Synthesis, Crystal Structure and Photophysical Properties of Lanthanide Coordination Polymers of 4- 4-(9H-Carbazol-9-Yl)Butoxy Benzoate: The Effect of Bidentate Nitrogen Donors on Luminescence

A new aromatic carboxylate ligand, 4-[4-(9H-carbazol-9-yl)butoxy]benzoic acid (HL), has been synthesized by the replacement of the hydroxyl hydrogen of 4-hydroxy benzoic acid with a 9-butyl-9H-carbazole moiety. The anion derived from HL has been used for the support of a series of lanthanide coordination compounds [Ln = Eu (1), Gd (2) and Tb (3)]. The new lanthanide complexes have been characterized by a variety of spectroscopic techniques. Complex 3 was structurally authenticated by single-crystal X-ray diffraction and found to exist as a solvent-free 1D coordination polymer with the formula [Tb(L)(3)](n). The structural data reveal that the terbium atoms in compound 3 reside in an octahedral ligand environment that is somewhat unusual for a lanthanide. It is interesting to note that each carboxylate group exhibits only a bridging-bidentate mode, with a complete lack of more complex connectivities that are commonly observed for extended lanthanide-containing solid-state structures. Examination of the packing diagram for 3 revealed the existence of two-dimensional molecular arrays held together by means of CH-pi interactions. Aromatic carboxylates of the lanthanides are known to exhibit highly efficient luminescence, thus offering the promise of applicability as optical devices. However, due to difficulties that arise on account of their polymeric nature, their practical application is somewhat limited. Accordingly, synthetic routes to discrete molecular species are highly desirable. For this purpose, a series of ternary lanthanide complexes was designed, synthesized and characterized, namely [Eu(L)(3)(phen)] (4), [Eu(L)(3)(tmphen)] (5), [Tb(L)(3)(phen)] (6) and [Tb(L)(3)(tmphen)] (7) (phen = 1,10-phenanthroline and tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline). The photophysical properties of the foregoing complexes in the solid state at room temperature have been investigated. The quantum yields of the ternary complexes 4 (9.65%), 5 (21.00%), 6 (14.07%) and 7 (32.42%), were found to be significantly enhanced in the presence of bidentate nitrogen donors when compared with those of the corresponding binary compounds 1 (0.11%) and 3 (1.45%). Presumably this is due to effective energy transfer from the ancillary ligands.Council of Scientific and Industrial Research (CSIR-TAPSUN Project) SSL, NWP-55CSIR, New DelhiRobert A. Welch Foundation F-0003Chemistr

Electronic screening and damping in magnetars

We calculate the screening of the ion-ion potential due to electrons in the presence of a large background magnetic field, at densities of relevance to neutron star crusts. Using the standard approach to incorporate electron screening through the one-loop polarization function, we show that the magnetic field produces important corrections both at short and long distances. In extreme fields, realized in highly magnetized neutron stars called magnetars, electrons occupy only the lowest Landau levels in the relatively low density region of the crust. Here our results show that the screening length for Coulomb interactions between ions can be smaller than the inter-ion spacing. More interestingly, we find that the screening is anisotropic and the screened potential between two static charges exhibits long range Friedel oscillations parallel to the magnetic field. This long-range oscillatory behavior is likely to affect the lattice structure of ions, and can possibly create rod-like structures in the magnetar crusts. We also calculate the imaginary part of the electron polarization function which determines the spectrum of electron-hole excitations and plays a role in damping lattice phonon excitations. We demonstrate that even for modest magnetic fields this damping is highly anisotropic and will likely lead to anisotropic phonon heat transport in the outer neutron star crust.Comment: 14 pages, 5 Figure

Reinterpreting Shock Wave Structure Predictions using the Navier-Stokes Equations

