Depletion interaction between spheres of unequal size and demixing in binary mixtures of colloids

The possibility to induce demixing in a colloidal mixture by adding small polymers, or other equivalent depletant agents, is theoretically investigated. By use of Mean Field Theory, suitably generalized to deal with short range effective interactions, the phase diagram of a binary mixture ofcolloidal particles (modelled as hard spheres) in a solvent is determined as a function of the polymer concentration on the basis of the Asakura-Oosawa model.The topology of the phase diagram changes when the relative size of the colloidal particles is reduced: the critical line connecting the liquid-vapour critical points of the two pure fluids breaks and the branch starting from the critical point of the bigger particles bends to higher volume fractions, where concentration fluctuations drive the transition. The effects of a softer colloid-polymer interaction is also investigated: Even the presence of a small repulsive tail in the potential gives rise to a significant lowering of the stability threshold. In this case, phase transitions may take place by adding just a few percent of depletant in volume fraction. These results may be relevant for the interpretation of recent experiments of solidification kinetics in colloidal mixtures.Comment: To be published in Molecular Physic

Shell Effects and Phase Separation in a Trapped Multi-Component Fermi System

Shell effects in the coordinate space can be seen with degenerate Fermi vapors in non-uniform trapping potentials. In particular, below the Fermi temperature, the density profile of a Fermi gas in a confining harmonic potential is characterized by several local maxima. This effect is enhanced for "magic numbers" of particles and in quasi-1D (cigar-shaped) configurations. In the case of a multi-component Fermi vapor, the separation of Fermi components in different spatial shells (phase-separation) depends on temperature, number of particles and scattering length. We derive analytical formulas, based on bifurcation theory, for the critical density of Fermions and the critical chemical potential, which give rise to the phase-separation.Comment: to be published in the Proceedings of the VIII Meeting on Problems in Theoretical Nuclear Physics, Cortona, October 18-20, 2000, Ed. G. Pisent, A. Fabrocini and L. Canton (World Scientific

Effective wave-equations for the dynamics of cigar-shaped and disc-shaped Bose condensates

Starting from the 3D Gross-Pitaevskii equation and using a variational approach, we derive an effective 1D wave-equation that describes the axial dynamics of a Bose condensate confined in an external potential with cylindrical symmetry. The trapping potential is harmonic in the transverse direction and generic in the axial one. Our equation, that is a time-dependent non-polynomial nonlinear Schr\"odinger equation (1D NPSE), can be used to model cigar-shaped condensates, whose dynamics is essentially 1D. We show that 1D NPSE gives much more accurate results than all other effective equations recently proposed. By using 1D NPSE we find analytical solutions for bright and dark solitons, which generalize the ones known in the literature. We deduce also an effective 2D non-polynomial Schr\"odinger equation (2D NPSE) that models disc-shaped Bose condensates confined in an external trap that is harmonic along the axial direction and generic in the transverse direction. In the limiting cases of weak and strong interaction, our approach gives rise to Schr\"odinger-like equations with different polynomial nonlinearities.Comment: 7 pages, 5 figures, to be published in Phys. Rev.

Bosonic clouds with attractive interaction beyond the local interaction approximation

We study the properties of a Bose-Einstein condensed cloud of atoms with negative scattering length confined in a harmonic trap. When a realistic non local (finite range) effective interaction is taken into account, we find that, besides the known low density metastable solution, a new branch of Bose condensate appears at higher density. This state is self-bound but its density can be quite low if the number $N$ of atoms is not too big. The transition between the two classes of solutions as a function of $N$ can be either sharp or smooth according to the ratio between the range of the attractive interaction and the length of the trap. A tight trap leads to a smooth transition. In addition to the energy and the shape of the cloud we study also the dynamics of the system. In particular, we study the frequencies of collective oscillation of the Bose condensate as a function of the number of atoms both in the local and in the non local case. Moreover, we consider the dynamics of the cloud when the external trap is switched off.Comment: Latex, 6 pages, 2 figure, 1 table, presented to the International Symposium of Quantum Fluids and Solids 98, Amherst (USA), 9-14 June 199

