern humans known to have been recovered in Europe so far, and were found in association with an Initial Upper Palaeolithic artefact assemblage. Unlike two previously studied individuals of similar ages from Romania7 and Siberia8 who did not contribute detectably to later populations, these individuals are more closely related to present-day and ancient populations in East Asia and the Americas than to later west Eurasian populations. This indicates that they belonged to a modern human migration into Europe that was not previously known from the genetic record, and provides evidence that there was at least some continuity between the earliest modern humans in Europe and later people in Eurasia. Moreover, we find that all three individuals had Neanderthal ancestors a few generations back in their family history, confirming that the first European modern humans mixed with Neanderthals and suggesting that such mixing could have been common

Track A Basic Science

Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/138319/1/jia218438.pd

Experimental design and experimental inference in stone artifact archaeology

Lithic researchers rely heavily on experimentation to infer past behaviors and activities based on stone artifacts. This paper explores the analogical nature of archaeological inference and the relationship between experimental design and inference validity in stone artifact experimentation. We show that actualistic flintknapping lacks vital aspects of scientific experimentation, and thus has inherent inferential issues of analogical adequacy and confidence. It is argued that a greater emphasis on hypothesis construction and variable control is needed in order to establish sound referential linkages upon which constructive analogic inferences about the past can be built