Classical Navier-Stokes equations fail to predict shock wave profiles accurately. In this paper, the Navier-Stokes system is fully transformed using a velocity variable transformation. The transformed equations termed the re-casted Navier-Stokes equations display physics not initially included. We then analyse the stationary shock structure problem in a monatomic gas by solving both the classical and the re-casted Navier-Stokes equations numerically using a finite difference global solution (FDGS) scheme. The numerical results are presented for different upstream Mach numbers ranging from supersonic to hypersonic flows. We found that the re-casted Navier-Stokes equations show better agreements with the experimentally measured density and reciprocal shock thickness profiles

Experimental Evidence of Time Delay Induced Death in Coupled Limit Cycle Oscillators

Experimental observations of time delay induced amplitude death in a pair of coupled nonlinear electronic circuits that are individually capable of exhibiting limit cycle oscillations are described. In particular, the existence of multiply connected death islands in the parameter space of the coupling strength and the time delay parameter for coupled identical oscillators is established. The existence of such regions was predicted earlier on theoretical grounds in [Phys. Rev. Lett. 80, 5109 (1998); Physica 129D, 15 (1999)]. The experiments also reveal the occurrence of multiple frequency states, frequency suppression of oscillations with increased time delay and the onset of both in-phase and anti-phase collective oscillations.Comment: 4 aps formatted RevTeX pages; 6 figures; to appear in Phys. Rev. Let

Dust extinction from Balmer decrements of star-forming galaxies at 0.75<z<1.5 with HST/WFC3 spectroscopy from the WISP survey

Spectroscopic observations of Halpha and Hbeta emission lines of 128 star-forming galaxies in the redshift range 0.75<z<1.5 are presented. These data were taken with slitless spectroscopy using the G102 and G141 grisms of the Wide-Field-Camera 3 (WFC3) on board the Hubble Space Telescope as part of the WFC3 Infrared Spectroscopic Parallel (WISP) survey. Interstellar dust extinction is measured from stacked spectra that cover the Balmer decrement (Halpha/Hbeta). We present dust extinction as a function of Halpha luminosity (down to 3 x 10^{41} erg/s), galaxy stellar mass (reaching 4 x 10^{8} Msun), and rest-frame Halpha equivalent width. The faintest galaxies are two times fainter in Halpha luminosity than galaxies previously studied at z~1.5. An evolution is observed where galaxies of the same Halpha luminosity have lower extinction at higher redshifts, whereas no evolution is found within our error bars with stellar mass. The lower Halpha luminosity galaxies in our sample are found to be consistent with no dust extinction. We find an anti-correlation of the [OIII]5007/Halpha flux ratio as a function of luminosity where galaxies with L_{Halpha}<5 x 10^{41} erg/s are brighter in [OIII]5007 than Halpha. This trend is evident even after extinction correction, suggesting that the increased [OIII]5007/Halpha ratio in low luminosity galaxies is likely due to lower metallicity and/or higher ionization parameters.Comment: 11 pages, 9 figures, 2 tables; version addressing the referee comment

Effect of Level Statistics on Local Magnetism in Nanoscale Metallic Grains

Effect of level statistics on local electronic states and local magnetism in nanoscale metallic grains with transition-metal impurity in the ballistic regime is studied. It is shown that the mean occupation of local electron and the local magnetic moment in nanoscale metallic grains with odd conduction electrons are larger than those with even conduction electrons. The effect of even-odd parity on the condition for the occurrence of local magnetic moment is also discussed, it is found that the critical value $\rho_{d}(0)U_{c}$ for the formation of local moment in nanoscale metallic grains is much smaller than that in bulks. The dependences of the local spin susceptibility on size and the Coulomb interaction are obtained. These results show that the level statistics plays an important role for the local magnetism, it distinguishes the properties of nanoscale metallic grains from those of small clusters and bulks.Comment: Latex, 6 figures in Postscrip

