Low-Energy Scale Excitations in the Spectral Function of Organic Monolayer Systems

Using high-resolution photoemission spectroscopy we demonstrate that the electronic structure of several organic monolayer systems, in particular 1,4,5,8-naphthalene tetracarboxylic dianhydride and Copper-phtalocyanine on Ag(111), is characterized by a peculiar excitation feature right at the Fermi level. This feature displays a strong temperature dependence and is immediatly connected to the binding energy of the molecular states, determined by the coupling between the molecule and the substrate. At low temperatures, the line-width of this feature, appearing on top of the partly occupied lowest unoccupied molecular orbital of the free molecule, amounts to only $\approx 25$ meV, representing an unusually small energy scale for electronic excitations in these systems. We discuss possible origins, related e.g. to many-body excitations in the organic-metal adsorbate system, in particular a generalized Kondo scenario based on the single impurity Anderson model.Comment: 6 pages, 3 figures, accepted as PRB Rapid Communication

Core hole-electron correlation in coherently coupled molecules

We study the core hole-electron correlation in coherently coupled molecules by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In a transient phase, which exists during the transition between two bulk arrangements, 1,4,5,8-naphthalene-tetracarboxylicacid-dianhydride multilayer films exhibit peculiar changes of the line shape and energy position of the X-ray absorption signal at the C K-edge with respect to the bulk and gas phase spectra. By a comparison to a theoretical model based on a coupling of transition dipoles, which is established for optical absorption, we demonstrate that the observed spectroscopic differences can be explained by an intermolecular delocalized core hole-electron pair. By applying this model we can furthermore quantify the coherence length of the delocalized core-exciton.Comment: 5 pages, 3 figures, Accepted Version, PRL, minor wording change

Forecasting Wheat and Grass Yields from Climatic Factors

A study of the factors of climate and their relation to wheat and short grass yields was conducted at Hays, Kansas. Statistical correlations were made between the elements of the climate and wheat and short grass yields, also correlations between elements of the climate. A 22-year period was used for forecasting short grass yields and a 30-year period for wheat. In the study, September temperature, spring temperature and spring precipitation, all showed a significant correlation when compared statistically to short grass yields. September temperature was the only element of fall climate that showed a significant amount of correlation when compared to the following year’s grass yields. September temperatures can accurately be used to forecast average short grass production nearly a year prior to harvesting. Spring temperature and spring precipitation accounted for 75 percent of the variability in short grass yields. When comparing September and May soil moisture data to short grass yields, no correlation existed in the study at Hays, Kansas. A highly significant negative correlation existed between temperature and precipitation at Hays, Kansas. Spring temperature, fall precipitation and September precipitation, all showed a significant correlation when compared statistically with wheat production. Fall precipitation, approximately at the time of planting, can accurately be used to forecast average wheat production

Echo of the Quantum Phase Transition of CeCu6−x_{6-x}Aux_x in XPS: Breakdown of Kondo Screening

We present an X-ray photoemission study of the heavy-fermion system CeCu$_{6-x}$Au$_x$ across the magnetic quantum phase transition of this compound at temperatures above the single-ion Kondo temperature $T_K$. In dependence of the Au concentration $x$ we observe a sudden change of the $f$-occupation number $n_f$ and the core-hole potential $U_{df}$ at the critical concentration $x_c=0.1$. We interpret these findings in the framework of the single-impurity Anderson model. Our results are in excellent agreement with findings from earlier UPS measurements %\cite{klein08qpt} and provide further information about the precursors of quantum criticality at elevated temperatures.Comment: 5 pages, 3 figures; published version, references updated, minor changes in wordin

High-temperature signatures of quantum criticality in heavy fermion systems

We propose a new criterion for distinguishing the Hertz-Millis (HM) and the local quantum critical (LQC) mechanism in heavy fermion systems with a magnetic quantum phase transition (QPT). The criterion is based on our finding that the spin screening of Kondo ions can be completely suppressed by the RKKY coupling to the surrounding magnetic ions even without magnetic ordering and that, consequently, the signature of this suppression can be observed in spectroscopic measurements above the magnetic ordering temperature. We apply the criterion to high-resolution photoemission (UPS) measurements on CeCu$_{6-x}$Au$_{x}$ and conclude that the QPT in this system is dominated by the LQC scenario.Comment: Inveted paper, International Conference on Magnetism, ICM 2009, Karlsruhe. Published version, added discussions of the relevance of Fermi-surface fluctuations and of a structural transition near the QC

Momentum-resolved evolution of the Kondo lattice into 'hidden-order' in URu2Si2

We study, using high-resolution angle-resolved photoemission spectroscopy, the evolution of the electronic structure in URu2Si2 at the Gamma, Z and X high-symmetry points from the high-temperature Kondo-screened regime to the low-temperature `hidden-order' (HO) state. At all temperatures and symmetry points, we find structures resulting from the interaction between heavy and light bands, related to the Kondo lattice formation. At the X point, we directly measure a hybridization gap of 11 meV already open at temperatures above the ordered phase. Strikingly, we find that while the HO induces pronounced changes at Gamma and Z, the hybridization gap at X does not change, indicating that the hidden-order parameter is anisotropic. Furthermore, at the Gamma and Z points, we observe the opening of a gap in momentum in the HO state, and show that the associated electronic structure results from the hybridization of a light electron band with the Kondo-lattice bands characterizing the paramagnetic state.Comment: Updated published version. Mansucript + Supplemental Material (8 pages, 9 figures). Submitted 16 September 201

Structure and transport in multi-orbital Kondo systems

We consider Kondo impurity systems with multiple local orbitals, such as rare earth ions in a metallic host or multi--level quantum dots coupled to metallic leads. It is shown that the multiplet structure of the local orbitals leads to multiple Kondo peaks above the Fermi energy $E_F$, and to ``shadow'' peaks below $E_F$. We use a slave boson mean field theory, which recovers the strong coupling Fermi liquid fixed point, to calculate the Kondo peak positions, widths, and heights analytically at T=0, and NCA calculations to fit the temperature dependence of high--resolution photoemission spectra of Ce compounds. In addition, an approximate conductance quantization for transport through multi--level quantum dots or single--atom transistors in the Kondo regime due to a generalized Friedel sum rule is demonstrated.Comment: 4 pages, 3 figures. Invited article, 23rd International Conference on Low Temperature Physics LT23, Hiroshima, Japan 200