Modeling the morphology and mechanical behavior of shape memory polyurethanes based on solid-state NMR and synchrotron SAXS/WAXD

A combination of solid-state proton Wide-line Nuclear Magnetic Resonance (NMR) relaxometry and synchrotron Small-angle (SAXS) and Wide-angle (WAXD) X-ray scattering was used to elucidate the microphase morphology of shape memory thermoplastic multi-block polyurethanes based on poly(3-caprolactone), as switching segment and polyurethane based permanent or hard segments (HS). The polyurethanes are produced from the condensation of 1,4-butanediol (BDO) with hexamethylenediisocyanate (HDI). The morphology – induced by the hard-segment crystallization – converts from dispersed randomly placed hard-segment domains into progressively more periodic, but interconnected HS nanophases with increasing HS content. Irrespective of the actual morphology, the SAXS data could be described satisfactorily by using a clipped Gaussian random field (GRF) model. The NMR data demonstrate that the HS domain fraction corresponds to the chemical feed, pointing at a complete phase separation. The material mechanical behavior during repeated deformation cycles can be explained on morphological grounds and involves a spatially heterogeneous plastic deformation of the hard domains

Modeling the Morphology and Mechanical Behavior of Shape memory Polyurethanes based on Solid State NMR and Synchrotron SAXS/WAXD

status: publishe