A Lean Methane Prelixed Laminar Flame Doped witg Components of Diesel Fuel. Part I: n)Butylbenzene

To better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar) of methane, 36.8% of oxygen and 0.96% of n-butylbenzene corresponding to an equivalence ratio of 0.74 and a ratio C10H14 / CH4 of 13.5%. The flame has been stabilized on a burner at a pressure of 6.7 kPa using argon as diluent, with a gas velocity at the burner of 49.2 cm/s at 333 K. Quantified species included the usual methane C0-C2 combustion products, but also 16 C3-C5 hydrocarbons, 7 C1-C3 oxygenated compounds, as well as 20 aromatic products, namely benzene, toluene, phenylacetylene, styrene, ethylbenzene, xylenes, allylbenzene, propylbenzene, cumene, methylstyrenes, butenylbenzenes, indene, indane, naphthalene, phenol, benzaldehyde, anisole, benzylalcohol, benzofuran, and isomers of C10H10 (1-methylindene, dihydronaphtalene, butadienylbenzene). A new mechanism for the oxidation of n-butylbenzene is proposed whose predictions are in satisfactory agreement with measured species profiles in flames and flow reactor experiments. The main reaction pathways of consumption of n butylbenzene have been derived from flow rate analyses

WEIRD: Wide-orbit Exoplanet search with InfraRed Direct imaging

We report results from the Wide-orbit Exoplanet search with InfraRed Direct imaging (WEIRD), a survey designed to search for Jupiter-like companions on very wide orbits (1000 to 5000 AU) around young stars ($<$120 Myr) that are known members of moving groups in the solar neighborhood ($<$70 pc). Sharing the same age, distance, and metallicity as their host while being on large enough orbits to be studied as "isolated" objects make such companions prime targets for spectroscopic observations and valuable benchmark objects for exoplanet atmosphere models. The search strategy is based on deep imaging in multiple bands across the near-infrared domain. For all 177 objects of our sample, $z_{ab}^\prime$, $J$, [3.6] and [4.5] images were obtained with CFHT/MegaCam, GEMINI/GMOS, CFHT/WIRCam, GEMINI/Flamingos-2, and $Spitzer$/IRAC. Using this set of 4 images per target, we searched for sources with red $z_{ab}^\prime$ and $[3.6]-[4.5]$ colors, typically reaching good completeness down to 2Mjup companions, while going down to 1Mjup for some targets, at separations of $1000-5000$ AU. The search yielded 4 candidate companions with the expected colors, but they were all rejected through follow-up proper motion observations. Our results constrain the occurrence of 1-13 Mjup planetary-mass companions on orbits with a semi-major axis between 1000 and 5000 AU at less than 0.03, with a 95\% confidence level.Comment: 55 pages, 16 figures, accepted to A