Discovery of the Interstellar Chiral Molecule Propylene Oxide (CH3_3CHCH2_2O)

Life on Earth relies on chiral molecules, that is, species not superimposable on their mirror images. This manifests itself in the selection of a single molecular handedness, or homochirality, across the biosphere. We present the astronomical detection of a chiral molecule, propylene oxide (CH$_3$CHCH$_2$O), in absorption toward the Galactic Center. Propylene oxide is detected in the gas phase in a cold, extended molecular shell around the embedded, massive protostellar clusters in the Sagittarius B2 star-forming region. This material is representative of the earliest stage of solar system evolution in which a chiral molecule has been found

A Bima Array Survey of Molecules in Comets Linear (C/2002 T7) and Neat (C/2001 Q4)

We present an interferometric search for large molecules, including methanol, methyl cyanide, ethyl cyanide, ethanol, and methyl formate in comets LINEAR (C/2002 T7) and NEAT (C/2001 Q4) with the Berkeley-Illinois-Maryland Association (BIMA) array. In addition, we also searched for transitions of the simpler molecules CS, SiO, HNC, HN13C and 13CO . We detected transitions of methanol and CS around Comet LINEAR and one transition of methanol around Comet NEAT within a synthesized beam of ~20''. We calculated the total column density and production rate of each molecular species using the variable temperature and outflow velocity (VTOV) model described by Friedel et al.(2005).Considering the molecular production rate ratios with respect to water, Comet T7 LINEAR is more similar to Comet Hale-Bopp while Comet Q4 NEAT is more similar to Comet Hyakutake. It is unclear, however, due to such a small sample size, whether there is a clear distinction between a Hale-Bopp and Hyakutake class of comet or whether comets have a continuous range of molecular production rate ratios.Comment: Accepted for Publication in the Astrophysical Journa

Science with an ngVLA: Observing the Effects of Chemistry on Exoplanets and Planet Formation

One of the primary mechanisms for inferring the dynamical history of planets in our Solar System and in exoplanetary systems is through observation of elemental ratios (i.e. C/O). The ability to effectively use these observations relies critically on a robust understanding of the chemistry and evolutionary history of the observed abundances. Significant efforts have been devoted to this area from within astrochemistry circles, and these efforts should be supported going forward by the larger exoplanetary science community. In addition, the construction of a next-generation radio interferometer will be required to test many of these predictive models in situ, while simultaneously providing the resolution necessary to pinpoint the location of planets in formation.Comment: To be published in the ASP Monograph Series, "Science with a Next-Generation VLA", ed. E. J. Murphy (ASP, San Francisco, CA

Interstellar Carbodiimide (HNCNH) - A New Astronomical Detection from the GBT PRIMOS Survey via Maser Emission Features

In this work, we identify carbodiimide (HNCNH), which is an isomer of the well-known interstellar species cyanamide (NH2CN), in weak maser emission, using data from the GBT PRIMOS survey toward Sgr B2(N). All spectral lines observed are in emission and have energy levels in excess of 170 K, indicating that the molecule likely resides in relatively hot gas that characterizes the denser regions of this star forming region. The anticipated abundance of this molecule from ice mantle experiments is ~10% of the abundance of NH2CN, which in Sgr B2(N) corresponds to ~2 x 10^13 cm-2. Such an abundance results in transition intensities well below the detection limit of any current astronomical facility and, as such, HNCNH could only be detected by those transitions which are amplified by masing.Comment: Accepted in The Astrophysical Journal Letters, 13 pages, 2 figures, generated using AAS LaTeX Macros v 5.

CSO and CARMA Observations of L1157. I. A Deep Search for Hydroxylamine (NH2_2OH)

A deep search for the potential glycine precursor hydroxylamine (NH$_2$OH) using the Caltech Submillimeter Observatory (CSO) at $\lambda = 1.3$ mm and the Combined Array for Research in Millimeter-wave Astronomy (CARMA) at $\lambda = 3$ mm is presented toward the molecular outflow L1157, targeting the B1 and B2 shocked regions. We report non-detections of NH$_2$OH in both sources. We a perform non-LTE analysis of CH$_3$OH observed in our CSO spectra to derive kinetic temperatures and densities in the shocked regions. Using these parameters, we derive upper limit column densities of NH$_2$OH of $\leq1.4 \times 10^{13}$~cm$^{-2}$ and $\leq1.5 \times 10^{13}$~cm$^{-2}$ toward the B1 and B2 shocks, respectively, and upper limit relative abundances of $N_{NH_2OH}/N_{H_2} \leq1.4 \times 10^{-8}$ and $\leq1.5 \times 10^{-8}$, respectively.Comment: Accepted in the Astrophysical Journa

Numerical Simulation of the Flow Inside a Scroll Compressor Equipped with Intermediate Discharge Valves

