72 research outputs found
Seat shock test stand development
The UNLV CMEST (The Center for Mechanical & Environment Systems Technology) lab and Army Research Labs have undertaken a research project to develop a seat system that will reduce the level of shock introduced into the bottom of a seat when a vehicle trips a land mine. In order to develop the seat system, a test stand was designed using an air cannon to fire a 5 pound steel slug at an impact plate, creating a high acceleration impulse or shock. The shock from the slug impact is redirected from the horizontal plane to the vertical plane through a pinned rocker assembly designed to strike the bottom of the seat; The test stand was designed with the aid of LS-DYNA, a finite element code capable of modeling the deformations and stresses in dynamic systems. Materials used to construct the test stand were simulated in the model to determine if they are able to withstand the impact from the slug. The LS-DYNA model was used to determine possible acceleration levels output by the test stand in different testing configurations. After completing the construction of the stand, the computer models were verified by comparing the simulated results to experimental testing data. Testing was completed in the CMEST lab using a data collection system and high G accelerometers. (Abstract shortened by UMI.)
Membership Drive Success: ALA/Alabama\u27s Support Staff Pilot Initiative
Many professional associations are grappling with membership challenges. Recently, the American Medical Association (AMA) adopted a strategy they termed the âmember-centeredâ approach (Romano, 2004). One feature of this approach designed to boost membership is teaming with state and specialty societies. The American Medical Association believes that âfuture cooperation and collaboration with state associations is vital to any membership turnaroundâ (Romano, 2004, p. 11). This partnership makes good business sense.
The American Library Association considers a cooperative venture with state associations as an important avenue to increase membership as well. Taking to heart the COPE recommendations and incorporating the idea of partnerships with state associations, ALA created a new membership option targeting library support staff at the state level. Alabama is the first state in which ALA will launch this cooperative endeavor. This article describes the joint staff membership initiative between a state association, the Alabama Library Association (ALLA), and the American Library Association â a unique pilot program already beginning to spread nationwide
Evgenij AkelÂŽev, Povsednevnaja ĆŸiznÂŽ vorovskogo mira Moskvy vo vremena VanÂŽki Kaina
The popular Molodaia Gvardia âLiving Historyâ book series on everyday life, now approaching 100Â titles, is a baggy collection of histories and current events. Some of its history books are not the new social or cultural studies suggested by the series title but merely standard accounts with the fashionable label âeveryday lifeâ tacked on. Others are rehashes of gossipy court or high society studies. But a few are genuinely original, powerful works of historical excavation. A recent addition t..
Implicit Questions in Michael Confinoâs Essay
AbstractThe essay commends Michael Confinoâs challenging criticisms over many years of the conceptualizations commonly used by historians of Russia. David L. Ransel agrees with the criticisms of the soslovie paradigm advanced by Confino in his recent essay. Ransel suggests that by adapting the soslovie to class conceptualization of Russiaâs modernization, historians may have missed seeing a more fruitful and instructive conceptualization, one usually associated with Ibero-Latin regimes rather than Russia, namely, the development of Russia from a patrimonial state to a corporate state and society. Ransel also points out the obstacles presented by the soslovie paradigm for understanding of the micro-dynamics of Russian history. The soslovie paradigm tends to blind scholars to a feature of Russian life that Confino himself had commented on many years ago: Russians of all social statuses lived in close proximity and interacted daily. Ransel gives examples from his own work and the work of others and calls for more study of the micro-dynamics of Russian history.RĂ©sumĂ©Le prĂ©sent essai appuie les critiques stimulantes formulĂ©es par Michael Confino pendant de nombreuses annĂ©es sur les conceptualisations communĂ©ment utilisĂ©es par les historiens de la Russie. Lâauteur admet les critiques de la notion de soslovie avancĂ©es par Confino dans son dernier article (CMR, 49 (4), 2008). Il laisse entendre quâen adoptant le modĂšle selon lequel la modernisation de la Russie se serait opĂ©rĂ©e par le passage dâune sociĂ©tĂ© de soslovija Ă une sociĂ©tĂ© de classes, les historiens ont pu passer Ă cĂŽtĂ© dâune autre conceptualisation plus fructueuse et Ă©difiante, associĂ©e dâordinaire aux rĂ©gimes latino-amĂ©ricains et ibĂ©riens plutĂŽt quâĂ la Russie, Ă savoir, le dĂ©veloppement de la Russie par le passage dâun Ătat patrimonial Ă un Ătat et une sociĂ©tĂ© corporatistes. Lâauteur pointe Ă©galement les obstacles que soulĂšve la notion de soslovie dans la comprĂ©hension de la microdynamique de lâhistoire russe. La notion de soslovie tend Ă masquer un aspect de la vie russe que Confino lui-mĂȘme avait commentĂ© il y a longtemps dĂ©jĂ Â : les Russes de tous statuts sociaux vivaient en proximitĂ© Ă©troite et Ă©taient en contact quotidiennement. Lâauteur propose des exemples extraits de diffĂ©rents travaux, dont les siens, et invite Ă utiliser davantage lâapproche microdynamique de lâhistoire russe
