Optimization of Biogas Production Process in Solid State Digesters in Semiarid Areas of Northern Tanzania

Solid state digestion process has received much attention due to its low water requirements, making it preferred in semi-arid areas as well. In this study, the performance of the household solid state digesters was evaluated through monitoring of the feedstock mixing ratios and using the digester gas pressure as a measure of performance. Additionally, a batch study to verify the appropriate and optimal mixing ratio of feedstocks was also done. The mixing ratios of cow dung to water ranged from 2:1, 3:1 and 4:1. Total solids determined were 120, 150 and 170 mg/g for the ratios 2:1, 3:1 and 4:1, respectively. Biogas yield for 2:1, 3:1 and 4:1 mixing ratios in laboratory batch mode were 21.4, 22.7 and 46.4 mL/gVS, respectively. These results from a practical scenario show a promising future of the technology which can be adopted by all solid state digester users living in dry areas. Key words: Cowdung, Biogas, Mixing ratio, Batch solid state anaerobic digeste

In-situ synthesis of calcium/magnesium phosphate system for water de-fluoridation: Clay ceramic materials

This research article was published, Elsevier, Volume 278Clay ceramic water filters impregnated with silver colloids have been used to purify water in many parts of East Africa disregarding the removal of fluoride, which is a health-threatening ion in water supplies. This paper presents a synthesis of clay ceramic materials containing in-situ generated calcium/magnesium phosphate system as an adsorbent for water de-fluoridation. The materials were prepared in varied ratios of clay (K) to heat-pretreated dolostone (R) (K:R = 0:100, 90∶10, 85∶15, 75∶25 and 100:0), sintered at temperatures between 500 °C and 900 °C, and characterized using XRF, AAS, CHNS–O analyzer and X-ray PDF analysis. The materials improved in de-fluoridation performance with increase in sintering temperature at 500–700 °C, before exhibiting a sharp drop at 800 °C. The adsorption performance of K:R = 75:25 was higher than that of K:R = 0:100, signifying the effect of clay. The adsorption data obeyed Freundlich isotherm model, suggesting multi-layer adsorption. Fluoride uptake follows pseudo-second-order and intra-particle diffusion models, which suggests a chemisorption process involving rate-limiting intra-particle diffusion

Effect of Elevated Temperature on Compressive Strength and Physical Properties of Neem Seed Husk Ash Concrete.

This research article published by MDPI, 2020High temperature rise mostly caused by a fire outbreak is currently becoming a threat that endangers concrete's structural performance for buildings and the safety of occupants. The behavior of concrete after fire subjection has been of much interest for the structural materials design purposes. This study investigated the physical properties and the compressive strength of M25 concrete incorporating Neem Seed Husk Ash (NSHA), exposed to and through targeted different levels of temperature (200 °C to 800 °C) for a period of three hours in an electric furnace. The NSHA was produced by calcining neem seed husks at 800 °C for six hours and then sieved through the 125 μm sieve. Different amounts of NSHA were investigated while considering the plain concrete as the control sample. 150 concrete cubes of 150 mm sizes were cast and properly cured for 7 and 28 days. The experimental results show that the compressive strength of the 5% NSHA concrete exposed to temperatures up to 400 °C is 21.3% and 23.8% better than the normal concrete at 7 and 28 curing days, respectively. Surface cracks and spalling are noticeable at 600 °C and 800 °C for all samples considered in this study

Performance of water filters towards the removal of selected pollutants in Arusha, Tanzania.

