An Endohedral Single-Molecule Magnet with Long Relaxation Times: DySc₂N@C₈₀

The magnetism of DySc₂N@C₈₀ endofullerene was studied with X-ray magnetic circular dichroism (XMCD) and a magnetometer with a superconducting quantum interference device (SQUID) down to temperatures of 2 K and in fields up to 7 T. XMCD shows hysteresis of the 4f spin and orbital moment in Dy^III ions. SQUID magnetometry indicates hysteresis below 6 K, while thermal and nonthermal relaxation is observed. Dilution of DySc₂N@C₈₀ samples with C₆₀ increases the zero-field 4f electron relaxation time at 2 K to several hours

Oxygen-Stabilized Rh Adatoms: 0D Oxides on a Vicinal Surface

We have investigated the initial oxidation of the Rh(113) and Rh(223) vicinal surfaces by STM and ab initio simulations. Upon adsorption of small amounts of oxygen, the surface morphology is completely altered. Surprisingly, oxygen-stabilized Rh adatoms can be observed on the (113) facets, with oxide-like electronic properties. We present models of these “0D oxide” phases and discuss reasons for their stability

Triangular Monometallic Cyanide Cluster Entrapped in Carbon Cage with Geometry-Dependent Molecular Magnetism

Clusterfullerenes are capable of entrapping a variety of metal clusters within carbon cage, for which the entrapped metal cluster generally keeps its geometric structure (e.g., bond distance and angle) upon changing the isomeric structure of fullerene cage, and whether the properties of the entrapped metal cluster is geometry-dependent remains unclear. Herein we report an unusual triangular monometallic cluster entrapped in fullerene cage by isolating several novel terbium cyanide clusterfullerenes (TbNC@C₈₂) with different cage isomeric structures. Upon varying the isomeric structure of C₈₂ cage from C₂(5) to C_s(6) and to C_2v(9), the entrapped triangular TbNC cluster exhibits significant distortions as evidenced by the changes of Tb–C­(N) and C–N bond distances and variation of the Tb–C­(N)–N­(C) angle by up to 20°, revealing that the geometric structure of the entrapped triangular TbNC cluster is variable. All three TbNC@C₈₂ molecules are found to be single-ion magnets, and the change of the geometric structure of TbNC cluster directly leads to the alternation of the magnetic relaxation time of the corresponding TbNC@C₈₂ clusterfullerene