Shear-melting of a hexagonal columnar crystal by proliferation of dislocations

A hexagonal columnar crystal undergoes a shear-melting transition above a critical shear rate or stress. We combine the analysis of the shear-thinning regime below the melting with that of synchrotron X-ray scattering data under shear and propose the melting to be due to a proliferation of dislocations, whose density is determined by both techniques to vary as a power law of the shear rate with a 2/3 exponent, as expected for a creep model of crystalline solids. Moreover, our data suggest the existence under shear of a line hexatic phase, between the columnar crystal and the liquid phase

The atomic orbitals of the topological atom

The effective atomic orbitals have been realized in the framework of Bader’s atoms in molecules theory for a general wavefunction. This formalism can be used to retrieve from any type of calculation a proper set of orthonormalized numerical atomic orbitals, with occupation numbers that sum up to the respective Quantum Theory of Atoms in Molecules (QTAIM) atomic populations. Experience shows that only a limited number of effective atomic orbitals exhibit significant occupation numbers. These correspond to atomic hybrids that closely resemble the core and valence shells of the atom. The occupation numbers of the remaining effective orbitals are almost negligible, except for atoms with hypervalent character. In addition, the molecular orbitals of a calculation can be exactly expressed as a linear combination of this orthonormalized set of numerical atomic orbitals, and the Mulliken population analysis carried out on this basis set exactly reproduces the original QTAIM atomic populations of the atoms. Approximate expansion of the molecular orbitals over a much reduced set of orthogonal atomic basis functions can also be accomplished to a very good accuracy with a singular value decomposition procedure

Is emamectin benzoate effective against the different stages of Spodoptera exigua (Hübner) (Lepidoptera, Noctuidae)?

peer-reviewedThis work was partially supported by the Spanish Ministry of Science and Innovation (project AGL 2007-66130-C03-02 to P. Medina). F. Amor and P. Bengochea acknowledge the ministry of Education and Culture and the Technical University of Madrid (UPM) for the doctoral fellowships. Special thanks to Syngenta Agro S.A. for their support.The beet armyworm, Spodoptera exigua (Hübner) (Lepidoptera, Noctuidae), is a major polyphagous pest in greenhouses and open fields worldwide and also a main problem in sweet pepper greenhouses. The effectiveness of the pesticide emamectin benzoate was tested in the laboratory on different stages of S. exigua using different concentrations and uptake routes. After dipping young (48-h-old) S. exigua eggs in emamectin benzoate at 0.5, 1 and 1.5 mg/L a.i. the chemical did not exhibit any ovicidal activity. There was, however, progressive neonate mortality at all concentrations, culminating at 72 hours after hatching, when 100% of the larvae from the treated young eggs died. Second and fourth instar S. exigua larvae did not exhibit significant mortality when exposed to the inert surfaces which were treated. In contrast, ingesting a diet contaminated with 0.5 mg/L a.i. of emamectin benzoate caused 100% mortality in L2 and L4 larvae 24 and 72 hours after ingestion, respectively. The LC50 value of the compound against L4 larvae that fed on sprayed sweet pepper leaves for 24 hours was 0.81 mg/L a.i.. When adults were fed on a solution of 0.5 mg/L a.i., there was a reduction in the female and male lifespan of 29.3% and 55.3%, respectively. Fecundity was reduced by more than 99%. These data suggest that emamectin benzoate is not only a useful insecticide when ingested by beet armyworm larvae but it also has ovolarvicidal and adult activity.Spanish Ministry of Science and Innovatio

Riding the kinematic waves in the Milky Way disk with Gaia

Gaia DR2 has delivered full-sky 6-D measurements for millions of stars, and the quest to understand the dynamics of our Galaxy has entered a new phase. Our aim is to reveal and characterize the kinematic sub-structure of the different Galactic neighbourhoods, to form a picture of their spatial evolution that can be used to infer the Galactic potential, its evolution and its components. We take ~5 million stars in the Galactic disk from the Gaia DR2 catalogue and build the velocity distribution of many different Galactic Neighbourhoods distributed along 5 kpc in Galactic radius and azimuth. We decompose their distribution of stars in the V_R-V_phi plane with the wavelet transformation and asses the statistical significance of the structures found. We detect many kinematic sub-structures (arches and more rounded groups) that diminish their azimuthal velocity as a function of Galactic radius in a continuous way, connecting volumes up to 3 kpc apart in some cases. The decrease rate is, on average, of ~23 km/s/kpc. In azimuth, the kinematic sub-structures present much smaller variations. We also observe a duality in their behaviour: some conserve their vertical angular momentum with radius (e.g., Hercules), while some seem to have nearly constant kinetic energy (e.g., Sirius). These two trends are consistent with the approximate predictions of resonances and of phase mixing, respectively. Besides, the overall spatial evolution of Hercules is consistent with being related to the Outer Lindblad Resonance of the Bar. We also detect structures without apparent counterpart in the vicinity of the Sun. The various trends observed and their continuity with radius and azimuth allows for future work to deeply explore the parameter space of the models. Also, the characterization of extrasolar moving groups opens the opportunity to expand our understanding of the Galaxy beyond the Solar Neighbourhood.Comment: 16 pages. Submitted to Astronomy and Astrophysics on 24th of May, 2018. Related on-line material available (see Appendix B