An evaluation of trace metal distribution, enrichment factors and risk in sediments of a coastal lagoon (Ria de Aveiro, Portugal)

This paper describes a sediment survey undertaken to unravel patterns of distribution and dispersion of trace metals in an Iberian Peninsula northwestern coastal lagoon (Ria de Aveiro). Cadmium, lead, chromium, copper and zinc were analyzed in bottom sediments. Geochemical normalization is performed and two different regression models for each metal versus aluminum are tested and compared using the respective enrichment factors (EF), an estimation of the relative importance of anthropogenic contributions to the studied sediments. Mean sediment quality guideline quotients (mSQGQ) are used to evaluate sediment quality and associated potential risk to biota with effects range low as empirical sediment quality guideline (SQG) in the basis for mSQGQ calculation. Additionally, the geoaccumulation index is calculated to compare studied sediment levels to global baseline levels. The application of SQGs revealed insufficient characterization capability, especially when contrasted to EF calculated from the regression methods. These pointed a mildly enriched system with localized "hot spot" areas. Therefore, it can be considered that bottom sediments in the Ria de Aveiro system are in their majority unpolluted, zinc being the only metal of concern, presenting enrichment in all four main channels. The major rivers outlets (Caster, Antuã, and Vouga) constitute point sources, thus presenting potential risk for biota. Yet, the strong tidal influence creates a damping effect by efficiently redistributing sediment bound metals

Dissolved Organic Carbon in Multilayered Aquifers of Pondicherry Region (India): Spatial and Temporal Variability and Relationships to Major Ion Chemistry

Carbon, which is an essential element found in rocks and minerals, is used by biologically diverse life forms as a source of energy. Natural organic carbon is mainly derived from decomposing vegetation and other organic matter in the soil zone. Dissolved organic carbon (DOC) is an important component in biogeochemical cycling of elements characterized by high susceptibility to leaching. The significance of DOC was studied in layered coastal aquifers of the Pondicherry region during four different seasons. Pondicherry region has varied geological setup ranging from Cretaceous to Recent formations. A total of 324 groundwater samples were collected from various aquifers, namely Alluvium, Tertiary, Cretaceous, and Mixed formations, during different seasons of pre-monsoon, southwest monsoon, northeast monsoon, and post-monsoon. The samples were analyzed for major ions and DOC. The range of DOC in the study area is 0–10 mg/l. Very high DOC concentrations were measured in most of the samples from Alluvium and Upper Cuddalore Formation and in few samples from the Lower Cuddalore Formation. The relationships of DOC with other ions in this study indicate that the hydrochemistry of groundwater was controlled by both aerobic and anaerobic environments in the different formations of the study area