This paper presents the findings of a study carried out to investigate the efficiency of selected common water filters in the removal of Escherichiacoli, organic matter and fluoride. Additionally, the Total Suspended Solids, Turbidity andcolour were also considered for assessing the performance of the filters in ensuring safe water provision. The results showedthat various filters performed differently at particular retention times. Removal of Escherichia coli, was found to be 100%, 75%, 96%, 96.5, 98.5%forbio-sand, slow sand, ceramic, bone char and membrane purifier respectively. Organic matter removal was found to be 47%, 43%, 53%, 43.4% for bio-sand, slow sand, ceramic and membrane purifier respectively, while, fluoride removal was found to be 95.5% for bone char filter. Furthermore, filters were also assessed in terms of media availability, buying costs, operation, benefits/ effectiveness towards major pollutants, and drawbacks. The study concluded that filters currently present in the market especially in Arusha are effective towards specific pollutants. To remove multiple pollutants, an integrated filter would be needed for optimized performance.Key words: water filters, water purification, E. coli, organic matter, fluorid

Numerical Analysis of Heat Exchanger for Spray-Assisted Low-Temperature Desalination System

This research article was published by Hindawi in 2020A numerical study for heat exchanger for spray-assisted low-temperature desalination system is presented for an existing low-temperature desalination unit at Arusha Technical College. This is aimed at recognizing the effect of mass flow and physical parameters like tube layout (diameter and length) on the overall heat transferred and the pressure drop in the shell-and-tube heat exchanger (STHX), as well as the impact of these parameters on the heat transfer coefficient and the overdesign of the STHX. Also, the study provides a suitable mathematical model for the replacement of the current condensation unit which tends to reduce energy consumption by reducing some of the electrical components in the system. A Math CAD model was developed using the Delaware method to obtain the mentioned parameters. The results show that at 0.8 kg/s flow rate a maximum heat transfer coefficient of 23212 W/m2K is achieved in a minimum diameter of 10 mm within a maximum tube length of 1000 mm heat exchanger and the pressure drop seems to be very low in a range of 0.328-0.957 Pa from all configurations. The configuration with 1000 mm tube length and 10 mm diameter performed well on the mass flow of 0.3 kg/s-0.8 kg/s by providing a suitable overall heat transfer coefficient of 2306-2539 W/m2K, while 12.8 is a maximum overdesign coefficient achieved on 0.8 kg/s mass flow. The study results show the possibility of using STHX instead of the current condensation unit in implementing a proposed system layout with the minimum effect of energy consumption

The role of textural properties and surface chemistry of activated carbon support in catalytic deoxygenation of triglycerides into renewable diesel

This research article was published in the Journals Catalysis Communications Volume 181,2023The textural properties and surface chemistry of activated carbon support are commonly known to have influ- ence on the catalytic performance of catalysts. Many authors have assessed the effect of textural properties and surface chemistry of activated carbon support in the deoxygenation of triglycerides. This review focuses on reconciling literature on the role/relevance of textural properties and surface chemistry of activated carbon support in deoxygenation of triglycerides into diesel-like hydrocarbons. It is revealed that different activated carbon (AC) exhibit distinct effects on the catalytic behaviors of the supported catalyst. The degree of influence of both textural properties and surface chemistry of AC support varies with the nature of the supported catalyst

Impacts of Wood Fuel Uses on Forest Cover: The Case of Semiarid Areas in Northern Tanzania

Satellite images for the years 1987, 1997, 2002 and 2017, and questionnaire surveys were used to assess energy sources and demands as well as the impacts of wood fuel use to forest cover changes in Meru and Mwanga Districts. The major energy sources identified include cow dung cake, firewood, charcoal, liquefied petroleum gas and biogas. The total energy demands from these sources were 1400 (in Meru), 6289, 724 and 21 kg per day, respectively. The amount of biogas was not quantified since the reactors were constructed locally with no reading meter. Analysis from Landsat images showed variations in forest cover. The areas covered with forests in Meru were found to be 1510, 1723, 1612 and 1327 ha for 1987, 1997, 2002 and 2017, respectively. The changes observed in Mwanga District were 31705, 31988, 17939 and 30960 ha for 1987, 1997, 2002 and 2017, respectively. From the findings it was observed that, the ongoing use of wood fuel in semi-arid areas of Meru and Mwanga could deplete forests completely. The study concludes that charcoal and firewood consumptions are real threats to the long-term persistence of forests in Tanzania and proposes the use of renewable energy such as biogas for alleviating forest losses. Keywords: Biogas, energy sources, Satellite image

Investigation of functional performance of treatment systems for textile wastewater in selected textile industries in Tanzania

