306 research outputs found
Electronic and phonon excitations in {\alpha}-RuCl
We report on THz, infrared reflectivity and transmission experiments for wave
numbers from 10 to 8000 cm ( 1 meV - 1 eV) and for temperatures
from 5 to 295 K on the Kitaev candidate material {\alpha}-RuCl. As reported
earlier, the compound under investigation passes through a first-order
structural phase transition, from a monoclinic high-temperature to a
rhombohedral low-temperature phase. The phase transition shows an extreme and
unusual hysteretic behavior, which extends from 60 to 166 K. In passing this
phase transition, in the complete frequency range investigated we found a
significant reflectance change, which amounts almost a factor of two. We
provide a broadband spectrum of dielectric constant, dielectric loss and
optical conductivity from the THz to the mid infrared regime and study in
detail the phonon response and the low-lying electronic density of states. We
provide evidence for the onset of an optical energy gap, which is of order 200
meV, in good agreement with the gap derived from measurements of the DC
electrical resistivity. Remarkably, the onset of the gap exhibits a strong blue
shift on increasing temperatures.Comment: 18 pages, 7 figure
Grandmothers As Child Caregivers: A Unique Child Care Arrangement
This paper draws attention to grandmothers who provide child care and the parents and children they serve, by sharing the results of a study of a group of employed mothers from rural, low-income families who used grandmother care on a regular basis. Although their experiences cannot represent those of all mothers who use grandmother care, they are valuable in understanding the perspective of many women with few feasible options who depend on this type of care
個人面接を通して見た多読への動機付け
© 2016 American Pharmacists Association®.Benzoic acid is a model compound for drug substances in pharmaceutical research. Process design requires information about thermodynamic phase behavior of benzoic acid and its mixtures with water and organic solvents. This work addresses phase equilibria that determine stability and solubility. In this work, Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) was used to model the phase behavior of aqueous and organic solutions containing benzoic acid and chlorobenzoic acids. Absolute vapor pressures of benzoic acid and 2-, 3-, and 4-chlorobenzoic acid from literature and from our own measurements were used to determine pure-component PC-SAFT parameters. Two binary interaction parameters between water and/or benzoic acid were used to model vapor-liquid and liquid-liquid equilibria of water and/or benzoic acid between 280 and 413 K. The PC-SAFT parameters and 1 binary interaction parameter were used to model aqueous solubility of the chlorobenzoic acids. Additionally, solubility of benzoic acid in organic solvents was predicted without using binary parameters. All results showed that pure-component parameters for benzoic acid and for the chlorobenzoic acids allowed for satisfying modeling phase equilibria. The modeling approach established in this work is a further step to screen solubility and to predict the whole phase region of mixtures containing pharmaceuticals
Magnetic Excitations and Continuum of a Field-Induced Quantum Spin Liquid in -RuCl
We report on terahertz spectroscopy of quantum spin dynamics in
-RuCl, a system proximate to the Kitaev honeycomb model, as a
function of temperature and magnetic field. An extended magnetic continuum
develops below the structural phase transition at K. With the onset
of a long-range magnetic order at K, spectral weight is transferred to
a well-defined magnetic excitation at meV, which is
accompanied by a higher-energy band at meV. Both
excitations soften in magnetic field, signaling a quantum phase transition at
T where we find a broad continuum dominating the dynamical response.
Above , the long-range order is suppressed, and on top of the continuum,
various emergent magnetic excitations evolve. These excitations follow clear
selection rules and exhibit distinct field dependencies, characterizing the
dynamical properties of the field-induced quantum spin liquid
Psychological Issues in Education and Health. Proceedings of the 1st Scientific Meeting in Psychology 2016.