The Classification of Obsessive–Compulsive and Related Disorders in the ICD-11

Background To present the rationale for the new Obsessive–Compulsive and Related Disorders (OCRD) grouping in the Mental and Behavioural Disorders chapter of the Eleventh Revision of the World Health Organization’s International Classification of Diseases and Related Health Problems (ICD-11), including the conceptualization and essential features of disorders in this grouping. Methods Review of the recommendations of the ICD-11 Working Group on the Classification for OCRD. These sought to maximize clinical utility, global applicability, and scientific validity. Results The rationale for the grouping is based on common clinical features of included disorders including repetitive unwanted thoughts and associated behaviours, and is supported by emerging evidence from imaging, neurochemical, and genetic studies. The proposed grouping includes obsessive–compulsive disorder, body dysmorphic disorder, hypochondriasis, olfactory reference disorder, and hoarding disorder. Body-focused repetitive behaviour disorders, including trichotillomania and excoriation disorder are also included. Tourette disorder, a neurological disorder in ICD-11, and personality disorder with anankastic features, a personality disorder in ICD-11, are recommended for cross-referencing. Limitations Alternative nosological conceptualizations have been described in the literature and have some merit and empirical basis. Further work is needed to determine whether the proposed ICD-11 OCRD grouping and diagnostic guidelines are mostly likely to achieve the goals of maximizing clinical utility and global applicability. Conclusion It is anticipated that creation of an OCRD grouping will contribute to accurate identification and appropriate treatment of affected patients as well as research efforts aimed at improving our understanding of the prevalence, assessment, and management of its constituent disorders

Neutrino Propagation In Color Superconducting Quark Matter

We calculate the neutrino mean free path in color superconducting quark matter, and employ it to study the cooling of matter via neutrino diffusion in the superconducting phase as compared to a free quark phase. The cooling process slows when quark matter undergoes a second order phase transition to a superconducting phase at the critical temperature $T_c$. Cooling subsequently accelerates as the temperature decreases below $T_c$. This will directly impact the early evolution of a newly born neutron star should its core contain quark matter. Consequently, there may be observable changes in the early neutrino emission which would provide evidence for superconductivity in hot and dense matter.Comment: 12 pages, 5 figure

Is deep venous thrombosis a common complication in patients treated with Ilizarov external fixator?

Background: Determining the incidence of deep venous thrombosis (DVT), a prospective study, in patients treated with Ilizarov external fixators for lower extremity fractures, fracture non unions or deformity correction.Methods: A Prospective, observational and cross sectional study. 49 Patients with complex lower extremity injuries, deformities and non-union of fractures were treated with Ilizarov external fixator application, were assessed clinically and radiological (Venous Doppler) at regular intervals- 6 days post-surgery then at 6 weeks, 12 weeks and between 4 to 6 months post-operative. None were given chemoprophylaxis for the prevention of DVT and everyone were assessed pre operatively with a questionnaire and wells criteria was taken for assessment of high risk for developing venous thrombosis. There were 41 men and 8 women, 85.75% of the study group is of age 30 to 60 years.Results: Only 1 of 49 patients developed radiological evident DVT within 6 days of surgery. Patients who underwent application of Ilizarov external fixator electively for deformity correction, osteomyelitis and non-union showed no clinical or radiological evident signs of DVT.Conclusions: The incidence of DVT and PTE is minimal when patients without chemoprophylaxis underwent lower limb Ilizarov external fixator application for acute trauma and electively for deformity correction, treatment of non-union and osteomyelitis. However further comparative and randomized studies need to be done to confirm our results

Realistic Neutrino Opacities for Supernova Simulations With Correlations and Weak Magnetism

Advances in neutrino transport allow realistic neutrino interactions to be incorporated into supernova simulations. We add tensor couplings to relativistic RPA calculations of neutrino opacities. Our results reproduce free-space neutrino-nucleon cross sections at low density, including weak magnetism and recoil corrections. In addition, our opacities are thermodynamically consistent with relativistic mean field equations of state. We find antineutrino mean free paths that are considerably larger then those for neutrinos. This difference depends little on density. In a supernova, this difference could lead to an average energy of $\bar\nu_\mu$ that is larger than that for $\nu_\mu$ by an amount that is comparable to the energy difference between $\nu_\mu$ and $\bar\nu_e$Comment: 15 pages, 10 figures, submitted to PRC, minor changes to figs. (9,10