This research article was published by IWA publishing, Volume 87, Issue 3Textile industrialization is an integral part of the economic growth in Tanzania. However, the corresponding wastewater from textile treat ment processes consists of dyes and auxiliaries associated with acute toxicological impacts. This necessitates an investigation of the functional performance of the industrial treatment systems used before effluent discharge. The study primarily accesses the catalog of indus trial dyes and the functionality of the treatment system at Arusha, Morogoro and Dar es Salaam vis-à-vis the effluent physicochemical properties. The analytical study reveals disperse (42%), vat (34%) and reactive (26%) as the most used industrial dyes. The physicochemical properties of the quantified wastewater reveal a significant amount of and phosphorus which was consequent to the high turbidity, bio chemical oxygen demand (BOD) and chemical oxygen demand (COD) apart from the color at the different sampling points. Although the treatability of the wastewater was 90% efficient using an activated carbon system (237.33 + 0.67 mg/L). Similarly, the use of aerated con structed wetlands shows efficiency in the remediation of the recalcitrant having a value of 12.13 + 0.89b mg/L (90%) and 13.22 + 0.15a mg/L (94%). Thereafter, needful recommendations were suggested based on the physicochemical properties of the textile wastewater and to improve the functionality of the treatment systems in the respective industries

Preparation and Characterization of Biogenic Chitosan-Hydroxyapatite Composite: Application in Defluoridation

This research article published by Cambridge University Press, Volume 3 Issue 36, 2018In Northern Tanzania, high levels of fluoride in community drinking water supply is recognized as one of the major public health concern, the problem is further ameliorated by presence Escherichia coli and fecal coliform bacteria in surface water and shallow wells. Efforts to decontaminate the water involve mostly the use of low efficient bone char for fluoride removal without disinfecting the pathogens. To address this problem, a robust adsorbent which is capable of removing fluoride and microbes simultaneously with minimal diverse impact on the treated water is necessary. Here we highlight development of composite material developed from recycling of crustacean biomass waste from sea food industry. Chitosan polymer, isolated from prawns shell was composited with crab shell derived brushite (CaHPO4.2H2O) to form chitosan-hydroxyapatite composite. XRD and FT-IR analysis confirmed transformation of brushite phases into hydroxyapatite and formation hybrid composite. Fluoride adsorption tests were performed in batch mode to evaluate effectiveness. Defluoridation capacity of up to 6.4 mg/g in field water containing fluoride concentration of 5-70 mg/L was achieved. The best performance was observed with fluoride concentration of 10 mg/L and below. Apart from fluoride removal, the composite also reduced color tint and microbes from surface water samples. The pH of the treated water in most samples remained around 6.5-8.5, which is acceptable for drinking water

Functional impacts of polyaniline in composite matrix of photocatalysts: an instrumental overview

This research article was published by Royal Society of Chemistry in 2023The challenges associated with photocatalysts including their agglomeration, electron–hole recombination and limited optoelectronic reactivity to visible light during the photocatalysis of dye-laden effluent make it necessary to fabricate versatile polymeric composite photocatalysts, and in this case the incredibly reactive conducting polyaniline can be employed. The selection of polyaniline among the conducting polymers is based on its proficient functional impacts in composite blends and proficient synergism with other nanomaterials, especially semiconductor catalysts, resulting in a high photocatalytic performance for the degradation of dyes. However, the impacts of PANI in the composite matrix, which result in the desired photocatalytic activities, can only be assessed using multiple characterization techniques, involving both microscopic and spectroscopic assessment. The characterization results play a significant role in the detection of possible points of agglomeration, surface tunability and improved reactivity during the fabrication of composites, which are necessary to improve their performance in the photocatalysis of dyes. Accordingly, studies revealed the functional impacts of polyaniline in composites including morphological transformation, improved surface functionality, reduction in agglomeration and lowered bandgap potential employing different characterization techniques. In this review, we present the most proficient fabrication techniques based on the in situ approach to achieve improved functional and reactive features and efficiencies of 93, 95, 96, 98.6 and 99% for composites in dye photocatalysis