Proceedings of the 1st Scientific Meeting in Psychology 2016. University of Evora & University of Leipzig
Sub-gap optical response across the structural phase transition in van der Waals layered \alpha-RuCl
We report magnetic, thermodynamic, thermal expansion, and on detailed optical
experiments on the layered compound -RuCl focusing on the THz and
sub-gap optical response across the structural phase transition from the
monoclinic high-temperature to the rhombohedral low-temperature structure,
where the stacking sequence of the molecular layers is changed. This type of
phase transition is characteristic for a variety of tri-halides crystallizing
in a layered honeycomb-type structure and so far is unique, as the
low-temperature phase exhibits the higher symmetry. One motivation is to
unravel the microscopic nature of spin-orbital excitations via a study of
temperature and symmetry-induced changes. We document a number of highly
unusual findings: A characteristic two-step hysteresis of the structural phase
transition, accompanied by a dramatic change of the reflectivity. An electronic
excitation, which appears in a narrow temperature range just across the
structural phase transition, and a complex dielectric loss spectrum in the THz
regime, which could indicate remnants of Kitaev physics. Despite significant
symmetry changes across the monoclinic to rhombohedral phase transition, phonon
eigenfrequencies and the majority of spin-orbital excitations are not strongly
influenced. Obviously, the symmetry of the single molecular layers determine
the eigenfrequencies of most of these excitations. Finally, from this combined
terahertz, far- and mid-infrared study we try to shed some light on the so far
unsolved low energy (< 1eV) electronic structure of the ruthenium
electrons in -RuCl.Comment: 22 pages, 9 figure
Evolution of coordinated mutagenesis and somatic hypermutation in VH5
The VH5 human antibody gene was analyzed using a computer program (mfg) which simulates transcription, to better understand transcription-driven mutagenesis events that occur during phase 1 of somatic hypermutation. Results show that the great majority of mutations in the non-transcribed strand occur within loops of two predicted high-stability stem-loop structures, termed SLSs 14.9 and 13.9. In fact, 89% of the 2505 mutations reported are within the encoded complementarity-determining region (CDR) and occur in loops of these high-stability structures. In vitro studies were also done and verified the existence of SLS 14.9. Following the formation of SLSs 14.9 and 13.9, a sustained period of transcriptional activity occurs within a window size of 60-70 nucleotides. During this period, the stability of these two SLSs does not change, and may provide the substrate for base exchanges and mutagenesis. The data suggest that many mutable bases are exposed simultaneously at pause sites, allowing for coordinated mutagenesis
Psychology in Education and Health. Proceedings of the III Leipzig-Evora Scientific Meeting in Psychology
The phenomena of achievement motivation is one of the most important among studied
by psychology as far as its study approaches of scientists to the answer to the question
about motivation forces of human behavior and activity. Motivation for achievement
consists of two main components - adaptive and transcendent vectors. Based on the
empirical studies carried out, the authors obtained results that became the basis for the
assumption that the motivation of achievement among people who are conditionally
called healthy is fundamentally different from the motivation of achievement among
people with mental pathology.
There is a non-linear link between mental health, mental disorders and adaptation,
transcendence. Mental health requires a balance of these two components of the
motivational sphere
Dynamics of the G-excess illusion
The G-excess illusion is increasingly recognized as a cause of aviation mishaps especially when pilots perform high-speed, steeply banked turns at low altitudes. Centrifuge studies of this illusion have examined the perception of subject orientation and/or target displacement during maintained hypergravity with the subject's head held stationary. The transient illusory perceptions produced by moving the head in hypergravity are difficult to study onboard centrifuges because the high angular velocity ensures the presence of strong Coriolis cross-coupled semicircular canal effects that mask immediate transient otolith-organ effects. The present study reports perceptions following head movements in hypergravity produced by high-speed aircraft maintaining a banked attitude with low angular velocity to minimize cross-coupled effects. Methods: Fourteen subjects flew on the NASA KC-135 and were exposed to resultant gravity forces of 1.3, 1.5, and 1.8 G for 3 minute periods. On command, seated subjects made controlled head movements in roll, pitch, and yaw at 30 second intervals both in the dark and with faint targets at a distance of 5 feet. Results: head movement produced transient perception of target displacement and velocity at levels as low as 1.3 G. Reports of target velocity without appropriate corresponding displacement were common. At 1.8 G when yaw head movements were made from a face down position, 4 subjects reported oscillatory rotational target displacement with fast and slow alternating components suggestive of torsional nystagmus. Head movements evoked symptoms of nausea in most subjects, with 2 subjects and 1 observer vomiting. Conclusions: The transient percepts present conflicting signals, which introduced confusion in target and subject orientation. Repeated head movements in hypergravity generate nausea by mechanisms distinct from cross-coupled Coriolis effects
Benzoic Acid and Chlorobenzoic Acids: Thermodynamic Study of the Pure Compounds and Binary Mixtures with Water
© 2016 American Pharmacists Association®.Benzoic acid is a model compound for drug substances in pharmaceutical research. Process design requires information about thermodynamic phase behavior of benzoic acid and its mixtures with water and organic solvents. This work addresses phase equilibria that determine stability and solubility. In this work, Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) was used to model the phase behavior of aqueous and organic solutions containing benzoic acid and chlorobenzoic acids. Absolute vapor pressures of benzoic acid and 2-, 3-, and 4-chlorobenzoic acid from literature and from our own measurements were used to determine pure-component PC-SAFT parameters. Two binary interaction parameters between water and/or benzoic acid were used to model vapor-liquid and liquid-liquid equilibria of water and/or benzoic acid between 280 and 413 K. The PC-SAFT parameters and 1 binary interaction parameter were used to model aqueous solubility of the chlorobenzoic acids. Additionally, solubility of benzoic acid in organic solvents was predicted without using binary parameters. All results showed that pure-component parameters for benzoic acid and for the chlorobenzoic acids allowed for satisfying modeling phase equilibria. The modeling approach established in this work is a further step to screen solubility and to predict the whole phase region of mixtures containing pharmaceuticals
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