This paper presents the results of CFD simulations of the compression process of a scroll compressor. The compressor geometry accounts for the final scroll gas pockets, two Intermediate Discharge Valves (IDVs), the central discharge zone and the upper shell. The numerical model uses a real gas equation of state to determine gas properties during the compression process and accounts for the motion of the orbiting scroll and IDVs using a mesh smoothing and remeshing algorithm. The IDVs are represented as a spring mass system with their movement controlled via the pressure difference around the valve. Appropriate pressure based boundary conditions are used at entry to the third gas pocket and at the exit of the upper shell. An initial analysis of the results has shown that it is possible to achieve time accurate results of the pressure field throughout the flow domain and also determine the impact of the IDVs on scroll performance. The results will also enable a more thorough analysis of the fluid flow and compression process inside the scroll in order to improve its performance

Simultaneous Observations of Comet C/2002 T7 (LINEAR) with the Berkeley-Illinois-Maryland Association and Owens Valley Radio Observatory Interferometers: HCN and CH_3OH

We present observations of HCN J = 1-0 and CH_3OH J(K_a, K_c) = 3(1, 3)-4(0, 4) A+ emission from comet C/2002 T7 (LINEAR) obtained simultaneously with the Owens Valley Radio Observatory (OVRO) and Berkeley-Illinois-Maryland Association (BIMA) millimeter interferometers. We combined the data from both arrays to increase the (u, v) sampling and signal to noise of the detected line emission. We also report the detection of CH_3OH J(K_a, K_c) = 8(0, 8)-7(1, 7) A^+ with OVRO data alone. Using a molecular excitation code that includes the effects of collisions with water and electrons, as well as pumping by the Solar infrared photons (for HCN alone), we find a production rate of HCN of 2.9 × 10^(26) s^(–1) and for CH_3OH of 2.2 × 10^(27) s^(–1). Compared to the adopted water production rate of 3 × 10^(29) s^(–1), this corresponds to an HCN/H_2O ratio of 0.1% and a CH_3OH/H_2O ratio of 0.7%. We critically assess the uncertainty of these values due to the noise (~10%), the uncertainties in the adopted comet model (~50%), and the uncertainties in the adopted collisional excitation rates (up to a factor of 2). Pumping by Solar infrared photons is found to be a minor effect for HCN, because our 15" synthesized beam is dominated by the region in the coma where collisions dominate. Since the uncertainties in the derived production rates are at least as large as one-third of the differences found between comets, we conclude that reliable collision rates and an accurate comet model are essential. Because the collisionally dominated region critically depends on the water production rate, using the same approximate method for different comets may introduce biases in the derived production rates. Multiline observations that directly constrain the molecular excitation provide much more reliable production rates

The Distribution, Excitation and Formation of Cometary Molecules: Methanol, Methyl Cyanide and Ethylene Glycol

We present an interferometric and single dish study of small organic species toward Comets C/1995 O1 (Hale-Bopp) and C/2002 T7 (LINEAR) using the BIMA interferometer at 3 mm and the ARO 12m telescope at 2 mm. For Comet Hale-Bopp, both the single-dish and interferometer observations of CH3OH indicate an excitation temperature of 105+/-5 K and an average production rate ratio Q(CH3OH)/Q(H2O)~1.3% at ~1 AU. Additionally, the aperture synthesis observations of CH3OH suggest a distribution well described by a spherical outflow and no evidence of significant extended emission. Single-dish observations of CH3CN in Comet Hale-Bopp indicate an excitation temperature of 200+/-10 K and a production rate ratio of Q(CH3CN)/Q(H2O)~0.017% at ~1 AU. The non-detection of a previously claimed transition of cometary (CH2OH)2 toward Comet Hale-Bopp with the 12m telescope indicates a compact distribution of emission, D<9'' (<8500 km). For the single-dish observations of Comet T7 LINEAR, we find an excitation temperature of CH3OH of 35+/-5 K and a CH3OH production rate ratio of Q(CH3OH)/Q(H2O)~1.5% at ~0.3 AU. Our data support current chemical models that CH3OH, CH3CN and (CH2OH)2 are parent nuclear species distributed into the coma via direct sublimation off cometary ices from the nucleus with no evidence of significant production in the outer coma.Comment: accepted for publication in Ap

Detection of Voigt Spectral Line Profiles of Hydrogen Radio Recombination Lines toward Sagittarius B2(N)

We report the detection of Voigt spectral line profiles of radio recombination lines (RRLs) toward Sagittarius B2(N) with the 100-m Green Bank Telescope (GBT). At radio wavelengths, astronomical spectra are highly populated with RRLs, which serve as ideal probes of the physical conditions in molecular cloud complexes. An analysis of the Hn(alpha) lines presented herein shows that RRLs of higher principal quantum number (n>90) are generally divergent from their expected Gaussian profiles and, moreover, are well described by their respective Voigt profiles. This is in agreement with the theory that spectral lines experience pressure broadening as a result of electron collisions at lower radio frequencies. Given the inherent technical difficulties regarding the detection and profiling of true RRL wing spans and shapes, it is crucial that the observing instrumentation produce flat baselines as well as high sensitivity, high resolution data. The GBT has demonstrated its capabilities regarding all of these aspects, and we believe that future observations of RRL emission via the GBT will be crucial towards advancing our knowledge of the larger-scale extended structures of ionized gas in the interstellar medium (ISM)