Role of Li_2B_(12)H_(12) for the Formation and Decomposition of LiBH_4

By in situ X-ray diffraction (XRD) and nuclear magnetic resonance (NMR) spectroscopy, the role of Li_2B_(12)H_(12) for the sorption of LiBH_4 is analyzed. We demonstrate that Li_2B_(12)H_(12) and an amorphous Li_2B_(10)H_(10) phase are formed by the reaction of LiBH_4 with diborane (B_2H_6) at 200 °C. Based on our present results, we propose that the Li -2B - (12)H_(12) formation in the desorption of LiBH_4 can be explained as a result of reaction of diborane and LiBH_4. This reaction of the borohydride with diborane may also be observed for other borohydrides, where B_(12)H_(12) phases are found during decomposition

Proximity effect of vanadium on spin-density-wave magnetism in Cr films

The spin-density wave (SDW) state in thin chromium films is well known to be strongly affected by proximity effects from neighboring layers. To date the main attention has been given to effects arising from exchange interactions at interfaces. In the present work we report on combined neutron and synchrotron scattering studies of proximity effects in Cr/V films where the boundary condition is due to the hybridization of Cr with paramagnetic V at the interface. We find that the V/Cr interface has a strong and long-range effect on the polarization, period, and the N\'{e}el temperature of the SDW in rather thick Cr films. This unusually strong effect is unexpected and not predicted by theory.Comment: 7 figure

Сіверські князі Наримунтовичі

У статті досліджується генеалогія та діяльність сіверських Наримунтовичів – однієї з гілок литовсько-руської династії Гедиміновичів, представники якої наприкінці XIV – початку XV ст. володіли кількома удільними князівствами у Сіверській землі.В статье исследуется генеалогия и деятельность северских Наримунтовичей – одной из ветвей литовско-русской династии Гедиминовичей, представители которой в конце XIV – начале XV вв. владели несколькими удельными княжествами в Северской земле.The article deals with genealogy and activity of the seversky Narimuntoviches as one of branches of the Lithuanian-Russian dynasty of the Gediminoviches, representatives of which at the end XIV – beginning of XV centuries owned some specific principalities in the Seversky land

Hydrogen Dynamics in Lightweight Tetrahydroborates

The high hydrogen content in complex hydrides such as M[AlH4]x and M[BH4]x (M = Li, Na,K, Mg, Ca) stimulated many research activities to utilize them as hydrogen storage materials. An understanding of the dynamical properties on themolecular level is important to understand and to improve the sorption kinetics. Hydrogen dynamics in complex hydrides comprise long range translational diffusion as well as localized motions like vibrations, librations or rotations. All the different motions are characterized by their specific length- and timescales. Within this review we give an introduction to the physical properties of lightweight complex hydrides and illustrate the huge variety of dynamical phenomena on selected example

АСУ ТП горения жидкого и газообразного топлива на основе бесконтактных оптических техник

В результате выполнения магистерской диссертации разработана автоматизированная система управления горением жидкого и газообразного топлива на основе бесконтактных оптических техник. В процессе выполнения работы был произведен анализ существующих бесконтактных оптических методов. Также были проведены экспериментальные исследования, и произведен выбор схемы регулирования. Разработаны схема структурная, схема функциональная, схема принципиальная электрическая, схема монтажная внешних проводок и сборочный чертеж щита управления со спецификацией на него. Осуществлен выбор технических средств автоматизации и составлена заказная спецификация. Система разработана с учетом технических требований, нормативных документов и исходя из результатов научно-исследовательской работы.As a result of the master's thesis, an automated control system for the combustion of liquid and gaseous fuels based on contactless optical techniques was developed. In the course of the work, the analysis of the existing non-contact optical methods was carried out. Experimental studies were also carried out, and the choice of the control scheme was made. A structural diagram, a functional diagram, an electrical circuit diagram, a wiring diagram of external wiring and an assembly drawing of the control panel with a specification for it are developed. The choice of technical means of automation is carried out and the custom specification is made. The system is developed taking into account technical requirements and research results

The hyperfine properties of a hydrogenated Fe/V superlattice

: We study the effect of hydrogen on the electronic, magnetic and hyperfine structures of an iron-vanadium superlattice consisting of three Fe monolayers and nine V monolayers. The contact charge density ({\rho}), the contact hyperfine field (Bhf) and the electronic field gradient (EFG) at the Fe sites for different H locations and H fillings are calculated using the first principle full-potential linear-augmented-plane-wave (FP-LAPW) method . It is found that sizeable changes in the hyperfine properties are obtained only when H is in the interface region.Comment: 6 pages, 2 figures, 3 tables, ICAME 2011 conference (Kobe, Japan

Isotope effects in switchable metal-hydride mirrors

Measurements of optical reflectance, transmittance, and electrical resistivity on the switchable mirror systems YHx and YDx show that the absorption of hydrogen induces the same variations as that of deuterium. In both cases there is a weak transparency window for the metallic dihydride (dideuteride) phase and a yellowish transparency in the insulating trihydride (trideuteride) phase. The slightly higher electrical resistivity of the deuterides is related to the lower energy of their optical phonons. The absence of significant isotope effects in the optical properties of YHx(YDx) is at variance with Peierls-like theoretical models. It is, however, compatible with strong electron correlation model