121 research outputs found
Correlations in quantum thermodynamics: Heat, work, and entropy production
We provide a characterization of energy in the form of exchanged heat and
work between two interacting constituents of a closed, bipartite, correlated
quantum system. By defining a binding energy we derive a consistent quantum
formulation of the first law of thermodynamics, in which the role of
correlations becomes evident, and this formulation reduces to the standard
classical picture in relevant systems. We next discuss the emergence of the
second law of thermodynamics under certain---but fairly general---conditions
such as the Markovian assumption. We illustrate the role of correlations and
interactions in thermodynamics through two examples.Comment: 16 page
Zeno effect for quantum computation and control
It is well known that the quantum Zeno effect can protect specific quantum
states from decoherence by using projective measurements. Here we combine the
theory of weak measurements with stabilizer quantum error correction and
detection codes. We derive rigorous performance bounds which demonstrate that
the Zeno effect can be used to protect appropriately encoded arbitrary states
to arbitrary accuracy, while at the same time allowing for universal quantum
computation or quantum control.Comment: Significant modifications, including a new author. To appear in PR
Quantum discord and non-Markovianity of quantum dynamics
The problem of recognizing (non-)Markovianity of a quantum dynamics is
revisited through analyzing quantum correlations. We argue that
instantaneously-vanishing quantum discord provides a necessary and sufficient
condition for Markovianity of a quantum map. This is used to introduce a
measure of non-Markovianity. This measure, however, requires demanding
knowledge about the system and the environment. By using a quantum correlation
monogamy property and an ancillary system, we propose a simplified measure with
less requirements. Non-Markovianity is thereby decided by quantum state
tomography of the system and the ancilla.Comment: 5 pages, 3 figure
The Solid Phase Extraction of Some Metal Ions Using Palladium Nanoparticles Attached to Silica Gel Chemically Bonded by Silica-Bonded N-Propylmorpholine as New Sorbent prior to Their Determination by Flame Atomic Absorption Spectroscopy
In this research at first palladium nanoparticle attached to a new chemically bonded silica gel has been synthesized and has been characterized with different techniques such as X-ray diffraction (XRD), fourier transform infrared (FT-IR), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). Then, this new sorbent (chemically modified silica gel with N-propylmorpholine (PNP-SBNPM)) was efficiently used for preconcentration of some metal ions in various food samples. The influence of effective variables including mass of sorbent, flow rate, pH of sample solutions and condition of eluent such as volume, type and concentration on the recoveries of understudy metal ions were investigated. Following the optimization of variables, the interfering effects of some foreign ions on the preconcentration and determination of the investigated metal ions described. At optimum values of variables, all investigated metal ions were efficiently recovered with efficiency more than 95%, relative standard deviation (RSD) between 2.4 and 2.8, and detection limit in the range of 1.4–2.7 ng mL−1. The present method is simple and rapidly applicable for the determination of the understudied metal ions (ng mL−1) in different natural food samples
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