20 research outputs found

    Nonmonotonic Rayleigh-Taylor Instabilities Driven by Gas–Liquid CO<sub>2</sub> Chemisorption

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    Density variations induced by gas absorption in reactive aqueous solutions often trigger buoyancy-induced motions, generally in the form of plumes monotonically sinking into the bulk liquid and enhancing the absorption rate. Here, we contrast two types of CO<sub>2</sub>-absorbing alkaline solutions, studying their dynamics inside a vertical Hele-Shaw cell by interferometry. While the first one indeed behaves as expected, the second one leads to a quite unusual oscillatory (phase-slipping) dynamics of convective plumes, which moreover does not lead to a significant transfer enhancement. Thanks to a simplified model of momentum and species transport, we show that this particular dynamics is related to a nonmonotonic density stratification, resulting in a stagnant layer close to the interface. Conditions for this to occur are highlighted in terms of the ratios of species’ diffusivities and their contribution to density, a classification deemed to be useful for optimizing chemisorption (e.g., for CO<sub>2</sub> capture or sequestration) processes

    Influence of a nonlinear reference temperature profile on oscillatory Benard-Marangoni convection.

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    We analyze oscillatory instabilities in a fluid layer of infinite horizontal extent, heated from above or cooled from below, taking into account the nonlinearity of the reference temperature profile during the transient state of heat conduction. The linear stability analysis shows that a nonlinear reference temperature profile can have a strong effect on the system, either stabilizing or destabilizing, depending on the relative importance of buoyancy and surface tension forces. For the nonlinear analysis we use a Galerkin-Eckhaus method leading to a finite set of amplitude equations. In the two-dimensional (2D) case, we show the solution of these amplitude equations are standing waves
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