A General Effective Theory for Dense Quark Matter

A general effective action for quark matter at nonzero temperature and/or nonzero density is derived. Irrelevant quark modes are distinguished from relevant quark modes, and hard from soft gluon modes, by introducing two separate cut-offs in momentum space, one for quarks, $\Lambda_q$, and one for gluons, $\Lambda_g$. Irrelevant quark modes and hard gluon modes are then exactly integrated out in the functional integral representation of the QCD partition function. Depending on the specific choice for $\Lambda_q$ and $\Lambda_g$, the resulting effective action contains well-known effective actions for hot and/or dense quark matter, for instance the ``Hard Thermal Loop'' (HTL) or the ``Hard Dense Loop'' (HDL) action, as well as the high-density effective theory proposed by Hong and others.Comment: 10 pages, 6 figures, contribution to proceedings of SEWM 200

Blue-fluorescence of NADPH as an indicator of marine primary production

Nicotinamide Adenine Dinucleotide Phosphate (NADPH) is the primary product of photosynthesisand can therefore serve as an indicator of biomass and photosynthetic activity. Pure NADPH whichis the reduced form of NADP shows an absorption maximum at 340 nm and a maximum of emissionat 460 nm. NADPH concentrations in terrestrial vegetation have already been studied since1957 in great detail with optical methods. However, its potential as a biomass parameter of oceanicphytoplankton which can be assessed in situ and remotely with fluorescence spectroscopy has notyet been investigated.In this paper, we report on laboratory investigations of the blue-fluorescence spectrum in algalsuspensions of Chlorella and Thalassiosira when excited with UV-A light. It is shown that cell densitiesof about 106 per litre as they are typically found under natural conditions are too low for precisedetection of NADPH fluorescence, while concentrated samples with 108-1010 cells per litre exhibitsignificant blue-fluorescence which can be related to NADPH. Inhibition of photosynthetic activityby addition of DCMU decreases the strength of blue-fluorescence remarkably. Since NADPHis an end product of photosynthesis, changes of PAR illumination levels should directly affect itsconcentration and hence the intensity of blue-fluorescence. However, no effect of illumination onblue-fluorescence could be observed in our study. Possible reasons of these observations are discussed,and perspectives for practical applications of the method used are proposed

The steady-state of heterogeneous catalysis, studied by first-principles statistical mechanics

The turn-over frequency of the catalytic oxidation of CO at RuO2(110) was calculated as function of temperature and partial pressures using ab initio statistical mechanics. The underlying energetics of the gas-phase molecules, dissociation, adsorption, surface diffusion, surface chemical reactions, and desorption were obtained by all-electron density-functional theory. The resulting CO2 formation rate [in the full (T, p_CO, p_O2)-space], the movies displaying the atomic motion and reactions over times scales from picoseconds to seconds, and the statistical analyses provide insights into the concerted actions ruling heterogeneous catalysis and open thermodynamic systems in general.Comment: 4 pages including 3 figures, Related publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm

The Location of the Core in M81

We report on VLBI observations of M81*, the northwest-southeast oriented nuclear core-jet source of the spiral galaxy M81, at five different frequencies between 1.7 and 14.8 GHz. By phase referencing to supernova 1993J we can accurately locate the emission region of M81* in the galaxy's reference frame. Although the emission region's size decreases with increasing frequency while the brightness peak moves to the southwest, the emission region seems sharply bounded to the southwest at all frequencies. We argue that the core must be located between the brightness peak at our highest frequency (14.8 GHz) and the sharp bound to the southwest. This narrowly constrains the location of the core, or the purported black hole in the center of the galaxy, to be within a region of +/-0.2 mas or +/-800 AU (at a distance of ~4 Mpc). This range includes the core position that we determined earlier by finding the most stationary point in the brightness distribution of M81* at only a single frequency. This independent constraint therefore strongly confirms our earlier core position. Our observations also confirm that M81* is a core-jet source, with a one-sided jet that extends to the northeast from the core, on average curved somewhat to the east, with a radio spectrum that is flat or inverted near the core and steep at the distant end. The brightness peak is unambiguously identified with the variable jet rather than the core, which indicates limitations in determining the proper motion of nearby galaxies and in refining the extragalactic reference frame.Comment: LaTeX, 10 pages with 3 figures. Typos fixed and slight rewording for clarity from previous version. Accepted for publication in the Astrophysical Journa

Plastic-crystalline solid-state electrolytes: Ionic conductivity and orientational dynamics in nitrile mixtures

Many plastic crystals, molecular solids with long-range, center-of-mass crystalline order but dynamic disorder of the molecular orientations, are known to exhibit exceptionally high ionic conductivity. This makes them promising candidates for applications as solid-state electrolytes, e.g., in batteries. Interestingly, it was found that the mixing of two different plastic-crystalline materials can considerably enhance the ionic dc conductivity, an important benchmark quantity for electrochemical applications. An example is the admixture of different nitriles to succinonitrile, the latter being one of the most prominent plastic-crystalline ionic conductors. However, until now only few such mixtures were studied. In the present work, we investigate succinonitrile mixed with malononitrile, adiponitrile, and pimelonitrile, to which 1 mol% of Li ions were added. Using differential scanning calorimetry and dielectric spectroscopy, we examine the phase behavior and the dipolar and ionic dynamics of these systems. We especially address the mixing-induced enhancement of the ionic conductivity and the coupling of the translational ionic mobility to the molecular reorientational dynamics, probably arising via a "revolving-door" mechanism.Comment: 9 pages, 7 figures; revised version as accepted for publication in J. Chem. Phy