Fluctuations and Pattern Formation in Fluids with Competing Interactions

One of the most interesting phenomena in the soft-matter realm consists in the spontaneous formation of super-molecular structures (microphases) in condition of thermodynamic equilibrium. A simple mechanism responsible for this self-organization or pattern formation is based on the competition between attractive and repulsive forces with different length scales in the microscopic potential, typically, a short-range attraction against a longer-range repulsion. We analyse this problem by simulations in 2D fluids. We find that, as the temperature is lowered, liquid-vapor phase separation is inhibited by the competition between attraction and repulsion, and replaced by a transition to non-homogeneous phases. The structure of the fluid shows well defined signatures of the presence of both intra- and inter-cluster correlations. Even when the competition between attraction and repulsion is not so strong as to cause microphase formation, it still induces large density fluctuations in a wide region of the temperature-density plane. In this large-fluctuation regime, pattern formation can be triggered by a weak external modulating field.Comment: To appear in the proceedings of the "International workshop on collective phenomena in macroscopic systems", 2006 Villa Olmo (Como), Ital

Quantum Monte Carlo study of a vortex in superfluid 4^4He and search for a vortex state in the solid

We have performed a microscopic study of a straight quantized vortex line in three dimensions in condensed $^4$He at zero temperature using the Shadow Path Integral Ground State method and the fixed-phase approximation. We have characterized the energy and the local density profile around the vortex axis in superfluid $^4$He at several densities, ranging from below the equilibrium density up to the overpressurized regime. For the Onsager-Feynman (OF) phase our results are exact and represent a benchmark for other theories. The inclusion of backflow correlations in the phase improves the description of the vortex with respect to the OF phase by a large reduction of the core energy of the topological excitation. At all densities the phase with backflow induces a partial filling of the vortex core and this filling slightly increases with density. The core size slightly decreases for increasing density and the density profile has well defined density dependent oscillations whose wave vector is closer to the wave vector of the main peak in the static density response function rather than to the roton wave vector. Our results can be applied to vortex rings of large radius $R$ and we find good agreement with the experimental value of the energy as function of $R$ without any free parameter. We have studied also $^4$He above the melting density in the solid phase using the same functional form for the phase as in the liquid. We found that off-diagonal properties of the solid are not qualitatively affected by the velocity field induced by the vortex phase, both with and without backflow correlations. Therefore we find evidence that a perfect $^4$He crystal is not a marginally stable quantum solid in which rotation would be able to induce off-diagonal long-range coherence.Comment: 15 pages, 8 figure

Thermodynamics of Bose-Condensed Atomic Hydrogen

We study the thermodynamics of the Bose-condensed atomic hydrogen confined in the Ioffe-Pritchard potential. Such a trapping potential, that models the magnetic trap used in recent experiments with hydrogen, is anharmonic and strongly anisotropic. We calculate the ground-state properties, the condensed and non-condensed fraction and the Bose-Einstein transition temperature. The thermodynamics of the system is strongly affected by the anharmonicity of this external trap. Finally, we consider the possibility to detect Josephson-like currents by creating a double-well barrier with a laser beam.Comment: 11 pages, 4 figures, to be published in European Physical Journal

Bounds for the Superfluid Fraction from Exact Quantum Monte Carlo Local Densities

For solid 4He and solid p-H2, using the flow-energy-minimizing one-body phase function and exact T=0 K Monte Carlo calculations of the local density, we have calculated the phase function, the velocity profile and upper bounds for the superfluid fraction f_s. At the melting pressure for solid 4He we find that f_s < 0.20-0.21, about ten times what is observed. This strongly indicates that the theory for the calculation of these upper bounds needs substantial improvements.Comment: to be published in Phys. Rev. B (Brief Reports