Revealing the Interplay Between Covalent and Non-Covalent Interactions Driving the Adsorption of Monosubstituted Thiourea Derivatives on the Au(111) Surface
âThis document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry C, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:
https://pubs.acs.org/doi/10.1021/acs.jpcc.0c00729This work reports a detailed study of the adsorption of thiourea and seven monosubstituted thiourea derivatives on the Au(111) surface based on self-consistent periodic density functional theory (DFT) calculations. We included in our analysis the most stable cis and trans configurations for each considered monosubstituted derivative. Different functional groups have been selected for the derivatives in order to address the electron-donating/withdrawing effect on the strength of the moleculeâmetal interaction. The comparison of the cis- and trans-derivatives revealed interactions of different nature between the molecules and the Au(111) surface. We have been able to disentangle these interactions analyzing the charge density difference plots, the projected density of states (pDOS) and the Non-Covalent Interactions (NCI). For the non-substituted thiourea and all the studied derivatives, besides the strong SâAu bond, it has been observed an Au···HâN interaction similar to a hydrogen bonding, which is caused by the charge transfer from the molecules to the Au(111) surface inducing a charge counterbalancing: AuÎŽâHÎŽ+NÎŽâ. Furthermore, ÏâAu interactions between the functional group of the derivatives and the Au(111) surface, mainly observed for the cis-derivatives, were highlighted by the NCI plots. In some particular cases it was also possible to distinguish long-range interactions of the type lone pairâAu. The present results provide insight into a new kind of organic moleculeâmetal surface interaction, opening the way for the synthesis of potential nanodevices with diverse applications such as sensing (biosensors or atmospheric sensors), optoelectronics, pollution control, or energy conversionThis work was partially supported by the âProyecto Nacional de Ciencias BĂĄsicasâ, Cuba Code P223LH001-079 âAbsorciĂłn de molĂ©culas organosulfuradas en superficies mĂ©talicasâ and by Project CTQ2016-76061-P of the Spanish Ministry of Science and Innovation. S.D.-T. acknowledges financial support from the Spanish Ministry of Science and Innovation, through the âMarĂa de Maeztuâ Programme for Units of Excellence in R&D (CEX2018-000805-M). M.P.H. would like to thank DGAPAUNAM for a 4-month fellowship through Programa de
Estancias de InvestigaciĂłn en la UNAM (PREI
Synergy effects in heavy metal Ion chelation with aryl- and aroyl-substituted thiourea derivatives
Detection and removal of metal ion contaminants have attracted great interest due to the health risks that they represent for humans and wildlife. Among the proposed compounds developed for these purposes, thiourea derivatives have been shown as quite efficient chelating agents of metal cations and have been proposed for heavy metal ion removal and for components of high-selectivity sensors. Understanding the nature of metal-ionophore activity for these compounds is thus of high relevance. We present a theoretical study on the interaction between substituted thioureas and metal cations, namely, Cd2+, Hg2+, and Pb2+. Two substituent groups have been chosen: 2-furoyl and m-trifluoromethylphenyl. Combining density functional theory simulations with wave function analysis techniques, we study the nature of the metal-thiourea interaction and characterize the bonding properties. Here, it is shown how the N,NâČ-disubstituted derivative has a strong affinity for Hg2+, through cation-hydrogen interactions, due to its greater oxidizing capacityR.B. acknowledges FundaciĂłn Carolina, Spain, for a Ph.D. fellowship. This work was partially supported by the MICINN, Spanish Ministry of Science and Innovation, project PID2019-110091GB-I00 and the âMarĂa de Maeztuâ Program for Centers of Excellence in R&D (CEX2018-000805-M
Breaking the Ties That Bound: The Politics of Marital Strife in Late Imperial Russia. By Barbara Alpern Engel. Ithaca: Cornell University Press, 2011. xi, 282 pp. Appendixes. Notes. Index. Illustrations. Photographs. Tables. $39.95, hard bound.
Nests of the Gentry: Family, Estate, and Local Loyalties in Provincial Russia. By Mary W. Cavender. Newark: University of Delaware Press/Associated University Presses, 2007. 251 pp. Notes. Bibliography. Index. Map. $55.00, hard bound.
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