Logarithmic coarsening and glassy behavior in a polymer model with mass-dependent diffusion

We present a model of polymer growth and diffusion with frustration mechanisms for density increase and with diffusion rates of Arrhenius form with mass-dependent energy barriers Gamma(m) ~ (m-1)^gamma. It shows non-universal logarithmic coarsening involving the exponent gamma. Strong-glass behavior is found in the typical times for disappearance of all polymers up to a given length, without reference to the equilibrium states of the macroscopic system. These features are predicted by numerical simulations, scaling theories and an analytic solution of the master equation within an independent interval approximation, which also provides the cluster size distribution.Comment: 16 pages, including 7 figures. To be published in Phys. Rev.

Non-universal coarsening and universal distributions in far-from equilibrium systems

Anomalous coarsening in far-from equilibrium one-dimensional systems is investigated by simulation and analytic techniques. The minimal hard core particle (exclusion) models contain mechanisms of aggregated particle diffusion, with rates epsilon<<1, particle deposition into cluster gaps, but suppressed for the smallest gaps, and breakup of clusters which are adjacent to large gaps. Cluster breakup rates vary with the cluster length x as kx^alpha. The domain growth law x ~ (epsilon t)^z, with z=1/(2+alpha) for alpha>0, is explained by a scaling picture, as well as the scaling of the density of double vacancies (at which deposition and cluster breakup are allowed) as 1/[t(epsilon t)^z]. Numerical simulations for several values of alpha and epsilon confirm these results. An approximate factorization of the cluster configuration probability is performed within the master equation resulting from the mapping to a column picture. The equation for a one-variable scaling function explains the above results. The probability distributions of cluster lengths scale as P(x)= 1/(epsilon t)^z g(y), with y=x/(epsilon t)^z. However, those distributions show a universal tail with the form g(y) ~ exp(-y^{3/2}), which disagrees with the prediction of the independent cluster approximation. This result is explained by the connection of the vacancy dynamics with the problem of particle trapping in an infinite sea of traps and is confirmed by simulation.Comment: 30 pages (10 figures included), to appear in Phys. Rev.

Modeling one-dimensional island growth with mass-dependent detachment rates

We study one-dimensional models of particle diffusion and attachment/detachment from islands where the detachment rates gamma(m) of particles at the cluster edges increase with cluster mass m. They are expected to mimic the effects of lattice mismatch with the substrate and/or long-range repulsive interactions that work against the formation of long islands. Short-range attraction is represented by an overall factor epsilon<<1 in the detachment rates relatively to isolated particle hopping rates [epsilon ~ exp(-E/T), with binding energy E and temperature T]. We consider various gamma(m), from rapidly increasing forms such as gamma(m) ~ m to slowly increasing ones, such as gamma(m) ~ [m/(m+1)]^b. A mapping onto a column problem shows that these systems are zero-range processes, whose steady states properties are exactly calculated under the assumption of independent column heights in the Master equation. Simulation provides island size distributions which confirm analytic reductions and are useful whenever the analytical tools cannot provide results in closed form. The shape of island size distributions can be changed from monomodal to monotonically decreasing by tuning the temperature or changing the particle density rho. Small values of the scaling variable X=epsilon^{-1}rho/(1-rho) favour the monotonically decreasing ones. However, for large X, rapidly increasing gamma(m) lead to distributions with peaks very close to and rapidly decreasing tails, while slowly increasing gamma(m) provide peaks close to /2$ and fat right tails.Comment: 16 pages, 6 figure

Decentering the cold war in Southern Africa: the portuguese policy of decolonization and détente in Angola and Mozambique (1974–1984)

Contrary to the expectations of many, the break between Portugal and its former colonies in southern Africa was far from complete after decolonization. This article points to three major reasons. First, the impact on relations with Angola and Mozambique of the fragmentation of Portuguese state power and tense polarization in the Portuguese polity after the military coup of 24 April 1974 has been overstated and was far from entirely negative. Second, diplomatic relations were normalized between Portugal, Angola, and Mozambique during the Cold War in a way that has significant parallels with West Germany's Ostpolitik. Portugal's Südpolitik saw a cultural identity worth preserving despite geopolitical divisions and pushed for better relations and deepened ties with these states to help move them away from strict alignment with the Soviet bloc. Third, officers of the Armed Forces Movement that carried out the April 1974 coup exercised a fundamental, positive influence in Portuguese policies toward Angola and Mozambique during decolonization and for years afterward.info:eu-repo/semantics/publishedVersio

High harmonic generation from Bloch electrons in solids

We study the generation of high harmonic radiation by Bloch electrons in a model transparent solid driven by a strong mid-infrared laser field. We solve the single-electron time-dependent Schr\"odinger equation (TDSE) using a velocity-gauge method [New J. Phys. 15, 013006 (2013)] that is numerically stable as the laser intensity and number of energy bands are increased. The resulting harmonic spectrum exhibits a primary plateau due to the coupling of the valence band to the first conduction band, with a cutoff energy that scales linearly with field strength and laser wavelength. We also find a weaker second plateau due to coupling to higher-lying conduction bands, with a cutoff that is also approximately linear in the field strength. To facilitate the analysis of the time-frequency characteristics of the emitted harmonics, we also solve the TDSE in a time-dependent basis set, the Houston states [Phys. Rev. B 33, 5494 (1986)], which allows us to separate inter-band and intra-band contributions to the time-dependent current. We find that the inter-band and intra-band contributions display very different time-frequency characteristics. We show that solutions in these two bases are equivalent under an unitary transformation but that, unlike the velocity gauge method, the Houston state treatment is numerically unstable when more than a few low lying energy bands are used

Cluster growth in far-from-equilibrium particle models with diffusion, detachment, reattachment and deposition

Monolayer cluster growth in far-from-equilibrium systems is investigated by applying simulation and analytic techniques to minimal hard core particle (exclusion) models. The first model (I), for post-deposition coarsening dynamics, contains mechanisms of diffusion, attachment, and slow activated detachment (at rate epsilon<<1) of particles on a line. Simulation shows three successive regimes of cluster growth: fast attachment of isolated particles; detachment allowing further (epsilon t)^(1/3) coarsening of average cluster size; and t^(-1/2) approach to a saturation size going like epsilon^(-1/2). Model II generalizes the first one in having an additional mechanism of particle deposition into cluster gaps, suppressed for the smallest gaps. This model exhibits early rapid filling, leading to slowing deposition due to the increasing scarcity of deposition sites, and then continued power law (epsilon t)^(1/2) cluster size coarsening through the redistribution allowed by slow detachment. The basic (epsilon t)^(1/3) domain growth laws and epsilon^(-1/2) saturation in model I are explained by a simple scaling picture. A second, fuller approach is presented which employs a mapping of cluster configurations to a column picture and an approximate factorization of the cluster configuration probability within the resulting master equation. This allows quantitative results for the saturation of model I in excellent agreement with the simulation results. For model II, it provides a one-variable scaling function solution for the coarsening probability distribution, and in particular quantitative agreement with the cluster length scaling and its amplitude.Comment: Accepted in Phys. Rev. E; 9 pages with figure